CARBON-CARBON BOND FORMING REACTIONS
I.A.7.a.3-37 Mori, M. et al., JOM, 464, 35.
47
Br 0
[Bu 3 SnSiMe 3 X]- R 4 N
+
*BnEt 3 NCl
74%
I.A.7.a.3-38 Imai, T. and Nishida, S., CC, 277; Shibasaki, M. et al.,
JOC, 59, 713.
Me
Ph ^^
CHO
+ J^
OMs
SnCI 2 »2H 2 0
►
C u I
OH Me
95% p h ^ S î ^ X / ^
similarly with (CO) 5 CrPhC0 2 Me
I.A.7.a.3-39 Liu, R.-S. et al., CC, 2705.
^ ^ L ^ C 0 2 H
1) RCHO, BF 3 .QEt 2
2) Me 3 NO
R
Me
W = W^-C 5 H 5 )(CO) 2
HO
50-56%
I.A.7.a.3-37 Mori, M. et al., JOM, 464, 35.
47
Br 0
[Bu 3 SnSiMe 3 X]- R 4 N
+
*BnEt 3 NCl
74%
I.A.7.a.3-38 Imai, T. and Nishida, S., CC, 277; Shibasaki, M. et al.,
JOC, 59, 713.
Me
Ph ^^
CHO
+ J^
OMs
SnCI 2 »2H 2 0
►
C u I
OH Me
95% p h ^ S î ^ X / ^
similarly with (CO) 5 CrPhC0 2 Me
I.A.7.a.3-39 Liu, R.-S. et al., CC, 2705.
^ ^ L ^ C 0 2 H
1) RCHO, BF 3 .QEt 2
2) Me 3 NO
R
Me
W = W^-C 5 H 5 )(CO) 2
HO
50-56%