Index
A
Asymmetric flow field-flow fractionation
(AF4), 147
B
Branched UHM PEs, HT-AF4
aim, 155
equipment, 156–157
materials, 155–156
measurement and evaluation, 159–161
preliminary investigations, 157–159
SEC, 155
C
Column-based chromatographic techniques
Crystallization analysis fractionation
(CRYSTAF), 5–6
copolymers, 11
crystallization elution fractionation
complex polyolefin analysis, 67–70
vs. dynamic crystallization, 65–67
physical separation, 66, 67
crystallization process, 47
cumulative and differential profile,
48–49
Flory–Huggins statistical thermodynamic
treatment, 11
instrumentation, 47–48
PE/PP blend analysis
aim, 54
CRYSTAF analysis, 55–57
DSC analysis, 53, 55, 56
equipment, 54
HDPE and LDPE, 56–59
materials, 54
preparatory investigations, 54–55
PE–PP combinations, 49
Polymer Char, 47
propylene and higher α-olefin copolymer
analysis
aim and materials, 60, 61
CRYSTAF analysis, 63
DSC analysis, 62–63
equipment, 60–61
melting and crystallization
temperature, 63–65
TREF (see Temperature rising elution
fractionation (TREF))
D
Differential scanning calorimetry (DSC), 6
CRYSTAF
PE/PP blend analysis, 53, 55–56
propylene and higher α-olefin
copolymer analysis, 62–63
HyperDSC, 7
IPCs, 26
E
Ethylene-octene (EO) copolymers
aim, 22
equipment, 22
homogeneous
aim, 50
CRYSTAF calibration curve, 52–53
materials and equipment, 50
preparatory investigations, 50–51
materials, 22
measurement and evaluation, 23–25
preparatory investigations, 22–23
Ethylene–propylene (EP) copolymerization,
18–19
# Springer International Publishing Switzerland 2014
H. Pasch, M.I. Malik, Advanced Separation Techniques for Polyolefins, Springer
Laboratory, DOI 10.1007/978-3-319-08632-3
175
A
Asymmetric flow field-flow fractionation
(AF4), 147
B
Branched UHM PEs, HT-AF4
aim, 155
equipment, 156–157
materials, 155–156
measurement and evaluation, 159–161
preliminary investigations, 157–159
SEC, 155
C
Column-based chromatographic techniques
Crystallization analysis fractionation
(CRYSTAF), 5–6
copolymers, 11
crystallization elution fractionation
complex polyolefin analysis, 67–70
vs. dynamic crystallization, 65–67
physical separation, 66, 67
crystallization process, 47
cumulative and differential profile,
48–49
Flory–Huggins statistical thermodynamic
treatment, 11
instrumentation, 47–48
PE/PP blend analysis
aim, 54
CRYSTAF analysis, 55–57
DSC analysis, 53, 55, 56
equipment, 54
HDPE and LDPE, 56–59
materials, 54
preparatory investigations, 54–55
PE–PP combinations, 49
Polymer Char, 47
propylene and higher α-olefin copolymer
analysis
aim and materials, 60, 61
CRYSTAF analysis, 63
DSC analysis, 62–63
equipment, 60–61
melting and crystallization
temperature, 63–65
TREF (see Temperature rising elution
fractionation (TREF))
D
Differential scanning calorimetry (DSC), 6
CRYSTAF
PE/PP blend analysis, 53, 55–56
propylene and higher α-olefin
copolymer analysis, 62–63
HyperDSC, 7
IPCs, 26
E
Ethylene-octene (EO) copolymers
aim, 22
equipment, 22
homogeneous
aim, 50
CRYSTAF calibration curve, 52–53
materials and equipment, 50
preparatory investigations, 50–51
materials, 22
measurement and evaluation, 23–25
preparatory investigations, 22–23
Ethylene–propylene (EP) copolymerization,
18–19
# Springer International Publishing Switzerland 2014
H. Pasch, M.I. Malik, Advanced Separation Techniques for Polyolefins, Springer
Laboratory, DOI 10.1007/978-3-319-08632-3
175