References
(1) Claisen, L.; Claparède, A. Condensationen von Ketonen Mit Aldehyden. Ber. Dtsch.
Chem. Ges. 1881, 14, 2460–2468.
(2) Claisen, L. Ueber Die Einführung von Säureradicalen in Ketone. Ber. Dtsch. Chem.
Ges. 1887, 20, 655–657.
(3) Seebach, D. Methods of Reactivity Umpolung. Angew. Chem. Int. Ed. Engl. 1979, 18,
239–258.
(4) Seebach, D.; Corey, E. J. Generation and Synthetic Applications of 2-Lithio-1,3Dithianes. J. Org. Chem. 1975, 40 (2), 231–237.
(5) Ganguly, N.; Barik, S. A Facile Mild Deprotection Protocol for 1,3-Dithianes and 1,3Dithiolanes with 30% Hydrogen Peroxide and Iodine Catalyst in Aqueous Micellar
System. Synthesis 2009, 8, 1393–1399.
(6) Adlington, R. M.; Baldwin, J. E.; Bottaro, J. C.; Perry, M. W. D. Azo Anions in
Synthesis. t-Butylhydrazones as Acyl-Anion Equivalents. J. Chem. Soc. Chem.
Commun. 1983, 18, 1040–1041.
(7) Wöhler; Liebig. Untersuchungen Über Das Radikal Der Benzoesäure. Ann. Phar.
1832, 3, 249–282.
(8) Stetter, H. Catalyzed Addition of Aldehydes to Activated Double Bonds? A New
Synthetic Approach. Angew. Chem. Int. Ed. Engl. 1976, 15, 639–647.
(9) Breslow, R. On the Mechanism of Thiamine Action. IV.
1
Evidence from Studies on
Model Systems. J. Am. Chem. Soc. 1958, 80, 3719–3726.
(10) Enders, D.; Breuer, K.; Runsink, J.; Teles, J. H. The First Asymmetric Intramolecular
Stetter Reaction. Preliminary Communication. Helv. Chim. Acta 1996, 79, 1899–
1902.
(11) Enders, D.; Han, J.; Henseler, A. Asymmetric Intermolecular Stetter Reactions
Catalyzed by a Novel Triazolium Derived N-Heterocyclic Carbene. Chem. Commun.
2008, 34, 3989–3991.
(12) Antranikian, G. Angewandte Mikrobiologie; Springer: Berlin, 2006.
(13) Beeson, T. D.; Mastracchio, A.; Hong, J.-B.; Ashton, K.; MacMillan, D. W. C.
Enantioselective Organocatalysis Using SOMO Activation. Science 2007, 316, 582–
585.
(14) Narasaka, K.; Okauchi, T.; Tanaka, K.; Murakami, M. Generation of Cation Radicals
from Enamines and Their Reactions with Olefins. Chem. Lett. 1992, 21, 2099–2102.
(15) Mizar, P.; Wirth, T. Flexible Stereoselective Functionalizations of Ketones through
Umpolung with Hypervalent Iodine Reagents. Angew. Chem. Int. Ed. 2014, 53, 5993–
5997.
© The Editor(s) (if applicable) and The Author(s), under exclusive license
to Springer Fachmedien Wiesbaden GmbH, part of Springer Nature 2020
M. Lemmerer, Chemoselective Nucleophilic α-Amination of Amides,
BestMaters, https://doi.org/10.1007/978-3-658-30020-3
(1) Claisen, L.; Claparède, A. Condensationen von Ketonen Mit Aldehyden. Ber. Dtsch.
Chem. Ges. 1881, 14, 2460–2468.
(2) Claisen, L. Ueber Die Einführung von Säureradicalen in Ketone. Ber. Dtsch. Chem.
Ges. 1887, 20, 655–657.
(3) Seebach, D. Methods of Reactivity Umpolung. Angew. Chem. Int. Ed. Engl. 1979, 18,
239–258.
(4) Seebach, D.; Corey, E. J. Generation and Synthetic Applications of 2-Lithio-1,3Dithianes. J. Org. Chem. 1975, 40 (2), 231–237.
(5) Ganguly, N.; Barik, S. A Facile Mild Deprotection Protocol for 1,3-Dithianes and 1,3Dithiolanes with 30% Hydrogen Peroxide and Iodine Catalyst in Aqueous Micellar
System. Synthesis 2009, 8, 1393–1399.
(6) Adlington, R. M.; Baldwin, J. E.; Bottaro, J. C.; Perry, M. W. D. Azo Anions in
Synthesis. t-Butylhydrazones as Acyl-Anion Equivalents. J. Chem. Soc. Chem.
Commun. 1983, 18, 1040–1041.
(7) Wöhler; Liebig. Untersuchungen Über Das Radikal Der Benzoesäure. Ann. Phar.
1832, 3, 249–282.
(8) Stetter, H. Catalyzed Addition of Aldehydes to Activated Double Bonds? A New
Synthetic Approach. Angew. Chem. Int. Ed. Engl. 1976, 15, 639–647.
(9) Breslow, R. On the Mechanism of Thiamine Action. IV.
1
Evidence from Studies on
Model Systems. J. Am. Chem. Soc. 1958, 80, 3719–3726.
(10) Enders, D.; Breuer, K.; Runsink, J.; Teles, J. H. The First Asymmetric Intramolecular
Stetter Reaction. Preliminary Communication. Helv. Chim. Acta 1996, 79, 1899–
1902.
(11) Enders, D.; Han, J.; Henseler, A. Asymmetric Intermolecular Stetter Reactions
Catalyzed by a Novel Triazolium Derived N-Heterocyclic Carbene. Chem. Commun.
2008, 34, 3989–3991.
(12) Antranikian, G. Angewandte Mikrobiologie; Springer: Berlin, 2006.
(13) Beeson, T. D.; Mastracchio, A.; Hong, J.-B.; Ashton, K.; MacMillan, D. W. C.
Enantioselective Organocatalysis Using SOMO Activation. Science 2007, 316, 582–
585.
(14) Narasaka, K.; Okauchi, T.; Tanaka, K.; Murakami, M. Generation of Cation Radicals
from Enamines and Their Reactions with Olefins. Chem. Lett. 1992, 21, 2099–2102.
(15) Mizar, P.; Wirth, T. Flexible Stereoselective Functionalizations of Ketones through
Umpolung with Hypervalent Iodine Reagents. Angew. Chem. Int. Ed. 2014, 53, 5993–
5997.
© The Editor(s) (if applicable) and The Author(s), under exclusive license
to Springer Fachmedien Wiesbaden GmbH, part of Springer Nature 2020
M. Lemmerer, Chemoselective Nucleophilic α-Amination of Amides,
BestMaters, https://doi.org/10.1007/978-3-658-30020-3