44
3 The Reactivity of Nitrile Imines
Et
3 N
65
o
C, 12 h
80 %
Et
3 N, PhMe
90
o
C, 5 h
85 %
F
3 C
Cl
N
NH
F
3 C
N
N
CO
2 Me
CO
2 Me
Et
3 N, PhH
80
o
C, 20 h
87 %
27:73 A:B
Cl
N
NH
SO
2 Ph
Ph
O
N N
Ph
O
N N
O
Ph
+
Cl
N
NH
N
N
OH
OH
A
B
Scheme 3.5
A brief example of the diverse range of known NI cycloadditions
3 The Reactivity of Nitrile Imines
Et
3 N
65
o
C, 12 h
80 %
Et
3 N, PhMe
90
o
C, 5 h
85 %
F
3 C
Cl
N
NH
F
3 C
N
N
CO
2 Me
CO
2 Me
Et
3 N, PhH
80
o
C, 20 h
87 %
27:73 A:B
Cl
N
NH
SO
2 Ph
Ph
O
N N
Ph
O
N N
O
Ph
+
Cl
N
NH
N
N
OH
OH
A
B
Scheme 3.5
A brief example of the diverse range of known NI cycloadditions