364
bonds (C=C, etc.) (Marciniec et al. 1992) for the preparation of comb-like polysiloxanes with different pendant groups, used as liquid-crystalline organosilicon
polymers (Finkelman 1987; Boileau and Teyssié 1991; Percec and Wang 1991,
1992; Madec and Maréchal 1993; Śledzińska et al.,1994; Białecka-Florjańczyk
et al. 1995; Caminade and Majoral 1995; Ruder et al. 1998), cosmetic ingredients, surfactants (Noll 1968; Hardman and Torkelson 1989), etc.
Other more important uses of PMHS are the following:
1. Synthesis of highly branched organosilicon polymers (dendrimers (Uchida et al.
1990; Morikawa et al. 1991, 1992; Van der Made and van Leeven 1992; Zhou
and Roovers 1993; Ruder et al. 1998; Yoon and Son 1999) and star polymers
(Zhou and Roovers 1993; Shim et al. 1998);
2. Grafting of macroinitiators (Kollefrath et al. 1996; Kickelbick et al. 1998), medicines (Bachrach and Zilkha 1984) and stabilizers (Rühlmann and Jansen 1985)
onto PMHS, preparation of silicone release coatings (Chruściel and Graczyk
2006), and interpenetrating polymer networks (IPNs) with good antiadhesive
(Wilczek 1993; Wilczek and Sun 1994; Dobkowski and Zielecka 1999; Zielecka
et al. 2000) and conductive properties (after dopping with salts) (Boileau
et al. 1998);
3. Preparation of solid polyelectrolytes (Oh et al. 2003) and biomaterials (Hron
et al. 1997; Chekina et al. 2006),
4. Synthesis of carbofunctional polysiloxanes from MH 2 D n (Greber and Jäger 1962);
5. Oxidation or hydrolysis of pendant Si-H groups and consecutive crosslinking of
preceramic polymers (West 1986; Chojnowski 1987; Laine and Babonneau
1993; Matyjaszewski 1998) and hydrophobic finishes on textiles (Rościszewski
1964; Noll 1968; Hardman and Torkelson 1989; Rościszewski and
Zielecka 2002);
6. Surface modification of inorganic fillers and supports (Cosgrove et al. 1990;
Reihs et al. 1995; Voliotis et al. 2003; Tertykh et al. 2003);
7. Modification of polymer properties (Bik et al. 2003; Chruściel et al. 2006;
Bieliński et al. 2007a, b; Chruściel and Leśniak 2012);
8. Reduction of organic compounds, e.g. aldehydes and ketones (Lopez and Fu
1997; Kobayashi 1998), alkenes (Miravet and Frechet 1997), nitro-compounds
(Lipowitz and Bowman 1973) or organic phosphorous esters (Fritzsche et al.
1964, 1965; Polmanteer et al. 1971; Segall et al. 1974).
PMHS are widely used as hydrophobic and antiadhesive, antifoaming (Noll
1968; Hardman and Torkelson 1989; Rościszewski and Zielecka 2002) and crosslinking agents (Noll 1968; McAfee 1985; Hardman and Torkelson 1989; Chang
et al. 1993; Michalczyk et al. 1993; Matsushita et al. 1994; Hara et al. 1994; White
1995; Chruściel 1999b; Rościszewski and Zielecka 2002; Bik et al. 2003; Chruściel
et al. 2006; Bieliński et al. 2007a, b), components for cosmetic materials and dental
composites (Hashimoto et al., 1994a). They are considered physiologically inert
(Ger. Pat. 3,416,694, 1985; Jap. Pat. 60,163,809; 1985, Hashimoto et al. 1994b;
Zielecka and Rościszewski 1994).
J. J. Chruściel
bonds (C=C, etc.) (Marciniec et al. 1992) for the preparation of comb-like polysiloxanes with different pendant groups, used as liquid-crystalline organosilicon
polymers (Finkelman 1987; Boileau and Teyssié 1991; Percec and Wang 1991,
1992; Madec and Maréchal 1993; Śledzińska et al.,1994; Białecka-Florjańczyk
et al. 1995; Caminade and Majoral 1995; Ruder et al. 1998), cosmetic ingredients, surfactants (Noll 1968; Hardman and Torkelson 1989), etc.
Other more important uses of PMHS are the following:
1. Synthesis of highly branched organosilicon polymers (dendrimers (Uchida et al.
1990; Morikawa et al. 1991, 1992; Van der Made and van Leeven 1992; Zhou
and Roovers 1993; Ruder et al. 1998; Yoon and Son 1999) and star polymers
(Zhou and Roovers 1993; Shim et al. 1998);
2. Grafting of macroinitiators (Kollefrath et al. 1996; Kickelbick et al. 1998), medicines (Bachrach and Zilkha 1984) and stabilizers (Rühlmann and Jansen 1985)
onto PMHS, preparation of silicone release coatings (Chruściel and Graczyk
2006), and interpenetrating polymer networks (IPNs) with good antiadhesive
(Wilczek 1993; Wilczek and Sun 1994; Dobkowski and Zielecka 1999; Zielecka
et al. 2000) and conductive properties (after dopping with salts) (Boileau
et al. 1998);
3. Preparation of solid polyelectrolytes (Oh et al. 2003) and biomaterials (Hron
et al. 1997; Chekina et al. 2006),
4. Synthesis of carbofunctional polysiloxanes from MH 2 D n (Greber and Jäger 1962);
5. Oxidation or hydrolysis of pendant Si-H groups and consecutive crosslinking of
preceramic polymers (West 1986; Chojnowski 1987; Laine and Babonneau
1993; Matyjaszewski 1998) and hydrophobic finishes on textiles (Rościszewski
1964; Noll 1968; Hardman and Torkelson 1989; Rościszewski and
Zielecka 2002);
6. Surface modification of inorganic fillers and supports (Cosgrove et al. 1990;
Reihs et al. 1995; Voliotis et al. 2003; Tertykh et al. 2003);
7. Modification of polymer properties (Bik et al. 2003; Chruściel et al. 2006;
Bieliński et al. 2007a, b; Chruściel and Leśniak 2012);
8. Reduction of organic compounds, e.g. aldehydes and ketones (Lopez and Fu
1997; Kobayashi 1998), alkenes (Miravet and Frechet 1997), nitro-compounds
(Lipowitz and Bowman 1973) or organic phosphorous esters (Fritzsche et al.
1964, 1965; Polmanteer et al. 1971; Segall et al. 1974).
PMHS are widely used as hydrophobic and antiadhesive, antifoaming (Noll
1968; Hardman and Torkelson 1989; Rościszewski and Zielecka 2002) and crosslinking agents (Noll 1968; McAfee 1985; Hardman and Torkelson 1989; Chang
et al. 1993; Michalczyk et al. 1993; Matsushita et al. 1994; Hara et al. 1994; White
1995; Chruściel 1999b; Rościszewski and Zielecka 2002; Bik et al. 2003; Chruściel
et al. 2006; Bieliński et al. 2007a, b), components for cosmetic materials and dental
composites (Hashimoto et al., 1994a). They are considered physiologically inert
(Ger. Pat. 3,416,694, 1985; Jap. Pat. 60,163,809; 1985, Hashimoto et al. 1994b;
Zielecka and Rościszewski 1994).
J. J. Chruściel