112
M. I. Qadir et al.
Table 4.1
(continued)
Entry
IL
Metallic precursor
Reducing agent
NPs
Size (nm)
References
21
IL
PEG750
RhCl
3 .H
2 O
H
2
Rh
1.3
± 0.2
[33]
22
BMIm.PF
6
Pt
2 (dba)
3
H
2
Pt
2.0–2.5
[17]
23
BMIm.PF
6
PtO
3
H
2
Pt
2.3
± 0.3
[34]
24
BMIm.BF
4
Pd(acac)
2
H
2
Pd
4.9
± 0.8
[35]
25
BMIm.PF
6
Pd(cod)Cl
2
H
2
Pd
6–8
[36]
26
BMIm.NTf
2
Ni(cod)
2
H
2
Ni
5.9
± 1.4
[37]
27
BMIm.BF
4
Ni(cod)
2
H
2
Ni
5.1
± 1.2
[37]
28
C
1 C
8 Im.NTf
2
Ni(cod)
2
H
2
Ni
5.6
± 1.3
[38]
29
C
1 C
10 Im.NTf
2
Ni(cod)
2
H
2
Ni
4.9
± 0.9
[38]
30
C
1 C
14 Im.NTf
2
Ni(cod)
2
H
2
Ni
5.1
± 0.9
[38]
31
C
1 C
16 Im.NTf
2
Ni(cod)
2
H
2
Ni
5.5
± 1.1
[38]
32
BMIm.NTf
2
Fe(cod)
2
H
2
FeO
5.3
± 1.6
[39]
33
BMIm.PF
6
Co(Cp)
2 /Pt
2 (dba)
3
H
2
Co/Pt
4.4
± 1.9
[40]
34
BMIm.PF
6
Ru(cod)(methylallyl)
2 /Pt
2 (dba)
3
H
2
Ru/Pt
2.9
± 0.2
[41]
35
BMIm.NTf
2
Fe(CO)
5 /Pt
2 (dba)
3
H
2
Fe/Pt
1.7
± 0.2
[42]
36
BMIm.PF
6
Fe(CO)
5 /Pt
2 (dba)
3
H
2
Fe/Pt
1.8
± 0.23
[42]
37
BMIm.BF
4
Fe(CO)
5 /Pt
2 (dba)
3
H
2
Fe/Pt
2.5
± 0.4
[42]
38
BMIm.NTf
2
Ru(cod)(methylallyl)
2 /Fe(CO)
5
H
2
Ru/Fe
1.7
± 0.3
[20]
39
BMIm.NTf
2
Ru(cod)(methylallyl)
2 /Ni(cod)
2
H
2
Ru/Ni
2.4
± 0.7
[43]
DMIm
= 1-n-decyl-3-methylimidazolium; IL
PEG750
= N,N-dimethyl-N-(2-(2-methoxyethoxy)ethyl)-N-(2-(2-octyloxyethoxy)ethyl)ammonium
methanesulfonate; dba
= dibenzylidene acetone; acac
= acetylacetonate; Cp
= bis(cylopentadienyl)