845
Complexation of Dissolved Organic Matter with Trace Metal Ions in Natural Waters
Simpson AJ, Kingery WL, Hayes MHB, Spraul M, Humpfer E, Dvortsak P, Kerssebaum R,
Godejohann M, Hofmann M (2002) Molecular structures and associations of humic substances in the terrestrial environment. Naturwissenschaften 89:84–88
Skoog A, Wedborg M, Fogelqvist E (1996) Photobleaching of fluorescence and the organic carbon concentration in a coastal environment. Mar Chem 55:333–345
Slawyk G, Raimbault P, Garcia N (1998) Measuring gross uptake of N-15-labeled nitrogen by
marine phytoplankton without particulate matter collection: evidence of low N-15 losses to
the dissolved organic nitrogen pool. Limnol Oceanogr 43:1734–1739
Slawyk G, Raimbault P, Garcia N (2000) Use of N-15 to measure dissolved organic nitrogen release by
marine phytoplankton (reply to comment by Bronk and Ward). Limnol Oceanogr 45:1884–1886
Martell AE, Smith, RM (1974) Critical stability constants. Plenum, New York
Smith DS, Kramer JR (1998) Multi-site aluminum speciation with natural organic matter using
multiresponse fluorescence data. Anal Chim Acta 363:21–29
Smith DS, Kramer JR (1999) Fluorescence analysis for multi-site aluminum binding to natural
organic matter. Environ Int 25:295–306
Smith RM, Martell AE (1987) Critical stability-constants, enthalpies and entropies for the formation of metal-complexes of Aminopolycarboxylic Acids and Carboxylic-Acids. Sci Total
Environ 64:125–147
Smith DS, Bell RA, Kramer JR (2002) Metal speciation in natural waters with emphasis on reduced sulfur groups as strong metal binding sites. Comp Biochem Phys C
133:65–74
Sonke JE, Salters VJM (2006) Lanthanide-humic substances complexation. I. Experimental evidence for a lanthanide contraction effect. Geochim Cosmochim Acta 70:1495–1506
Sponza DT (2003) Investigation of extracellular polymer substances (EPS) and physicochemical properties of different activated sludge flocs under steady-state conditions. Enz Microb
Technol 32:375–385
Sposito G, Inouye CA, Bingham F, Yadav S (1982) Trace metal complexation by fulvic acid extracted
from sewage sludge: II. Development of chemical models. Soil Sci Soc Am J 46:51–56
Stackhouse RA, Benson WH (1988) The influence of humic-acid on the toxicity and bioavailability of selected trace-metals. Aquat Toxicol 13:99–108
Stedmon CA, Markager S, Tranvik L, Kronberg L, Slatis T, Martinsen W (2007) Photochemical
production of ammonium and transformation of dissolved organic matter in the Baltic Sea.
Mar Chem 104:227–240
Steelink C (2002) Investigating humic acids in soils. Anal Chem 74:326a–333a
Stenson AC, Marshall AG, Cooper WT (2003) Exact masses and chemical formulas of individual
Suwannee River fulvic acids from ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectra. Anal Chem 75:1275–1284
Stevenson F, Fitch A, Brar M (1993) Stability constants of Cu (II)-humate complexes: comparison of select models. Soil Sci 155:77
Stoll JMA, Giger W (1998) Mass balance for detergent-derived fluorescent whitening agents in
surface waters of Switzerland. Water Res 32:2041–2050
Sun YP, Nguyen KL, Wallis AFA (1998) Ring-opened products from reaction of lignin model
compounds with UV-assisted peroxide. Holzforschung 52:61–66
Sunda W (1988) Trace metal interactions with marine phytoplankton. Biolog Oceanogr 6:411–442
Sunda W, Ferguson R (1983) Sensitivity of natural bacterial communities to additions of copper
and to cupric ion activity: a bioassay of copper complexation in seawater. In: Trace metals in
sea water NATO Conf Ser 4: Mar Sci V 9 Plenum, pp 87l–891
Sunda WG, Hanson AK (1987) Measurement of free cupric ion concentration in seawater by
a ligand competition technique involving copper sorption onto C-18 Sep-Pak cartridges.
Limnol Oceanogr 32:537–551
Sunda WG, Huntsman SA (1991) The use of chemiluminescence and ligand competition with edta to measure copper concentration and speciation in seawater. Mar Chem
36:137–163
Sundh I (1992) Biochemical-composition of dissolved organic-carbon released from natural
communities of lake phytoplankton. Arch Hydrobiol 125:347–369
Complexation of Dissolved Organic Matter with Trace Metal Ions in Natural Waters
Simpson AJ, Kingery WL, Hayes MHB, Spraul M, Humpfer E, Dvortsak P, Kerssebaum R,
Godejohann M, Hofmann M (2002) Molecular structures and associations of humic substances in the terrestrial environment. Naturwissenschaften 89:84–88
Skoog A, Wedborg M, Fogelqvist E (1996) Photobleaching of fluorescence and the organic carbon concentration in a coastal environment. Mar Chem 55:333–345
Slawyk G, Raimbault P, Garcia N (1998) Measuring gross uptake of N-15-labeled nitrogen by
marine phytoplankton without particulate matter collection: evidence of low N-15 losses to
the dissolved organic nitrogen pool. Limnol Oceanogr 43:1734–1739
Slawyk G, Raimbault P, Garcia N (2000) Use of N-15 to measure dissolved organic nitrogen release by
marine phytoplankton (reply to comment by Bronk and Ward). Limnol Oceanogr 45:1884–1886
Martell AE, Smith, RM (1974) Critical stability constants. Plenum, New York
Smith DS, Kramer JR (1998) Multi-site aluminum speciation with natural organic matter using
multiresponse fluorescence data. Anal Chim Acta 363:21–29
Smith DS, Kramer JR (1999) Fluorescence analysis for multi-site aluminum binding to natural
organic matter. Environ Int 25:295–306
Smith RM, Martell AE (1987) Critical stability-constants, enthalpies and entropies for the formation of metal-complexes of Aminopolycarboxylic Acids and Carboxylic-Acids. Sci Total
Environ 64:125–147
Smith DS, Bell RA, Kramer JR (2002) Metal speciation in natural waters with emphasis on reduced sulfur groups as strong metal binding sites. Comp Biochem Phys C
133:65–74
Sonke JE, Salters VJM (2006) Lanthanide-humic substances complexation. I. Experimental evidence for a lanthanide contraction effect. Geochim Cosmochim Acta 70:1495–1506
Sponza DT (2003) Investigation of extracellular polymer substances (EPS) and physicochemical properties of different activated sludge flocs under steady-state conditions. Enz Microb
Technol 32:375–385
Sposito G, Inouye CA, Bingham F, Yadav S (1982) Trace metal complexation by fulvic acid extracted
from sewage sludge: II. Development of chemical models. Soil Sci Soc Am J 46:51–56
Stackhouse RA, Benson WH (1988) The influence of humic-acid on the toxicity and bioavailability of selected trace-metals. Aquat Toxicol 13:99–108
Stedmon CA, Markager S, Tranvik L, Kronberg L, Slatis T, Martinsen W (2007) Photochemical
production of ammonium and transformation of dissolved organic matter in the Baltic Sea.
Mar Chem 104:227–240
Steelink C (2002) Investigating humic acids in soils. Anal Chem 74:326a–333a
Stenson AC, Marshall AG, Cooper WT (2003) Exact masses and chemical formulas of individual
Suwannee River fulvic acids from ultrahigh resolution electrospray ionization Fourier transform ion cyclotron resonance mass spectra. Anal Chem 75:1275–1284
Stevenson F, Fitch A, Brar M (1993) Stability constants of Cu (II)-humate complexes: comparison of select models. Soil Sci 155:77
Stoll JMA, Giger W (1998) Mass balance for detergent-derived fluorescent whitening agents in
surface waters of Switzerland. Water Res 32:2041–2050
Sun YP, Nguyen KL, Wallis AFA (1998) Ring-opened products from reaction of lignin model
compounds with UV-assisted peroxide. Holzforschung 52:61–66
Sunda W (1988) Trace metal interactions with marine phytoplankton. Biolog Oceanogr 6:411–442
Sunda W, Ferguson R (1983) Sensitivity of natural bacterial communities to additions of copper
and to cupric ion activity: a bioassay of copper complexation in seawater. In: Trace metals in
sea water NATO Conf Ser 4: Mar Sci V 9 Plenum, pp 87l–891
Sunda WG, Hanson AK (1987) Measurement of free cupric ion concentration in seawater by
a ligand competition technique involving copper sorption onto C-18 Sep-Pak cartridges.
Limnol Oceanogr 32:537–551
Sunda WG, Huntsman SA (1991) The use of chemiluminescence and ligand competition with edta to measure copper concentration and speciation in seawater. Mar Chem
36:137–163
Sundh I (1992) Biochemical-composition of dissolved organic-carbon released from natural
communities of lake phytoplankton. Arch Hydrobiol 125:347–369