1 Ligand-Free Sub-Nanometer Metal Clusters in Catalysis
37
63. Sá J, Goguet A, Taylor SFR et al (2011) Influence of methyl halide treatment on gold nanoparticles supported on activated carbon. Angew Chem Int Ed Engl 50:8912–8916. https://doi.org/
10.1002/anie.201102066
64. Sakaki S, Mizoe N, Sugimoto M (1998) theoretical study of platinum(0)-catalyzed hydrosilylation of ethylene. chalk − harrod mechanism or modified chalk − harrod mechanism.
Organometallics 17:2510–2523. https://doi.org/10.1021/om980190a
65. Scarabelli L, Coronado-Puchau M, Giner-Casares JJ et al (2014) monodisperse gold nanotriangles: size control, large-scale self-assembly, and performance in surface-enhanced raman
scattering. ACS Nano 8:5833–5842. https://doi.org/10.1021/nn500727w
66. Serna P, Gates BC (2014) Molecular metal catalysts on supports: organometallic chemistry
meets surface science. Acc Chem Res 47:2612–2620. https://doi.org/10.1021/ar500170k
67. Sharma S, Kurashige W, Niihori Y, Negishi Y (2016) Nanocluster Science. Elsevier Inc
68. Tian S, Fu Q, Chen W et al (2018) Carbon nitride supported Fe2 cluster catalysts with superior
performance for alkene epoxidation. Nat Commun 9:2353. https://doi.org/10.1038/s41467018-04845-x
69. Vajda S, White MG (2015) Catalysis applications of size-selected cluster deposition. ACS
Catal 5:7152–7176. https://doi.org/10.1021/acscatal.5b01816
70. Wang N, Sun Q, Yu J (2019) Ultrasmall metal nanoparticles confined within crystalline
nanoporous materials: a fascinating class of nanocatalysts. Adv Mater 31:1–23. https://doi.
org/10.1002/adma.201803966
71. Wu X-F, Anbarasan P, Neumann H, Beller M (2010) From noble metal to nobel prize: palladiumcatalyzed coupling reactions as key methods in organic synthesis. Angew Chemie, Int Ed
49:9047–9050. https://doi.org/10.1002/anie.201006374
72. Yang Y, Reber AC, Gilliland SE et al (2018) Donor/acceptor concepts for developing efficient
suzuki cross-coupling catalysts using graphene-supported Ni, Cu, Fe, Pd, and Bimetallic Pd/Ni
Clusters. J Phys Chem C 122:25396–25403. https://doi.org/10.1021/acs.jpcc.8b07538
73. Zea H, Lester K, Datye AK et al (2005) The influence of Pd-Ag catalyst restructuring on the
activation energy for ethylene hydrogenation in ethylene-acetylene mixtures. Appl Catal A
Gen 282:237–245. https://doi.org/10.1016/j.apcata.2004.12.026
74. Zhai Y, Pierre D, Si R (2010) Alkali-stabilized Pt-OH<em><sub>x</sub
></em> species catalyze low-temperature water-gas shift reactions. Science (80)
329:1633 LP–1636. https://doi.org/10.1126/science.1192449
75. Zhang C, Laine RM (2000) Hydrosilylation of allyl alcohol with [HSiMe2OSiO1.5]8: Octa
(3-hydroxypropyldimethylsiloxy) octasilsesquioxane and its octamethacrylate derivative as
potential precursors to hybrid nanocomposites. J Am Chem Soc 122:6979–6988. https://doi.
org/10.1021/ja000318r
76. Zitoun D, Respaud M, Fromen M-C et al (2002) Magnetic enhancement in nanoscale corh
particles. Phys Rev Lett 89:37203. https://doi.org/10.1103/PhysRevLett.89.037203
37
63. Sá J, Goguet A, Taylor SFR et al (2011) Influence of methyl halide treatment on gold nanoparticles supported on activated carbon. Angew Chem Int Ed Engl 50:8912–8916. https://doi.org/
10.1002/anie.201102066
64. Sakaki S, Mizoe N, Sugimoto M (1998) theoretical study of platinum(0)-catalyzed hydrosilylation of ethylene. chalk − harrod mechanism or modified chalk − harrod mechanism.
Organometallics 17:2510–2523. https://doi.org/10.1021/om980190a
65. Scarabelli L, Coronado-Puchau M, Giner-Casares JJ et al (2014) monodisperse gold nanotriangles: size control, large-scale self-assembly, and performance in surface-enhanced raman
scattering. ACS Nano 8:5833–5842. https://doi.org/10.1021/nn500727w
66. Serna P, Gates BC (2014) Molecular metal catalysts on supports: organometallic chemistry
meets surface science. Acc Chem Res 47:2612–2620. https://doi.org/10.1021/ar500170k
67. Sharma S, Kurashige W, Niihori Y, Negishi Y (2016) Nanocluster Science. Elsevier Inc
68. Tian S, Fu Q, Chen W et al (2018) Carbon nitride supported Fe2 cluster catalysts with superior
performance for alkene epoxidation. Nat Commun 9:2353. https://doi.org/10.1038/s41467018-04845-x
69. Vajda S, White MG (2015) Catalysis applications of size-selected cluster deposition. ACS
Catal 5:7152–7176. https://doi.org/10.1021/acscatal.5b01816
70. Wang N, Sun Q, Yu J (2019) Ultrasmall metal nanoparticles confined within crystalline
nanoporous materials: a fascinating class of nanocatalysts. Adv Mater 31:1–23. https://doi.
org/10.1002/adma.201803966
71. Wu X-F, Anbarasan P, Neumann H, Beller M (2010) From noble metal to nobel prize: palladiumcatalyzed coupling reactions as key methods in organic synthesis. Angew Chemie, Int Ed
49:9047–9050. https://doi.org/10.1002/anie.201006374
72. Yang Y, Reber AC, Gilliland SE et al (2018) Donor/acceptor concepts for developing efficient
suzuki cross-coupling catalysts using graphene-supported Ni, Cu, Fe, Pd, and Bimetallic Pd/Ni
Clusters. J Phys Chem C 122:25396–25403. https://doi.org/10.1021/acs.jpcc.8b07538
73. Zea H, Lester K, Datye AK et al (2005) The influence of Pd-Ag catalyst restructuring on the
activation energy for ethylene hydrogenation in ethylene-acetylene mixtures. Appl Catal A
Gen 282:237–245. https://doi.org/10.1016/j.apcata.2004.12.026
74. Zhai Y, Pierre D, Si R (2010) Alkali-stabilized Pt-OH<em><sub>x</sub
></em> species catalyze low-temperature water-gas shift reactions. Science (80)
329:1633 LP–1636. https://doi.org/10.1126/science.1192449
75. Zhang C, Laine RM (2000) Hydrosilylation of allyl alcohol with [HSiMe2OSiO1.5]8: Octa
(3-hydroxypropyldimethylsiloxy) octasilsesquioxane and its octamethacrylate derivative as
potential precursors to hybrid nanocomposites. J Am Chem Soc 122:6979–6988. https://doi.
org/10.1021/ja000318r
76. Zitoun D, Respaud M, Fromen M-C et al (2002) Magnetic enhancement in nanoscale corh
particles. Phys Rev Lett 89:37203. https://doi.org/10.1103/PhysRevLett.89.037203