CARBON-CARBON BOND FORMING REACTIONS
83
I.B.3-14 Luo, F.-T. and Hsieh, L.-C, TL, 35, 9585.
"
C 5
H 1 1
X
"
C 5
H 1 1
X
ί
O
TMSC1
\ = (
.0
R
rt
R
5-92%
I.B.3-15 Li, L.H., Wang, D., and Chan, T.H., OM, 13, 1757; Marek,
I., Normant, J.-F. et al., TL, 35, 6873.
Me
Me
'..OR
i. R»Cu
' O R
Si,
z ►
, / ^
S K
^
Me
2. R
2
X
R ^ ^ Y
Me
R
2
45-93%
I.B.3-16 Marco-Contelles, J. et al., JOC, 59, 1234; Ohta, A. et al., T,
50, 13575.
J
A c 0
~ \
/~
λ
Bu 3 SnH,AIBN
A c 0
-Γ)
\
/
U U 3 O I I I I , Λ Ι ϋ Π
\
t
ϊ
ί
Ph-Me
i
c
66%
I.B.3-17 Zakarya, D. et al., TL, 35, 2345.
TMSCH 2 .
CI Me
CHO
Me
OEt
V H O
\
C0 2 Et
60%
83
I.B.3-14 Luo, F.-T. and Hsieh, L.-C, TL, 35, 9585.
"
C 5
H 1 1
X
"
C 5
H 1 1
X
ί
O
TMSC1
\ = (
.0
R
rt
R
5-92%
I.B.3-15 Li, L.H., Wang, D., and Chan, T.H., OM, 13, 1757; Marek,
I., Normant, J.-F. et al., TL, 35, 6873.
Me
Me
'..OR
i. R»Cu
' O R
Si,
z ►
, / ^
S K
^
Me
2. R
2
X
R ^ ^ Y
Me
R
2
45-93%
I.B.3-16 Marco-Contelles, J. et al., JOC, 59, 1234; Ohta, A. et al., T,
50, 13575.
J
A c 0
~ \
/~
λ
Bu 3 SnH,AIBN
A c 0
-Γ)
\
/
U U 3 O I I I I , Λ Ι ϋ Π
\
t
ϊ
ί
Ph-Me
i
c
66%
I.B.3-17 Zakarya, D. et al., TL, 35, 2345.
TMSCH 2 .
CI Me
CHO
Me
OEt
V H O
\
C0 2 Et
60%