265
FT-MS spectra (Eiler et al. 2017), FTICR-MS could provide revolutionary capabilities in tracing and quantifying the incorporation of petroleum carbon into the nearsurface biogeosphere.
Acknowledgments This research was made possible in part by a grant from the Gulf of Mexico
Research Initiative through the Center for the Integrated Modeling and Analysis of the Gulf
Ecosystem (C-IMAGE) and in part from CFI, NSERC, the University of Calgary, and the Canada
Research Chairs. Data are publicly available through the Gulf of Mexico Research Initiative
Information & Data Cooperative (GRIIDC) at http://data.gulfresearchinitiative.org (doi: 10.7266/
N71R6NGQ).
References
Aeppli C, Carmichael CA, Nelson RK, Lemkau KL, Graham WM, Redmond MC, Valentine DL,
Reddy CM (2012) Oil weathering after the Deepwater horizon disaster led to the formation
of oxygenated residues. Environ Sci Technol 46(16):8799–8807. https://doi.org/10.1021/
es3015138
Aeppli C, Nelson RK, Radović JR, Carmichael CA, Valentine DL, Reddy CM (2014) Recalcitrance
and degradation of petroleum biomarkers upon abiotic and biotic natural weathering of
Deepwater horizon oil. Environ Sci Technol 48(12):6726–6734. https://doi.org/10.1021/
es500825q
Andersson JT, Schade T (2004) Higher alkylated dibenzothiophenes in some crude oils and
hydrodesulfurized fuels. ACS Division of Fuel Chemistry, Preprints 49
Atlas RM, Hazen TC (2011) Oil biodegradation and bioremediation: a tale of the two worst spills
in U.S. history. Environ Sci Technol 45(16):6709–6715. https://doi.org/10.1021/es2013227
Blumer M, Ehrhardt M, Jones JH (1973) The environmental fate of stranded crude oil. Deep-Sea
Res Oceanogr Abstr 20(3):239–259. https://doi.org/10.1016/0011-7471(73)90014-4
Chanton J, Zhao T, Rosenheim BE, Joye S, Bosman S, Brunner C, Yeager KM, Diercks AR,
Hollander D (2015) Using natural abundance radiocarbon to trace the flux of Petrocarbon to
the seafloor following the Deepwater horizon oil spill. Environ Sci Technol 49(2):847–854.
https://doi.org/10.1021/es5046524
Chen H, Hou A, Corilo YE, Lin Q, Lu J, Mendelssohn IA, Zhang R, Rodgers RP, McKenna AM
(2016) 4 years after the Deepwater horizon spill: molecular transformation of Macondo well oil
in Louisiana salt marsh sediments revealed by FT-ICR mass spectrometry. Environ Sci Technol
50(17):9061–9069. https://doi.org/10.1021/acs.est.6b01156
Comisarow MB, Marshall AG (1974) Fourier transform ion cyclotron resonance spectroscopy.
Chem Phys Lett 25:282–283. https://doi.org/10.1016/0009-2614(74)89137-2
Daly KL, Passow U, Chanton J, Hollander D (2016) Assessing the impacts of oil-associated
marine snow formation and sedimentation during and after the Deepwater horizon oil spill.
Anthropocene 13:18–33. https://doi.org/10.1016/j.ancene.2016.01.006
Doyle SM, Whitaker EA, De Pascuale V, Wade TL, Knap AH, Santschi PH, Quigg A, Sylvan JB
(2018) Rapid formation of microbe-oil aggregates and changes in community composition in
coastal surface water following exposure to oil and the dispersant Corexit. Front Microbiol
9(689). https://doi.org/10.3389/fmicb.2018.00689
Eiler J, Cesar J, Chimiak L, Dallas B, Grice K, Griep-Raming J, Juchelka D, Kitchen N, Lloyd M,
Makarov A, Robins R, Schwieters J (2017) Analysis of molecular isotopic structures at high
precision and accuracy by Orbitrap mass spectrometry. Int J Mass Spectrom 422:126–142.
https://doi.org/10.1016/j.ijms.2017.10.002
Gonsior M, Zwartjes M, Cooper WJ, Song W, Ishida KP, Tseng LY, Jeung MK, Rosso D, Hertkorn
N, Schmitt-Kopplin P (2011) Molecular characterization of effluent organic matter identified by
15 Applications of FTICR-MS in Oil Spill Studies
FT-MS spectra (Eiler et al. 2017), FTICR-MS could provide revolutionary capabilities in tracing and quantifying the incorporation of petroleum carbon into the nearsurface biogeosphere.
Acknowledgments This research was made possible in part by a grant from the Gulf of Mexico
Research Initiative through the Center for the Integrated Modeling and Analysis of the Gulf
Ecosystem (C-IMAGE) and in part from CFI, NSERC, the University of Calgary, and the Canada
Research Chairs. Data are publicly available through the Gulf of Mexico Research Initiative
Information & Data Cooperative (GRIIDC) at http://data.gulfresearchinitiative.org (doi: 10.7266/
N71R6NGQ).
References
Aeppli C, Carmichael CA, Nelson RK, Lemkau KL, Graham WM, Redmond MC, Valentine DL,
Reddy CM (2012) Oil weathering after the Deepwater horizon disaster led to the formation
of oxygenated residues. Environ Sci Technol 46(16):8799–8807. https://doi.org/10.1021/
es3015138
Aeppli C, Nelson RK, Radović JR, Carmichael CA, Valentine DL, Reddy CM (2014) Recalcitrance
and degradation of petroleum biomarkers upon abiotic and biotic natural weathering of
Deepwater horizon oil. Environ Sci Technol 48(12):6726–6734. https://doi.org/10.1021/
es500825q
Andersson JT, Schade T (2004) Higher alkylated dibenzothiophenes in some crude oils and
hydrodesulfurized fuels. ACS Division of Fuel Chemistry, Preprints 49
Atlas RM, Hazen TC (2011) Oil biodegradation and bioremediation: a tale of the two worst spills
in U.S. history. Environ Sci Technol 45(16):6709–6715. https://doi.org/10.1021/es2013227
Blumer M, Ehrhardt M, Jones JH (1973) The environmental fate of stranded crude oil. Deep-Sea
Res Oceanogr Abstr 20(3):239–259. https://doi.org/10.1016/0011-7471(73)90014-4
Chanton J, Zhao T, Rosenheim BE, Joye S, Bosman S, Brunner C, Yeager KM, Diercks AR,
Hollander D (2015) Using natural abundance radiocarbon to trace the flux of Petrocarbon to
the seafloor following the Deepwater horizon oil spill. Environ Sci Technol 49(2):847–854.
https://doi.org/10.1021/es5046524
Chen H, Hou A, Corilo YE, Lin Q, Lu J, Mendelssohn IA, Zhang R, Rodgers RP, McKenna AM
(2016) 4 years after the Deepwater horizon spill: molecular transformation of Macondo well oil
in Louisiana salt marsh sediments revealed by FT-ICR mass spectrometry. Environ Sci Technol
50(17):9061–9069. https://doi.org/10.1021/acs.est.6b01156
Comisarow MB, Marshall AG (1974) Fourier transform ion cyclotron resonance spectroscopy.
Chem Phys Lett 25:282–283. https://doi.org/10.1016/0009-2614(74)89137-2
Daly KL, Passow U, Chanton J, Hollander D (2016) Assessing the impacts of oil-associated
marine snow formation and sedimentation during and after the Deepwater horizon oil spill.
Anthropocene 13:18–33. https://doi.org/10.1016/j.ancene.2016.01.006
Doyle SM, Whitaker EA, De Pascuale V, Wade TL, Knap AH, Santschi PH, Quigg A, Sylvan JB
(2018) Rapid formation of microbe-oil aggregates and changes in community composition in
coastal surface water following exposure to oil and the dispersant Corexit. Front Microbiol
9(689). https://doi.org/10.3389/fmicb.2018.00689
Eiler J, Cesar J, Chimiak L, Dallas B, Grice K, Griep-Raming J, Juchelka D, Kitchen N, Lloyd M,
Makarov A, Robins R, Schwieters J (2017) Analysis of molecular isotopic structures at high
precision and accuracy by Orbitrap mass spectrometry. Int J Mass Spectrom 422:126–142.
https://doi.org/10.1016/j.ijms.2017.10.002
Gonsior M, Zwartjes M, Cooper WJ, Song W, Ishida KP, Tseng LY, Jeung MK, Rosso D, Hertkorn
N, Schmitt-Kopplin P (2011) Molecular characterization of effluent organic matter identified by
15 Applications of FTICR-MS in Oil Spill Studies