CARBON-CARBON BOND FORMING REACTIONS
I.A.7.a.3-9 Shinkai, I. et al., PAC, 66, 1551.
37
R
0 2 Me
Q
MeMg[N(TMS) 2 ]2" Li
+
R
►
-10°C, THF
Me
88%
I.A.7.a.3-10 Comins, D.L. and LaMunyon, D.H., TL, 35, 7343.
Si'Pr 3
1) R^COCl
2) R
2 MgX
Si'Pra
CO2R
1
50-91%, 60-78% de
I.A.7.a.3-ll Moise, C. et al., TL, 35, 8613.
\
(n
5 -C5H 5 ) 2 T.ci* ^
R C H O >
|j
'PrMgCl, -50°C
PH
R
42-73% S ^ / S l
I.A.7.a.3-9 Shinkai, I. et al., PAC, 66, 1551.
37
R
0 2 Me
Q
MeMg[N(TMS) 2 ]2" Li
+
R
►
-10°C, THF
Me
88%
I.A.7.a.3-10 Comins, D.L. and LaMunyon, D.H., TL, 35, 7343.
Si'Pr 3
1) R^COCl
2) R
2 MgX
Si'Pra
CO2R
1
50-91%, 60-78% de
I.A.7.a.3-ll Moise, C. et al., TL, 35, 8613.
\
(n
5 -C5H 5 ) 2 T.ci* ^
R C H O >
|j
'PrMgCl, -50°C
PH
R
42-73% S ^ / S l