12 Ligand Effects in Ruthenium Nanoparticle Catalysis
445
catalyst operating by a substrate-dependent dual site mechanism. Dalton Trans 40:10621–
10632
35. Fang M, Sánchez-Delgado RA (2014) Ruthenium nanoparticles supported on magnesium
oxide: a versatile and recyclable dual-site catalyst for hydrogenation of mono- and poly-cyclic
arenes, N-heteroaromatics, and S-heteroaromatics. J Catal 311:357–368
36. Martínez-Prieto LM, Puche M, Cerezo-Navarrete C, Chaudret B (2019) Uniform Ru nanoparticles on N-doped graphene for selective hydrogenation of fatty acids to alcohols. J Catal
77:429–437
37. Axet MR, Conejero S, Gerber IC (2018) Ligand effects on the selective hydrogenation of
nitrobenzene to cyclohexylamine using ruthenium nanoparticles as catalysts. ACS Appl Nano
Mater 1:5885–5894
38. Kurihara LK, Chow GM, Schoen PE (1995) Nanocrystalline metallic powders and films
produced by the polyol method. Nanostruct Mater 5:607–613
39. Tran T-H, Nguyen T-D (2011) Controlled growth of uniform noble metal nanocrystals: aqueousbased synthesis and some applications in biomedicine. Coll Surf B 88:1–22
40. Vidoni O, Philippot K, Amiens C, Chaudret B, Balmes O, Malm J-O, Bovin J-O, Senoq F,
Casanove M-J (1999) Novel, spongelike ruthenium particles of controllable size stabilized
only by organic solvents. Angew Chem Int Ed 38:3736–3738
41. Pelzer K, Vidoni O, Philippot K, Chaudret B, Collière V (2003) Organometallic synthesis of
size-controlled polycrystalline ruthenium nanoparticles in the presence of alcohols. Adv Funct
Mat 13:118–126
42. Martínez-Prieto LM, Carenco S, Wu CH, Bonnefille E, Axnanda S, Liu Z, Fazzini PF, Philippot
K, Salmeron M, Chaudret B (2014) Organometallic ruthenium nanoparticles as model catalysts
for CO hydrogenation: a nuclear magnetic resonance and ambient-pressure x-ray photoelectron
spectroscopy study. ACS Catal 4:3160–3168
43. Pelzer K, Philippot K, Chaudret B (2003) Z Phys Chem 217:1539–1548
44. Nowicki A, Zhang Y, Léger B, Rolland J-P, Bricout H, Monflier E, Roucoux A (2006)
Supramolecular shuttle and protective agent: a multiple role of methylated in the chemoselective hydrogenation of benzene derivatives with ruthenium nanoparticles. Chem Commun:
296–298
45. Chau NTT, Handjani S, Guegan J-P, Guerrero M, Monflier E, Philippot K, Denicourt-Nowicki
A, Roucoux A (2013) Methylated β-cyclodextrin-capped ruthenium nanoparticles: synthesis strategies, characterization, and application in hydrogenation reactions. ChemCatChem
5:1497–1503
46. González-Gómez R, Cusinato L, Bijani C, Coppel Y, Lecante P, Amiens C, del Rosal I, Philippot K, Poteau R (2019) Carboxylic acid-capped ruthenium nanoparticles: experimental and
theoretical case study with ethanoic acid. Nanoscale 11:9392–9409
47. Wang J, Feng J, Qin R, Fu H, Yuan M, Chen H, Li X (2007) Asymmetric hydrogenation
of aromatic ketones catalyzed by achiral monophosphine TPPTS-stabilized Ru. Tetrahedron
Asymmetry 18:1643–1647
48. García-Antón J, Axet MR, Jansat S, Philippot K, Chaudret B, Pery T, Buntkowsky G, Limbach
HH (2008) Reactions of olefins with ruthenium hydride nanoparticles: nmr characterization,
hydride titration, and room-temperature C-C bond activation. Angew Chem Int Ed 47:2074–
2078
49. Novio F, Monahan D, Coppel Y, Antorrena G, Lecante P, Philippot K, Chaudret B (2014)
Surface chemistry on small ruthenium nanoparticles: evidence for site selective reactions and
influence of ligands. Chem Eur J 20:1287–1297
50. Bonnefille E, Novio F, Gutmann T, Poteau R, Lecante P, Jumas J-C, Philippot K, Chaudret B
(2014) a way to tune selectivity in hydrogenation reaction. Nanoscale 6:9806–9816
51. Rothermel N, Röther T, Ayvalı T, Martínez-Prieto LM, Philippot K, Limbach H-H, Chaudret B, Gutmann T, Buntkowsky G (2019) Reactions of D2 with 1,4-butane-stabilized metal
nanoparticles-a combined gas-phase NMR, GC-MS and solid-state NMR study. ChemCatChem
11:1465–1471
445
catalyst operating by a substrate-dependent dual site mechanism. Dalton Trans 40:10621–
10632
35. Fang M, Sánchez-Delgado RA (2014) Ruthenium nanoparticles supported on magnesium
oxide: a versatile and recyclable dual-site catalyst for hydrogenation of mono- and poly-cyclic
arenes, N-heteroaromatics, and S-heteroaromatics. J Catal 311:357–368
36. Martínez-Prieto LM, Puche M, Cerezo-Navarrete C, Chaudret B (2019) Uniform Ru nanoparticles on N-doped graphene for selective hydrogenation of fatty acids to alcohols. J Catal
77:429–437
37. Axet MR, Conejero S, Gerber IC (2018) Ligand effects on the selective hydrogenation of
nitrobenzene to cyclohexylamine using ruthenium nanoparticles as catalysts. ACS Appl Nano
Mater 1:5885–5894
38. Kurihara LK, Chow GM, Schoen PE (1995) Nanocrystalline metallic powders and films
produced by the polyol method. Nanostruct Mater 5:607–613
39. Tran T-H, Nguyen T-D (2011) Controlled growth of uniform noble metal nanocrystals: aqueousbased synthesis and some applications in biomedicine. Coll Surf B 88:1–22
40. Vidoni O, Philippot K, Amiens C, Chaudret B, Balmes O, Malm J-O, Bovin J-O, Senoq F,
Casanove M-J (1999) Novel, spongelike ruthenium particles of controllable size stabilized
only by organic solvents. Angew Chem Int Ed 38:3736–3738
41. Pelzer K, Vidoni O, Philippot K, Chaudret B, Collière V (2003) Organometallic synthesis of
size-controlled polycrystalline ruthenium nanoparticles in the presence of alcohols. Adv Funct
Mat 13:118–126
42. Martínez-Prieto LM, Carenco S, Wu CH, Bonnefille E, Axnanda S, Liu Z, Fazzini PF, Philippot
K, Salmeron M, Chaudret B (2014) Organometallic ruthenium nanoparticles as model catalysts
for CO hydrogenation: a nuclear magnetic resonance and ambient-pressure x-ray photoelectron
spectroscopy study. ACS Catal 4:3160–3168
43. Pelzer K, Philippot K, Chaudret B (2003) Z Phys Chem 217:1539–1548
44. Nowicki A, Zhang Y, Léger B, Rolland J-P, Bricout H, Monflier E, Roucoux A (2006)
Supramolecular shuttle and protective agent: a multiple role of methylated in the chemoselective hydrogenation of benzene derivatives with ruthenium nanoparticles. Chem Commun:
296–298
45. Chau NTT, Handjani S, Guegan J-P, Guerrero M, Monflier E, Philippot K, Denicourt-Nowicki
A, Roucoux A (2013) Methylated β-cyclodextrin-capped ruthenium nanoparticles: synthesis strategies, characterization, and application in hydrogenation reactions. ChemCatChem
5:1497–1503
46. González-Gómez R, Cusinato L, Bijani C, Coppel Y, Lecante P, Amiens C, del Rosal I, Philippot K, Poteau R (2019) Carboxylic acid-capped ruthenium nanoparticles: experimental and
theoretical case study with ethanoic acid. Nanoscale 11:9392–9409
47. Wang J, Feng J, Qin R, Fu H, Yuan M, Chen H, Li X (2007) Asymmetric hydrogenation
of aromatic ketones catalyzed by achiral monophosphine TPPTS-stabilized Ru. Tetrahedron
Asymmetry 18:1643–1647
48. García-Antón J, Axet MR, Jansat S, Philippot K, Chaudret B, Pery T, Buntkowsky G, Limbach
HH (2008) Reactions of olefins with ruthenium hydride nanoparticles: nmr characterization,
hydride titration, and room-temperature C-C bond activation. Angew Chem Int Ed 47:2074–
2078
49. Novio F, Monahan D, Coppel Y, Antorrena G, Lecante P, Philippot K, Chaudret B (2014)
Surface chemistry on small ruthenium nanoparticles: evidence for site selective reactions and
influence of ligands. Chem Eur J 20:1287–1297
50. Bonnefille E, Novio F, Gutmann T, Poteau R, Lecante P, Jumas J-C, Philippot K, Chaudret B
(2014) a way to tune selectivity in hydrogenation reaction. Nanoscale 6:9806–9816
51. Rothermel N, Röther T, Ayvalı T, Martínez-Prieto LM, Philippot K, Limbach H-H, Chaudret B, Gutmann T, Buntkowsky G (2019) Reactions of D2 with 1,4-butane-stabilized metal
nanoparticles-a combined gas-phase NMR, GC-MS and solid-state NMR study. ChemCatChem
11:1465–1471