CO 2 adsorption, 5–15
four-connected framework, 2
hydrocarbon separation
butenes, 19–20
ethylene, 16–17
propylene, 17–19
methane, 20
nitrogen oxides, 22–23
three-dimensional, 2
water, 20–22
SMB zeolite 13X, propane/propylene, 176–183
Standard liters per minute (SLPM), 180
T
Technical limitations, 218
Temperature swing adsorption (TSA), 3
Tetrapropylammonium (TPA), 95
Textural properties analysis
pore size distribution, 47–51
pore volume, 45–47
specific surface area, 40–45
Transition state theory (TST), 71
True moving bed (TMB), 151, 178, 179
Tuning selectivity, 213–216
V
Vacuum pressure swing adsorption (VPSA),
148, 150, 151, 164, 169, 171,
173–178, 186, 203, 204
Vacuum swing adsorption (VSA), 3, 4, 9, 19,
148, 151, 159, 163, 173, 203–205
Validation, 165–171
W
Water, 20–21
Windows, 33
X
X-ray diffraction (XRD), 153
Z
Zeolite 13X, 41, 43, 147, 148, 150–152, 155,
157–161, 163, 172, 176, 177, 181,
185, 198
Zeolite adsorbents
CHA, 105–107
equilibrium, 100–103
framework structure, 99–100
ITQ-29, 105–106
kinetics, 103–105
LTA, 106
MFI, 92–94
mixture separation, 98
process aspects, 98
pulse field gradient, 97
renewable alcohols, 86–90
silicalite-1, 90–92
water, 94–96
Zeolite Rho, 131–142
Zeotypes, 12–15
Zero length column (ZLC) technique
CO 2 diffusivities, 131–142
experiment, 123–126
theory, 127–130
Index
229
four-connected framework, 2
hydrocarbon separation
butenes, 19–20
ethylene, 16–17
propylene, 17–19
methane, 20
nitrogen oxides, 22–23
three-dimensional, 2
water, 20–22
SMB zeolite 13X, propane/propylene, 176–183
Standard liters per minute (SLPM), 180
T
Technical limitations, 218
Temperature swing adsorption (TSA), 3
Tetrapropylammonium (TPA), 95
Textural properties analysis
pore size distribution, 47–51
pore volume, 45–47
specific surface area, 40–45
Transition state theory (TST), 71
True moving bed (TMB), 151, 178, 179
Tuning selectivity, 213–216
V
Vacuum pressure swing adsorption (VPSA),
148, 150, 151, 164, 169, 171,
173–178, 186, 203, 204
Vacuum swing adsorption (VSA), 3, 4, 9, 19,
148, 151, 159, 163, 173, 203–205
Validation, 165–171
W
Water, 20–21
Windows, 33
X
X-ray diffraction (XRD), 153
Z
Zeolite 13X, 41, 43, 147, 148, 150–152, 155,
157–161, 163, 172, 176, 177, 181,
185, 198
Zeolite adsorbents
CHA, 105–107
equilibrium, 100–103
framework structure, 99–100
ITQ-29, 105–106
kinetics, 103–105
LTA, 106
MFI, 92–94
mixture separation, 98
process aspects, 98
pulse field gradient, 97
renewable alcohols, 86–90
silicalite-1, 90–92
water, 94–96
Zeolite Rho, 131–142
Zeotypes, 12–15
Zero length column (ZLC) technique
CO 2 diffusivities, 131–142
experiment, 123–126
theory, 127–130
Index
229
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