36
J. Oliver–Meseguer and A. Leyva–Pérez
45. Mon M, Rivero-Crespo MA, Ferrando-Soria J et al (2018) synthesis of densely packaged,
ultrasmall Pt02 clusters within a thioether-functionalized mof: catalytic activity in industrial
reactions at low temperature. Angew Chemie, Int Ed 57:6186–6191. https://doi.org/10.1002/
anie.201801957
46. Murahashi T, Fujimoto M, Oka M (2006) discrete sandwich compounds of monolayer
palladium sheets. Science (80) 313:1104 LP–1107. https://doi.org/10.1126/science.1125245
47. Murahashi T, Kato N, Uemura T, Kurosawa H (2007) Rearrangement of a Pd4 skeleton from a
1D chain to a 2D sheet on the face of a perylene or fluoranthene ligand caused by exchange of
the binder molecule. Angew Chemie Int Ed 46:3509–3512. https://doi.org/10.1002/anie.200
700340
48. Murahashi T, Uemura T, Kurosawa H (2003) Perylene − Tetrapalladium Sandwich Complexes.
J Am Chem Soc 125:8436–8437. https://doi.org/10.1021/ja0358246
49. Oliver-Meseguer J, Cabrero-Antonino JR, Dominguez I (2012) Small gold clusters formed in
solution give reaction turnover numbers of 107 at room temperature. Sci (Washington, DC,
United States) 338:1452–1455. https://doi.org/10.1126/science.1227813
50. Oliver-Meseguer J, Dominguez I, Gavara R (2017) The wet synthesis and quantification of
ligand-free sub-nanometric Au clusters in solid matrices. Chem Commun (Cambridge, United
Kingdom) 53:1116–1119. https://doi.org/10.1039/C6CC09119A
51. Oliver-Meseguer J, Dominguez I, Gavara R et al (2017) Disassembling Metal Nanocrystallites
into Sub-nanometric Clusters and Low-faceted Nanoparticles for Multisite Catalytic Reactions.
Chem Cat Chem 9:1429–1435. https://doi.org/10.1002/cctc.201700037
52. Oliver-Meseguer J, Leyva-Perez A, Al-Resayes SI, Corma A (2013) Formation and stability
of 3–5 atom gold clusters from gold complexes during the catalytic reaction: dependence on
ligands and counteranions. Chem Commun (Cambridge, United Kingdom) 49:7782–7784.
https://doi.org/10.1039/c3cc44104k
53. Oliver-Meseguer J, Leyva-Perez A, Corma A (2013) Very small (3–6 atoms) gold cluster
catalyzed carbon-carbon and carbon-heteroatom bond-forming reactions in solution. Chem
Cat Chem 5:3509–3515. https://doi.org/10.1002/cctc.201300695
54. Oliver-Meseguer J, Liu L, Garcia-Garcia S et al (2015) Stabilized naked sub-nanometric cu clusters within a polymeric film catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions.
J Am Chem Soc 137:3894–3900. https://doi.org/10.1021/jacs.5b03889
55. Panyala RN, Pena-Mendez ME, Havel J (2009) Gold and nano-gold in medicine: overview,
toxicology and perspectives. J Appl Biomed 7:75–91
56. Pastoriza-Santos I, Liz-Marzan LM (1999) Formation and stabilization of silver nanoparticles through reduction by N, N-dimethylformamide. Langmuir 15:948–951. https://doi.org/
10.1021/LA980984U
57. Peredkov S, Peters S, Al-Hada M et al (2016) Structural investigation of supported Cun clusters under vacuum and ambient air conditions using EXAFS spectroscopy. Catal Sci Technol
6:6942–6952. https://doi.org/10.1039/C6CY00436A
58. Polozkov RG, Ivanov VK, Verkhovtsev AV (2013) New applications of the jellium model for
the study of atomic clusters. J. Phys. Conf. Ser. 438. https://doi.org/10.1088/1742-6596/438/
1/012009
59. Rivero-Crespo MA, Leyva-Pérez A, Corma A (2017) A ligand-free Pt 3 cluster catalyzes the
markovnikov hydrosilylation of alkynes with up to 10 6 turnover frequencies. Chem - A Eur J
23:1702–1708. https://doi.org/10.1002/chem.201605520
60. Rivero-Crespo MA, Mon M, Ferrando-Soria J et al (2018) Confined Pt11 + water clusters in
a MOF catalyze the low-temperature water-gas shift reaction with both CO 2 oxygen atoms
coming from water. Angew Chemie, Int Ed 57:17094–17099. https://doi.org/10.1002/anie.201
810251
61. Rubio-Marques P, Rivero-Crespo MA, Leyva-Perez A, Corma A (2015) Well-defined noble
metal single sites in zeolites as an alternative to catalysis by insoluble metal salts. J Am Chem
Soc 137:11832–11837. https://doi.org/10.1021/jacs.5b07304
62. Sa J, Frances S, Taylor R (2012) Redispersion of gold supported on oxides
J. Oliver–Meseguer and A. Leyva–Pérez
45. Mon M, Rivero-Crespo MA, Ferrando-Soria J et al (2018) synthesis of densely packaged,
ultrasmall Pt02 clusters within a thioether-functionalized mof: catalytic activity in industrial
reactions at low temperature. Angew Chemie, Int Ed 57:6186–6191. https://doi.org/10.1002/
anie.201801957
46. Murahashi T, Fujimoto M, Oka M (2006) discrete sandwich compounds of monolayer
palladium sheets. Science (80) 313:1104 LP–1107. https://doi.org/10.1126/science.1125245
47. Murahashi T, Kato N, Uemura T, Kurosawa H (2007) Rearrangement of a Pd4 skeleton from a
1D chain to a 2D sheet on the face of a perylene or fluoranthene ligand caused by exchange of
the binder molecule. Angew Chemie Int Ed 46:3509–3512. https://doi.org/10.1002/anie.200
700340
48. Murahashi T, Uemura T, Kurosawa H (2003) Perylene − Tetrapalladium Sandwich Complexes.
J Am Chem Soc 125:8436–8437. https://doi.org/10.1021/ja0358246
49. Oliver-Meseguer J, Cabrero-Antonino JR, Dominguez I (2012) Small gold clusters formed in
solution give reaction turnover numbers of 107 at room temperature. Sci (Washington, DC,
United States) 338:1452–1455. https://doi.org/10.1126/science.1227813
50. Oliver-Meseguer J, Dominguez I, Gavara R (2017) The wet synthesis and quantification of
ligand-free sub-nanometric Au clusters in solid matrices. Chem Commun (Cambridge, United
Kingdom) 53:1116–1119. https://doi.org/10.1039/C6CC09119A
51. Oliver-Meseguer J, Dominguez I, Gavara R et al (2017) Disassembling Metal Nanocrystallites
into Sub-nanometric Clusters and Low-faceted Nanoparticles for Multisite Catalytic Reactions.
Chem Cat Chem 9:1429–1435. https://doi.org/10.1002/cctc.201700037
52. Oliver-Meseguer J, Leyva-Perez A, Al-Resayes SI, Corma A (2013) Formation and stability
of 3–5 atom gold clusters from gold complexes during the catalytic reaction: dependence on
ligands and counteranions. Chem Commun (Cambridge, United Kingdom) 49:7782–7784.
https://doi.org/10.1039/c3cc44104k
53. Oliver-Meseguer J, Leyva-Perez A, Corma A (2013) Very small (3–6 atoms) gold cluster
catalyzed carbon-carbon and carbon-heteroatom bond-forming reactions in solution. Chem
Cat Chem 5:3509–3515. https://doi.org/10.1002/cctc.201300695
54. Oliver-Meseguer J, Liu L, Garcia-Garcia S et al (2015) Stabilized naked sub-nanometric cu clusters within a polymeric film catalyze C-N, C-C, C-O, C-S, and C-P Bond-Forming Reactions.
J Am Chem Soc 137:3894–3900. https://doi.org/10.1021/jacs.5b03889
55. Panyala RN, Pena-Mendez ME, Havel J (2009) Gold and nano-gold in medicine: overview,
toxicology and perspectives. J Appl Biomed 7:75–91
56. Pastoriza-Santos I, Liz-Marzan LM (1999) Formation and stabilization of silver nanoparticles through reduction by N, N-dimethylformamide. Langmuir 15:948–951. https://doi.org/
10.1021/LA980984U
57. Peredkov S, Peters S, Al-Hada M et al (2016) Structural investigation of supported Cun clusters under vacuum and ambient air conditions using EXAFS spectroscopy. Catal Sci Technol
6:6942–6952. https://doi.org/10.1039/C6CY00436A
58. Polozkov RG, Ivanov VK, Verkhovtsev AV (2013) New applications of the jellium model for
the study of atomic clusters. J. Phys. Conf. Ser. 438. https://doi.org/10.1088/1742-6596/438/
1/012009
59. Rivero-Crespo MA, Leyva-Pérez A, Corma A (2017) A ligand-free Pt 3 cluster catalyzes the
markovnikov hydrosilylation of alkynes with up to 10 6 turnover frequencies. Chem - A Eur J
23:1702–1708. https://doi.org/10.1002/chem.201605520
60. Rivero-Crespo MA, Mon M, Ferrando-Soria J et al (2018) Confined Pt11 + water clusters in
a MOF catalyze the low-temperature water-gas shift reaction with both CO 2 oxygen atoms
coming from water. Angew Chemie, Int Ed 57:17094–17099. https://doi.org/10.1002/anie.201
810251
61. Rubio-Marques P, Rivero-Crespo MA, Leyva-Perez A, Corma A (2015) Well-defined noble
metal single sites in zeolites as an alternative to catalysis by insoluble metal salts. J Am Chem
Soc 137:11832–11837. https://doi.org/10.1021/jacs.5b07304
62. Sa J, Frances S, Taylor R (2012) Redispersion of gold supported on oxides