35. Chang J, Zhao Q, Kang L, Li H, Xie M, Liao X (2016) Multiresponsive supramolecular gel
based on pillararene-containing polymers. Macromolecules 49:2814–2820
36. Webber MJ, Langer R (2017) Drug delivery by supramolecular design. Chem Soc Rev
46:6600–6620
37. Guo S, Liang T, Song Y, Cheng M, Hu X-Y, Zhu J-J, Wang L (2017) Supramolecular
Polymersomes constructed from water-soluble pillar[5]arene and cationic poly(glutamamide)s
and their applications in targeted anticancer drug delivery. Polym Chem 8:5718–5725
38. Chi X, Ji X, Xia D, Huang F (2015) A dual-responsive supra-amphiphilic polypseudorotaxane
constructed from a water-soluble pillar[7]arene and an azobenzene-containing random copolymer. J Am Chem Soc 137:1440–1443
39. Fu S, Zhang Y, Guan S, Huang Q, Wang R, Tian R, Zang M, Qiao S, Zhang X, Liu S, Fan X, Li
X, Luo Q, Hou C, Xu J, Dong Z, Liu J (2018) Reductive-responsive, single-molecular-layer
polymer nanocapsules prepared by lateral-functionalized pillar[5]arenes for targeting anticancer
drug delivery. ACS Appl Mater Interfaces 10:14281–14286
40. Yu G, Zhao R, Wu D, Zhang F, Shao L, Zhou J, Yang J, Tang G, Chen X, Huang F (2016) Pillar
[5]arene-based amphiphilic supramolecular brush copolymers: fabrication, controllable selfassembly and application in self-imaging targeted drug delivery. Polym Chem 7:6178–6188
41. (a) Jiang K, Sun S, Zhang L, Lu Y, Wu A, Cai C, Lin H (2015) Red, green, and blue
luminescence by carbon dots: full-color emission tuning and multicolor cellular imaging.
Angew Chem Int Ed 54:5360–5363; (b) Zhu X-H, Peng J, Cao Y, Roncali J (2011) SolutionProcessable single-material molecular emitters for organic light-emitting devices. Chem Soc
Rev 40:3509–3524
42. Sun C-L, Gao Z, Teng K-X, Niu L-Y, Chen Y-Z, Zhao YS, Yang Q-Z (2018) Supramolecular
polymer-based fluorescent microfibers for switchable optical waveguides. ACS Appl Mater
Interfaces 10:26526–26532
43. Meng L-B, Li D, Xiong S, Hu X-Y, Wang L, Li G (2015) FRET-capable supramolecular
polymers based on a BODIPY-bridged pillar[5]arene dimer with BODIPY guests for mimicking
the light-harvesting system of natural photosynthesis. Chem Commun 51:4643–4646
44. Li H, Chen W, Xu F, Fan X, Liang T, Qi X, Tian W (2018) A color-tunable fluorescent
supramolecular Hyperbranched polymer constructed by pillar[5]arene-based host–guest recognition and metal ion coordination interaction. Macromol Rapid Commun 39:1800053
45. Yang X, Cai W, Dong S, Zhang K, Zhang J, Huang F, Huang F, Cao Y (2017) Fluorescent
supramolecular polymers based on pillar[5]arene for OLED device fabrication. ACS Macro Lett
6:647–651
46. (a) Wang F, Klaikherd A, Thayumanavan S (2011) Temperature sensitivity trends and multistimuli sensitive behavior in amphiphilic oligomers. J Am Chem Soc 133:13496–13503; (b)
Betancourt JE, Rivera JM (2009) Nonpolymeric thermosensitive supramolecules. J Am Chem
Soc 131:16666–16668
47. Yu G, Zhou J, Chi X (2015) Pillar[10]arene-based size-selective host–guest complexation and
its application in tuning the LCST behavior of a thermoresponsive polymer. Macromol Rapid
Commun 36:23–30
48. (a) Xu Z, Wang S, Hu X-Y, Jiang J, Sun X, Wang L (2018) Sunlight-induced photo-thermochromic supramolecular nanocomposite hydrogel film for energy-saving smart window. Sol
RRL 2:1800204; (b) Wang S, Xu Z, Wang T, Xiao T, Hu X-Y, Shen Y-Z, Wang L (2018) Warm/
cool-tone switchable thermochromic material for smart windows by orthogonally integrating
properties of pillar[6]arene and ferrocene. Nat Commun 9:1737
49. (a) Peters O, Ritter H (2013) Supramolecular controlled water uptake of macroscopic materials
by a cyclodextrin-induced hydrophobic-to-hydrophilic transition. Angew Chem Int Ed
52:8961–8963; (b) Miyamae K, Nakahata M, Takashima Y, Harada A (2015) Self-healing,
expansion–contraction, and shape-memory properties of a preorganized supramolecular hydrogel through host–guest interactions. Angew Chem Int Ed 54:8984–8987
50. Ni M, Zhang N, Xia W, Wu X, Yao C, Liu X, Hu X-Y, Lin C, Wang L (2016) Dramatically
promoted swelling of a hydrogel by pillar[6]arene–ferrocene complexation with multistimuli
responsiveness. J Am Chem Soc 138:6643–6649
13 Pillararene-Based Supramolecular Polymer
381
based on pillararene-containing polymers. Macromolecules 49:2814–2820
36. Webber MJ, Langer R (2017) Drug delivery by supramolecular design. Chem Soc Rev
46:6600–6620
37. Guo S, Liang T, Song Y, Cheng M, Hu X-Y, Zhu J-J, Wang L (2017) Supramolecular
Polymersomes constructed from water-soluble pillar[5]arene and cationic poly(glutamamide)s
and their applications in targeted anticancer drug delivery. Polym Chem 8:5718–5725
38. Chi X, Ji X, Xia D, Huang F (2015) A dual-responsive supra-amphiphilic polypseudorotaxane
constructed from a water-soluble pillar[7]arene and an azobenzene-containing random copolymer. J Am Chem Soc 137:1440–1443
39. Fu S, Zhang Y, Guan S, Huang Q, Wang R, Tian R, Zang M, Qiao S, Zhang X, Liu S, Fan X, Li
X, Luo Q, Hou C, Xu J, Dong Z, Liu J (2018) Reductive-responsive, single-molecular-layer
polymer nanocapsules prepared by lateral-functionalized pillar[5]arenes for targeting anticancer
drug delivery. ACS Appl Mater Interfaces 10:14281–14286
40. Yu G, Zhao R, Wu D, Zhang F, Shao L, Zhou J, Yang J, Tang G, Chen X, Huang F (2016) Pillar
[5]arene-based amphiphilic supramolecular brush copolymers: fabrication, controllable selfassembly and application in self-imaging targeted drug delivery. Polym Chem 7:6178–6188
41. (a) Jiang K, Sun S, Zhang L, Lu Y, Wu A, Cai C, Lin H (2015) Red, green, and blue
luminescence by carbon dots: full-color emission tuning and multicolor cellular imaging.
Angew Chem Int Ed 54:5360–5363; (b) Zhu X-H, Peng J, Cao Y, Roncali J (2011) SolutionProcessable single-material molecular emitters for organic light-emitting devices. Chem Soc
Rev 40:3509–3524
42. Sun C-L, Gao Z, Teng K-X, Niu L-Y, Chen Y-Z, Zhao YS, Yang Q-Z (2018) Supramolecular
polymer-based fluorescent microfibers for switchable optical waveguides. ACS Appl Mater
Interfaces 10:26526–26532
43. Meng L-B, Li D, Xiong S, Hu X-Y, Wang L, Li G (2015) FRET-capable supramolecular
polymers based on a BODIPY-bridged pillar[5]arene dimer with BODIPY guests for mimicking
the light-harvesting system of natural photosynthesis. Chem Commun 51:4643–4646
44. Li H, Chen W, Xu F, Fan X, Liang T, Qi X, Tian W (2018) A color-tunable fluorescent
supramolecular Hyperbranched polymer constructed by pillar[5]arene-based host–guest recognition and metal ion coordination interaction. Macromol Rapid Commun 39:1800053
45. Yang X, Cai W, Dong S, Zhang K, Zhang J, Huang F, Huang F, Cao Y (2017) Fluorescent
supramolecular polymers based on pillar[5]arene for OLED device fabrication. ACS Macro Lett
6:647–651
46. (a) Wang F, Klaikherd A, Thayumanavan S (2011) Temperature sensitivity trends and multistimuli sensitive behavior in amphiphilic oligomers. J Am Chem Soc 133:13496–13503; (b)
Betancourt JE, Rivera JM (2009) Nonpolymeric thermosensitive supramolecules. J Am Chem
Soc 131:16666–16668
47. Yu G, Zhou J, Chi X (2015) Pillar[10]arene-based size-selective host–guest complexation and
its application in tuning the LCST behavior of a thermoresponsive polymer. Macromol Rapid
Commun 36:23–30
48. (a) Xu Z, Wang S, Hu X-Y, Jiang J, Sun X, Wang L (2018) Sunlight-induced photo-thermochromic supramolecular nanocomposite hydrogel film for energy-saving smart window. Sol
RRL 2:1800204; (b) Wang S, Xu Z, Wang T, Xiao T, Hu X-Y, Shen Y-Z, Wang L (2018) Warm/
cool-tone switchable thermochromic material for smart windows by orthogonally integrating
properties of pillar[6]arene and ferrocene. Nat Commun 9:1737
49. (a) Peters O, Ritter H (2013) Supramolecular controlled water uptake of macroscopic materials
by a cyclodextrin-induced hydrophobic-to-hydrophilic transition. Angew Chem Int Ed
52:8961–8963; (b) Miyamae K, Nakahata M, Takashima Y, Harada A (2015) Self-healing,
expansion–contraction, and shape-memory properties of a preorganized supramolecular hydrogel through host–guest interactions. Angew Chem Int Ed 54:8984–8987
50. Ni M, Zhang N, Xia W, Wu X, Yao C, Liu X, Hu X-Y, Lin C, Wang L (2016) Dramatically
promoted swelling of a hydrogel by pillar[6]arene–ferrocene complexation with multistimuli
responsiveness. J Am Chem Soc 138:6643–6649
13 Pillararene-Based Supramolecular Polymer
381