H
Heteroselective, 63
HEXORB, 209
Homoselective, 63
Hydrogen production, 205–206
I
Ideal adsorbed solution theory (IAST), 71
Industrial zeolite applications
adsorbent, 197–198
air drying, 203
CO 2 separations, 207–208
commercial, 198–201
development
balancing capacity, 217–219
mass transfer, 219–221
tuning selectivity, 213–216
hydrogen production, 205–206
mechanical properties, 221–222
natural gas, 203
n-paraffin/i-paraffin separation, 209–210
oxygen production, 203–205
thermochemical, 221–222
xylene isomers separation, 210–212
Integration, 218
Interference microscopy (IFM), 104
International Union for Pure and Applied
Chemistry (IUPAC), 33
IPSORB, 209
K
KFI-type zeolites, 8–9
L
Linde type A (LTA), 6–7, 196
M
Mass transfer, 219–221
Mathematical modeling
energy balance, 167–168
initial conditions, 168
material balance, 165–166
momentum balance, 166–167
Mesopore size distribution, 51
Metal organic frameworks (MOFs), 2, 4–6
Methane, 20
Micropore size distribution, 48–50
Mixture separation, 98
Models
adsorbates, 62–63
adsorbents, 59–62
extra framework cations, 63–64
Molecular dynamics (MD), 69–71
Monte Carlo methods, 66–69
N
Nitrogen oxides (NOx), 22–23
O
Oxygen production, 203–205
P
Polyethylene terephthalate (PET), 210
Pore topology, 16
Pore volume, 45–47
Porous materials, 32, 34
Pressure swing adsorption (PSA), 148
Process aspects, 98
Propane, 17–19
Propane/propylene, binderless zeolite 13X,
172–176
Pulse field gradient (PFG), 97
Pure component adsorption equilibrium,
154–162
Q
Quantitative structure property relationship
(QSPR), 215
R
Raffinate recovery, 180
Regenerability, 217–219
S
Sample pretreatment, 35–36
Scanning electron microscopy (SEM), 153
Simulated moving bed (SMB), 148, 149,
151–153, 162, 165, 171–172,
176–183, 203, 211, 212
Simulation methods
molecular dynamics, 69–71
Monte Carlo, 66–69
Single-site Langmuir (SSL) model, 155
Small gases, 4
Small-pore zeolites
adsorbents, 4–5
228
Index
Heteroselective, 63
HEXORB, 209
Homoselective, 63
Hydrogen production, 205–206
I
Ideal adsorbed solution theory (IAST), 71
Industrial zeolite applications
adsorbent, 197–198
air drying, 203
CO 2 separations, 207–208
commercial, 198–201
development
balancing capacity, 217–219
mass transfer, 219–221
tuning selectivity, 213–216
hydrogen production, 205–206
mechanical properties, 221–222
natural gas, 203
n-paraffin/i-paraffin separation, 209–210
oxygen production, 203–205
thermochemical, 221–222
xylene isomers separation, 210–212
Integration, 218
Interference microscopy (IFM), 104
International Union for Pure and Applied
Chemistry (IUPAC), 33
IPSORB, 209
K
KFI-type zeolites, 8–9
L
Linde type A (LTA), 6–7, 196
M
Mass transfer, 219–221
Mathematical modeling
energy balance, 167–168
initial conditions, 168
material balance, 165–166
momentum balance, 166–167
Mesopore size distribution, 51
Metal organic frameworks (MOFs), 2, 4–6
Methane, 20
Micropore size distribution, 48–50
Mixture separation, 98
Models
adsorbates, 62–63
adsorbents, 59–62
extra framework cations, 63–64
Molecular dynamics (MD), 69–71
Monte Carlo methods, 66–69
N
Nitrogen oxides (NOx), 22–23
O
Oxygen production, 203–205
P
Polyethylene terephthalate (PET), 210
Pore topology, 16
Pore volume, 45–47
Porous materials, 32, 34
Pressure swing adsorption (PSA), 148
Process aspects, 98
Propane, 17–19
Propane/propylene, binderless zeolite 13X,
172–176
Pulse field gradient (PFG), 97
Pure component adsorption equilibrium,
154–162
Q
Quantitative structure property relationship
(QSPR), 215
R
Raffinate recovery, 180
Regenerability, 217–219
S
Sample pretreatment, 35–36
Scanning electron microscopy (SEM), 153
Simulated moving bed (SMB), 148, 149,
151–153, 162, 165, 171–172,
176–183, 203, 211, 212
Simulation methods
molecular dynamics, 69–71
Monte Carlo, 66–69
Single-site Langmuir (SSL) model, 155
Small gases, 4
Small-pore zeolites
adsorbents, 4–5
228
Index