444
L. M. Martínez-Prieto and P. W. N. M. van Leeuwen
15. Mourdikoudis S, Liz-Marzán LM (2013) Nanoparticle synthesis. Chem Mat 25:1465–1476
16. Can H, Metin Ö (2012) A facile synthesis of nearly monodisperse ruthenium nanoparticles and
their catalysis in the hydrolytic dehydrogenation of ammonia borane for chemical hydrogen
storage. App Catal B Env 125:304–310
17. Lee JY, Yang J, Deivaraj TC, Too H-P (2003) A novel synthesis route for—protected ruthenium
nanoparticles. J Colloid Interface Sci 268:77–80
18. Pan C, Pelzer K, Philippot K, Chaudret B, Dassenoy F, Lecante P, Casanove M-J (2001) Ligandstabilized ruthenium nanoparticles: synthesis, organization, and dynamics. J Am Chem Soc
123:7584–7593
19. Watt J, Yu C, Chang SLY, Cheong S, Tilley RD (2013) Shape control from thermodynamic
growth conditions: the case of hcp ruthenium hourglass nanocrystals. J Am Chem Soc 135:606–
609
20. Lignier P, Bellabarba R, Tooze RP, Su Z, Landon P, Ménard H, Zhou W (2012) Facile synthesis
of branched ruthenium nanocrystals and their use in catalysis. Cryst Growth Des 12:939–942
21. Zahmakıran M, Tristany M, Philippot K, Fajerwerg K, Özkar S, Chaudret B (2010) Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine–borane. Chem Commun
46:2938–2940
22. Zahmakıran M, Philippot K, Özkar S, Chaudret B (2012) Stabilized ruthenium(0) nanoparticles
catalyst for the dehydrogenation of dimethylamine–borane at room temperature. Dalton Trans
41:590–598
23. Tristany M, Philippot K, Guari Y, Collière V, Lecante P, Chaudret B (2010) Synthesis of composite ruthenium-containing silica nanomaterials from amine-stabilized ruthenium nanoparticles
as elemental bricks. J Mat Chem 20:9523–9530
24. Salas G, Santini CC, Philippot K, Colliere V, Chaudret B, Fenet B, Fazzini PF (2011) Influence
of amines on the size control of in situ synthesized ruthenium nanoparticles in imidazolium
ionic liquids. Dalton Trans 40:4660–4668
25. Salas G, Campbell PS, Santini CC, Philippot K, Costa GMF, Padua AAH (2012) Ligand effect
on the catalytic activity of ruthenium nanoparticles. Dalton Trans 41:13919–13926
26. Chau NTT, Guegan J-P, Menuel S, Guerrero M, Hapiot F, Monflier E, Philippot K, DenicourtNowicki A, Roucoux A (2013) β-Cyclodextrins grafted with chiral amino acids: a promising
supramolecular stabilizer of nanoparticles for? Appl Catal A 467:497–503
27. Favier I, Massou S, Teuma E, Philippot K, Chaudret B, Gomez M (2008) A new and specific
mode of stabilization of metallic nanoparticles. Chem Commun: 3296–3298
28. Creus J, Drouet S, Surinach S, Lecante P, Colliere V, Poteau R, Philippot K, Garcia-Anton
J, Sala X (2018) Ligand-capped Ru nanoparticles as efficient electrocatalyst for the hydrogen
evolution reaction. ACS Catal 8:11094–11102
29. Jansat S, Picurelli D, Pelzer K, Philippot K, Gomez M, Muller G, Lecante P, Chaudret B (2006)
Synthesis, characterization and catalytic reactivity of ruthenium nanoparticles stabilized by
chiral N-donor ligands. New J Chem 30:115–122
30. Martinez-Prieto LM, Urbaneja C, Palma P, Campora J, Philippot K, Chaudret B (2015) A
betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce
ultra-small ruthenium nanoparticles. Chem Commun 51:4647–4650
31. Novio F, Philippot K, Chaudret B (2010) Location and Dynamics of CO Co-ordination on Ru
Nanoparticles: a study. Catal Lett 140:1–7
32. Martinez-Prieto LM, Cano I, Marquez A, Baquero EA, Tricard S, Cusinato L, del Rosal I, Poteau
R, Coppel Y, Philippot K, Chaudret B, Campora J, van Leeuwen PWNM (2017) Zwitterionic
amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts. Chem Sci
8:2931–2941
33. López-Vinasco AM, Martínez-Prieto LM, Asensio JM, Lecante P, Chaudret B, Cámpora J,
van Leeuwen PWNM (2020) Magnetic and recyclable Ni nanoparticles for selective semihydrogenation of alkynes to (Z)-alkenes. Catal Sci Tech 10:342–350
34. Fang M, Machalaba N, Sanchez-Delgado RA (2011) Hydrogenation of arenes and Nheteroaromatic compounds over ruthenium nanoparticles on poly(4-vinylpyridine): a versatile
L. M. Martínez-Prieto and P. W. N. M. van Leeuwen
15. Mourdikoudis S, Liz-Marzán LM (2013) Nanoparticle synthesis. Chem Mat 25:1465–1476
16. Can H, Metin Ö (2012) A facile synthesis of nearly monodisperse ruthenium nanoparticles and
their catalysis in the hydrolytic dehydrogenation of ammonia borane for chemical hydrogen
storage. App Catal B Env 125:304–310
17. Lee JY, Yang J, Deivaraj TC, Too H-P (2003) A novel synthesis route for—protected ruthenium
nanoparticles. J Colloid Interface Sci 268:77–80
18. Pan C, Pelzer K, Philippot K, Chaudret B, Dassenoy F, Lecante P, Casanove M-J (2001) Ligandstabilized ruthenium nanoparticles: synthesis, organization, and dynamics. J Am Chem Soc
123:7584–7593
19. Watt J, Yu C, Chang SLY, Cheong S, Tilley RD (2013) Shape control from thermodynamic
growth conditions: the case of hcp ruthenium hourglass nanocrystals. J Am Chem Soc 135:606–
609
20. Lignier P, Bellabarba R, Tooze RP, Su Z, Landon P, Ménard H, Zhou W (2012) Facile synthesis
of branched ruthenium nanocrystals and their use in catalysis. Cryst Growth Des 12:939–942
21. Zahmakıran M, Tristany M, Philippot K, Fajerwerg K, Özkar S, Chaudret B (2010) Aminopropyltriethoxysilane stabilized ruthenium(0) nanoclusters as an isolable and reusable heterogeneous catalyst for the dehydrogenation of dimethylamine–borane. Chem Commun
46:2938–2940
22. Zahmakıran M, Philippot K, Özkar S, Chaudret B (2012) Stabilized ruthenium(0) nanoparticles
catalyst for the dehydrogenation of dimethylamine–borane at room temperature. Dalton Trans
41:590–598
23. Tristany M, Philippot K, Guari Y, Collière V, Lecante P, Chaudret B (2010) Synthesis of composite ruthenium-containing silica nanomaterials from amine-stabilized ruthenium nanoparticles
as elemental bricks. J Mat Chem 20:9523–9530
24. Salas G, Santini CC, Philippot K, Colliere V, Chaudret B, Fenet B, Fazzini PF (2011) Influence
of amines on the size control of in situ synthesized ruthenium nanoparticles in imidazolium
ionic liquids. Dalton Trans 40:4660–4668
25. Salas G, Campbell PS, Santini CC, Philippot K, Costa GMF, Padua AAH (2012) Ligand effect
on the catalytic activity of ruthenium nanoparticles. Dalton Trans 41:13919–13926
26. Chau NTT, Guegan J-P, Menuel S, Guerrero M, Hapiot F, Monflier E, Philippot K, DenicourtNowicki A, Roucoux A (2013) β-Cyclodextrins grafted with chiral amino acids: a promising
supramolecular stabilizer of nanoparticles for? Appl Catal A 467:497–503
27. Favier I, Massou S, Teuma E, Philippot K, Chaudret B, Gomez M (2008) A new and specific
mode of stabilization of metallic nanoparticles. Chem Commun: 3296–3298
28. Creus J, Drouet S, Surinach S, Lecante P, Colliere V, Poteau R, Philippot K, Garcia-Anton
J, Sala X (2018) Ligand-capped Ru nanoparticles as efficient electrocatalyst for the hydrogen
evolution reaction. ACS Catal 8:11094–11102
29. Jansat S, Picurelli D, Pelzer K, Philippot K, Gomez M, Muller G, Lecante P, Chaudret B (2006)
Synthesis, characterization and catalytic reactivity of ruthenium nanoparticles stabilized by
chiral N-donor ligands. New J Chem 30:115–122
30. Martinez-Prieto LM, Urbaneja C, Palma P, Campora J, Philippot K, Chaudret B (2015) A
betaine adduct of N-heterocyclic carbene and carbodiimide, an efficient ligand to produce
ultra-small ruthenium nanoparticles. Chem Commun 51:4647–4650
31. Novio F, Philippot K, Chaudret B (2010) Location and Dynamics of CO Co-ordination on Ru
Nanoparticles: a study. Catal Lett 140:1–7
32. Martinez-Prieto LM, Cano I, Marquez A, Baquero EA, Tricard S, Cusinato L, del Rosal I, Poteau
R, Coppel Y, Philippot K, Chaudret B, Campora J, van Leeuwen PWNM (2017) Zwitterionic
amidinates as effective ligands for platinum nanoparticle hydrogenation catalysts. Chem Sci
8:2931–2941
33. López-Vinasco AM, Martínez-Prieto LM, Asensio JM, Lecante P, Chaudret B, Cámpora J,
van Leeuwen PWNM (2020) Magnetic and recyclable Ni nanoparticles for selective semihydrogenation of alkynes to (Z)-alkenes. Catal Sci Tech 10:342–350
34. Fang M, Machalaba N, Sanchez-Delgado RA (2011) Hydrogenation of arenes and Nheteroaromatic compounds over ruthenium nanoparticles on poly(4-vinylpyridine): a versatile