426
Solvent-borne PU synthesis
prepolymer method
DBTDL, 181
diisocyanate, 181
quasiprepolymer method
NCO/OH ratio, 181
one-shot method, 181
Sonication, 109
Starch nanocrystals, 106
Steam explosion lignin (SE), 74
Stereolithographic/selective laser sintering, 295
Structure-activity relationship
BDE, 70, 71
carboxylic and alcohol groups, 69
DPPH• free radicals, 67, 70
phenolic hydroxyl groups, 69
phenylpropane units, 70
radical scavenging mechanism, 67
SPLET mechanism, 70
structural characteristics, 68
Sugarcane bagasse lignin (BG), 74
Sunscreen agents, 75
Super Ball Show, 224
Superspreaders, 317
Supramolecular polymers, 255
Surface relief grating (SRG), 272
Surfactants
agriculture, 262
amphiphilic siloxanes, 263
carbohydrate, 262
carbohydrate-containing
cyclosiloxane, 263
carbon nanotubes, 263
characteristics, 262
diblock, 319
gemini, 318
hyaluronan, 319
hydrophobic, 262
Mw, 318
nano-aggregates, 261
oleophobic properties, 262
oligo(ethylene oxide)trisiloxanes, 317
oligosiloxane, 317, 318
organic moieties, 262
polysiloxane functionalization, 262
preparation, PU foams, 319
self-assembly, vesicles, 262
silicone-polyol copolymers, 319
structures, 317
surface active materials, 262, 263
tetrasiloxane Gemini imidazolium, 262
Sustainable Moulding of Articles from
Recycled Tires (SMART) project, 49
Synthetic antioxidants, 66
T
Terephthalic acid, 164
Tetrachlorosilane (SiCl 4 ), 212
Tetrahydrofuran (THF), 174
2,2,6,6-Tetramethyl-1-piperidynyl-N-oxy
(TEMPO), 29
Thermal oxidation stabilizer
aminolysis, 82, 83
KL structures, 82
lignin/polymer mixtures, 82
NR, 83
PE/lignin mixtures, 82
Thermal stability, 304
Thermoplastic polymers, 296
Thermoplastic starch (TPS), 97
Thiol-ene click reaction, 243, 245
Thixotropy, 221
Three-dimensional (3D) printing
additive manufacturing, 295
advantage, 295
anatomic molds, 296
automated manufacturing, 295
conventional industrial materials, 295
craniofacial reconstructions, 295
disadvantages, 295
elastomeric polymers, 296
extrudable silicone, 298
HTV silicones, 297
limitations, 295
maxillofacial, 295
medicine and dentistry, 295
mold making/duplication, 297
production material, 295
rapid prototyping, 295
RTV-silicone, 297
silicone, 296
silicone elastomers, 297
small and medium-scale applications, 295
SRs, 298
stereolithographic/selective laser
sintering, 295
thermoplastic polymers, 296
waste material, 295
Tissue-engineered nerve transplantation, 78
Titanium dioxide (TiO2), 75
2,6-Toluene diisocyanates (TDI), 178
Toxicity and cell damage, lignin
antioxidant, 74
carbohydrates, 75
cell cytotoxicity assay, 73
eye and skin irritation test, 74
fractions, 74
HHSteCs, 74
hMSCs, 74
Index
Solvent-borne PU synthesis
prepolymer method
DBTDL, 181
diisocyanate, 181
quasiprepolymer method
NCO/OH ratio, 181
one-shot method, 181
Sonication, 109
Starch nanocrystals, 106
Steam explosion lignin (SE), 74
Stereolithographic/selective laser sintering, 295
Structure-activity relationship
BDE, 70, 71
carboxylic and alcohol groups, 69
DPPH• free radicals, 67, 70
phenolic hydroxyl groups, 69
phenylpropane units, 70
radical scavenging mechanism, 67
SPLET mechanism, 70
structural characteristics, 68
Sugarcane bagasse lignin (BG), 74
Sunscreen agents, 75
Super Ball Show, 224
Superspreaders, 317
Supramolecular polymers, 255
Surface relief grating (SRG), 272
Surfactants
agriculture, 262
amphiphilic siloxanes, 263
carbohydrate, 262
carbohydrate-containing
cyclosiloxane, 263
carbon nanotubes, 263
characteristics, 262
diblock, 319
gemini, 318
hyaluronan, 319
hydrophobic, 262
Mw, 318
nano-aggregates, 261
oleophobic properties, 262
oligo(ethylene oxide)trisiloxanes, 317
oligosiloxane, 317, 318
organic moieties, 262
polysiloxane functionalization, 262
preparation, PU foams, 319
self-assembly, vesicles, 262
silicone-polyol copolymers, 319
structures, 317
surface active materials, 262, 263
tetrasiloxane Gemini imidazolium, 262
Sustainable Moulding of Articles from
Recycled Tires (SMART) project, 49
Synthetic antioxidants, 66
T
Terephthalic acid, 164
Tetrachlorosilane (SiCl 4 ), 212
Tetrahydrofuran (THF), 174
2,2,6,6-Tetramethyl-1-piperidynyl-N-oxy
(TEMPO), 29
Thermal oxidation stabilizer
aminolysis, 82, 83
KL structures, 82
lignin/polymer mixtures, 82
NR, 83
PE/lignin mixtures, 82
Thermal stability, 304
Thermoplastic polymers, 296
Thermoplastic starch (TPS), 97
Thiol-ene click reaction, 243, 245
Thixotropy, 221
Three-dimensional (3D) printing
additive manufacturing, 295
advantage, 295
anatomic molds, 296
automated manufacturing, 295
conventional industrial materials, 295
craniofacial reconstructions, 295
disadvantages, 295
elastomeric polymers, 296
extrudable silicone, 298
HTV silicones, 297
limitations, 295
maxillofacial, 295
medicine and dentistry, 295
mold making/duplication, 297
production material, 295
rapid prototyping, 295
RTV-silicone, 297
silicone, 296
silicone elastomers, 297
small and medium-scale applications, 295
SRs, 298
stereolithographic/selective laser
sintering, 295
thermoplastic polymers, 296
waste material, 295
Tissue-engineered nerve transplantation, 78
Titanium dioxide (TiO2), 75
2,6-Toluene diisocyanates (TDI), 178
Toxicity and cell damage, lignin
antioxidant, 74
carbohydrates, 75
cell cytotoxicity assay, 73
eye and skin irritation test, 74
fractions, 74
HHSteCs, 74
hMSCs, 74
Index