Pillararene-Based Supramolecular Polymer
13
Xuan Wu, Yong Chen, and Yu Liu
Contents
13.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 341
13.2 Construction of Pillar[N]Arene-Based Supramolecular Polymer . . . . . . . . . . . . . . . . . . . . . . . 344
13.2.1 Supramolecular Polymer Formed by Host-Guest Interaction . . . . . . . . . . . . . . . . . 344
13.2.2 Supramolecular Polymer Formed by Hydrogen Bonding and Halogen
Bond . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 345
13.2.3 Supramolecular Polymer Formed by Metal-Ligand Binding . . . . . . . . . . . . . . . . . . 350
13.2.4 Supramolecular Polymer Constructed by Covalent Polymer . . . . . . . . . . . . . . . . . . 352
13.3 Function of Pillar[N]Arene-Based Supramolecular Polymer . . . . . . . . . . . . . . . . . . . . . . . . . . . 355
13.3.1 Chemical Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 356
13.3.2 Stimuli-Responsive Soft Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 360
13.3.3 Application for the Nano-carrier . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 365
13.3.4 Application for Optical Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 372
13.3.5 Other Functional Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 374
13.4 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 377
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 378
13.1 Introduction
As a new generation of macrocyclic host molecule, pillararene has attracted tremendous attention since its firstly being synthesized in 2008 [1] and advanced rapidly.
Different with calixarene [2], which was meta-bridged phenolic macrocycles and
X. Wu
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin, China
Y. Chen · Y. Liu (*)
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin, China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),
Tianjin, China
e-mail: yuliu@nankai.edu.cn
© Springer Nature Singapore Pte Ltd. 2020
Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
https://doi.org/10.1007/978-981-15-2686-2_14
341
13
Xuan Wu, Yong Chen, and Yu Liu
Contents
13.1 Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 341
13.2 Construction of Pillar[N]Arene-Based Supramolecular Polymer . . . . . . . . . . . . . . . . . . . . . . . 344
13.2.1 Supramolecular Polymer Formed by Host-Guest Interaction . . . . . . . . . . . . . . . . . 344
13.2.2 Supramolecular Polymer Formed by Hydrogen Bonding and Halogen
Bond . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 345
13.2.3 Supramolecular Polymer Formed by Metal-Ligand Binding . . . . . . . . . . . . . . . . . . 350
13.2.4 Supramolecular Polymer Constructed by Covalent Polymer . . . . . . . . . . . . . . . . . . 352
13.3 Function of Pillar[N]Arene-Based Supramolecular Polymer . . . . . . . . . . . . . . . . . . . . . . . . . . . 355
13.3.1 Chemical Sensors . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 356
13.3.2 Stimuli-Responsive Soft Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 360
13.3.3 Application for the Nano-carrier . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 365
13.3.4 Application for Optical Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 372
13.3.5 Other Functional Materials . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 374
13.4 Conclusion . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 377
References . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 378
13.1 Introduction
As a new generation of macrocyclic host molecule, pillararene has attracted tremendous attention since its firstly being synthesized in 2008 [1] and advanced rapidly.
Different with calixarene [2], which was meta-bridged phenolic macrocycles and
X. Wu
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin, China
Y. Chen · Y. Liu (*)
College of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University,
Tianjin, China
Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),
Tianjin, China
e-mail: yuliu@nankai.edu.cn
© Springer Nature Singapore Pte Ltd. 2020
Y. Liu et al. (eds.), Handbook of Macrocyclic Supramolecular Assembly,
https://doi.org/10.1007/978-981-15-2686-2_14
341