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1 Introduction
Complexation of the metal ions (M) with dissolved organic matter (DOM), i.e.
M-DOM formation is of fundamental importance in metal ion chemistry and can
control the occurrence of free toxic metals, the transport or migration of metals,
acid–base balance and solubility in water, occurrence of the photo-Fenton reaction
in surface water, biological effects, the bioavailability and toxicity to organisms in
water, sediment and soil environments. DOM in natural waters can either enhance
or decrease metal transport and affect the bioavailability of metals depending on its
composition. DOM is a complex mixture of organic compounds of allochthonous
Complexation of Dissolved Organic Matter
with Trace Metal Ions in Natural Waters
K. M. G. Mostofa et al. (eds.), Photobiogeochemistry of Organic Matter,
Environmental Science and Engineering, DOI: 10.1007/978-3-642-32223-5_9,
© Springer-Verlag Berlin Heidelberg 2013
Khan M. G. Mostofa, Cong-qiang Liu, Xinbin Feng, Takahito Yoshioka,
Davide Vione, Xiangliang Pan and Fengchang Wu
K. M. G. Mostofa (*) · C. Q. Liu· X. B. Feng
State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry,
Chinese Academy of Sciences, Guiyang 550002, China
e-mail: mostofa@vip.gyig.ac.cn
T. Yoshioka
Field Science Education and Research Center, Kyoto University, Kitashirakawa Oiwake-cho,
Sakyo-ku, Kyoto 606-8502, Japan
D. Vione
Dipartimento di Chimica Analitica, University of Turin, I-10125 Turin, Italy
Centro Interdipartimentale Natrisk, I-10094 Grugliasco, (TO), Italy
X. L. Pan
Xinjiang Key Laboratory of Water Cycle and Utilization in Arid Zone, Xinjiang Institute of Ecology
and Geography, Chinese Academy of Sciences, Urumqi 830011, People’s Republic of China
F. C. Wu
State Environmental Protection Key Laboratory of Lake Pollution Control, Chinese Research
Academy of Environmental Sciences, Chaoyang 100012, China
1 Introduction
Complexation of the metal ions (M) with dissolved organic matter (DOM), i.e.
M-DOM formation is of fundamental importance in metal ion chemistry and can
control the occurrence of free toxic metals, the transport or migration of metals,
acid–base balance and solubility in water, occurrence of the photo-Fenton reaction
in surface water, biological effects, the bioavailability and toxicity to organisms in
water, sediment and soil environments. DOM in natural waters can either enhance
or decrease metal transport and affect the bioavailability of metals depending on its
composition. DOM is a complex mixture of organic compounds of allochthonous
Complexation of Dissolved Organic Matter
with Trace Metal Ions in Natural Waters
K. M. G. Mostofa et al. (eds.), Photobiogeochemistry of Organic Matter,
Environmental Science and Engineering, DOI: 10.1007/978-3-642-32223-5_9,
© Springer-Verlag Berlin Heidelberg 2013
Khan M. G. Mostofa, Cong-qiang Liu, Xinbin Feng, Takahito Yoshioka,
Davide Vione, Xiangliang Pan and Fengchang Wu
K. M. G. Mostofa (*) · C. Q. Liu· X. B. Feng
State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry,
Chinese Academy of Sciences, Guiyang 550002, China
e-mail: mostofa@vip.gyig.ac.cn
T. Yoshioka
Field Science Education and Research Center, Kyoto University, Kitashirakawa Oiwake-cho,
Sakyo-ku, Kyoto 606-8502, Japan
D. Vione
Dipartimento di Chimica Analitica, University of Turin, I-10125 Turin, Italy
Centro Interdipartimentale Natrisk, I-10094 Grugliasco, (TO), Italy
X. L. Pan
Xinjiang Key Laboratory of Water Cycle and Utilization in Arid Zone, Xinjiang Institute of Ecology
and Geography, Chinese Academy of Sciences, Urumqi 830011, People’s Republic of China
F. C. Wu
State Environmental Protection Key Laboratory of Lake Pollution Control, Chinese Research
Academy of Environmental Sciences, Chaoyang 100012, China
