425
Self-healing silicone, 312
Sequential proton loss electron transfer
(SPLET) mechanism, 70
Silane monomers, 237, 238
Silane (SiH 4 ), 211
Silica NPs, 294
Silicate, 224
Silicones
antiflatulents, 227
aviation, 221
biocompatibility, 224, 225
chemical aging, 223
chemical structure, silicone rubber, 220
electronics, 221
energy silicone, 220
environmental effects, 227
epidemiology, 226
elastomers, 294
free flow agent, 222
hydrogel contact lenses, 266
hydrophilization, 316
manufacturing (see Manufacture of
silicones)
materials, 238, 273
medical field, 295
nanocomposites, 223, 224
PDMS, 227
personal care products, 220
pharmaceutical applications, 226
physical properties, 209–212
polysiloxanes, 208
printing, 296
putty, 310
recycling, 227
reinforcement, 222
Si-O-Si link, 208
sludge formation, 208
soils, 227
thermal aging resistance, 222
thermal isolation, 222
thickening and thixotropy, 221
weather resistance, 223
Silicone fluids, 208, 218, 219
Silicone rubbers (SRs), 219, 223, 224
Silicon nomenclature, 302, 303
Siloxane
backbiting degradation, 308
biocompatibility, 305
carbon-based polymers, 303
commercial use, 301, 306
crosslinking (see Crosslinking of siloxane
polymers)
daily routines, 301
diethyldichlorosilane, 305
difunctional monomers, polymerization, 309
direct method, 306, 307
environment, 305
functional monomers, 306
Grignard reaction, 306
hydridosilanes, 306
hydrochloric acid, 307
hydrophobic materials, 304
inherently reactive materials,
320, 321
ketone, 305
melting/crystallization, 304
monofunctional silanolate initiator, 308
Mw, 307, 308
PDMS, 303, 304, 308, 309
PDMS-co-PEG, 309, 310
PHMS, 309
physical properties, PDMS, 305
PIB, 303, 304
polycondensation
dichlorodialkylsilanes, 307, 308
silanediol, 307
polymerization techniques, 302
ROP, 308, 309
silane monomers, 306
silicon nomenclature, 302, 303
(see also Silicone)
thermal stability, 304
vinylsilanes, 306
viscosities, 305
zero-calorie oil substitutes, 305
Siloxane chemistry
‘click’ reaction, 316
hydrophobic, 316
Piers-Rubinsztajn reaction, 315
PVOH, 317
side-chains/end-groups, 315
silicone macroinitiators, 317
small molecules, 315
Siloxane surfactants, 265
Simultaneous enzymatic saccharification and
comminution (SESC), 80
Sludge formation, 208
Smart textiles, 22
Sodium hydroxide (NaOH), 174
Soft segments (SS), 173
Sol-gel materials, 266
Sol-gel process, 110
Solution-based techniques
LbL assembly, 108
LbL spinning techniques, 109
one-pot directed assembly, 108
rapid exfoliation, 108
thermal degradation temperatures, 108
Index
Self-healing silicone, 312
Sequential proton loss electron transfer
(SPLET) mechanism, 70
Silane monomers, 237, 238
Silane (SiH 4 ), 211
Silica NPs, 294
Silicate, 224
Silicones
antiflatulents, 227
aviation, 221
biocompatibility, 224, 225
chemical aging, 223
chemical structure, silicone rubber, 220
electronics, 221
energy silicone, 220
environmental effects, 227
epidemiology, 226
elastomers, 294
free flow agent, 222
hydrogel contact lenses, 266
hydrophilization, 316
manufacturing (see Manufacture of
silicones)
materials, 238, 273
medical field, 295
nanocomposites, 223, 224
PDMS, 227
personal care products, 220
pharmaceutical applications, 226
physical properties, 209–212
polysiloxanes, 208
printing, 296
putty, 310
recycling, 227
reinforcement, 222
Si-O-Si link, 208
sludge formation, 208
soils, 227
thermal aging resistance, 222
thermal isolation, 222
thickening and thixotropy, 221
weather resistance, 223
Silicone fluids, 208, 218, 219
Silicone rubbers (SRs), 219, 223, 224
Silicon nomenclature, 302, 303
Siloxane
backbiting degradation, 308
biocompatibility, 305
carbon-based polymers, 303
commercial use, 301, 306
crosslinking (see Crosslinking of siloxane
polymers)
daily routines, 301
diethyldichlorosilane, 305
difunctional monomers, polymerization, 309
direct method, 306, 307
environment, 305
functional monomers, 306
Grignard reaction, 306
hydridosilanes, 306
hydrochloric acid, 307
hydrophobic materials, 304
inherently reactive materials,
320, 321
ketone, 305
melting/crystallization, 304
monofunctional silanolate initiator, 308
Mw, 307, 308
PDMS, 303, 304, 308, 309
PDMS-co-PEG, 309, 310
PHMS, 309
physical properties, PDMS, 305
PIB, 303, 304
polycondensation
dichlorodialkylsilanes, 307, 308
silanediol, 307
polymerization techniques, 302
ROP, 308, 309
silane monomers, 306
silicon nomenclature, 302, 303
(see also Silicone)
thermal stability, 304
vinylsilanes, 306
viscosities, 305
zero-calorie oil substitutes, 305
Siloxane chemistry
‘click’ reaction, 316
hydrophobic, 316
Piers-Rubinsztajn reaction, 315
PVOH, 317
side-chains/end-groups, 315
silicone macroinitiators, 317
small molecules, 315
Siloxane surfactants, 265
Simultaneous enzymatic saccharification and
comminution (SESC), 80
Sludge formation, 208
Smart textiles, 22
Sodium hydroxide (NaOH), 174
Soft segments (SS), 173
Sol-gel materials, 266
Sol-gel process, 110
Solution-based techniques
LbL assembly, 108
LbL spinning techniques, 109
one-pot directed assembly, 108
rapid exfoliation, 108
thermal degradation temperatures, 108
Index