296
A. Palazzolo et al.
Fig. 9.20 Activities of RuNPs@NHC on enantiospecific deuteration of L-lysine as a function of
Ph [64]
of deuterium was observed on alcohols at the OH group’s α position compared to
amines. A mechanism similar to that proposed by Taglang et al. was presented.
The influence of introduction of Pt atoms at the surface of Ru NPs was studied by
Bouzouita et al. [66]. In this work, the authors prepared several RuPt NPs (Fig. 9.21)
and studied the influence of the Pt precursor on the surface composition and therefore
on the catalytic reactivity of the NPs. The exchange of Ru atoms by Pt led to a
decrease in the reaction rate of the H/D exchange in the α position of L-lysine
Fig. 9.21 Water-soluble Ru-Pt nanoparticles synthesis [66]. Reprinted with permission from Ref.
[66]. Copyright 2019 Royal Society of Chemistry
A. Palazzolo et al.
Fig. 9.20 Activities of RuNPs@NHC on enantiospecific deuteration of L-lysine as a function of
Ph [64]
of deuterium was observed on alcohols at the OH group’s α position compared to
amines. A mechanism similar to that proposed by Taglang et al. was presented.
The influence of introduction of Pt atoms at the surface of Ru NPs was studied by
Bouzouita et al. [66]. In this work, the authors prepared several RuPt NPs (Fig. 9.21)
and studied the influence of the Pt precursor on the surface composition and therefore
on the catalytic reactivity of the NPs. The exchange of Ru atoms by Pt led to a
decrease in the reaction rate of the H/D exchange in the α position of L-lysine
Fig. 9.21 Water-soluble Ru-Pt nanoparticles synthesis [66]. Reprinted with permission from Ref.
[66]. Copyright 2019 Royal Society of Chemistry