Alternative fit, 62
Alternative pig liver esterase, 68
Amberlite, 370
Amidase, 130
Amidase method, 53–54
Amide bond, 49–58
hydrolysis, 31
synthesis, 344–347
Amination, 139
Amine, 156
Amine dehydrogenase, 160, 365
donor, 247
transaminases, 246
Amino acid, 49, 159
L-α-Aminoadipate, 139
Aminoalcohols, 260
p-Aminobenzoic acid, 129
α-Amino-ε-caprolactam racemase, 53, 57
Aminolysis, 33, 344
6-Aminopenicillanic acid, 344
α-Aminophosphonic acid, 55
Amino transfer, 245–250
Ammonia, 245
Ammonia lyases, 227
Ammonolysis, 32
Amoxicillin, 50, 344
Ampicillin, 50, 344
Anaerobic organisms, 139
Anchor group, 181
Anion exchange resin, 339
Anomeric center, 240, 243
control, 243
Antibiotics, 9
Antifoam, 417
Arbutin, 244
Aristeromycin, 106
Aromatase, 167
Artemisinic acid, 9
Arthrobacter citreus, 247
Artificial metabolism, 213
Ascophyllum nodosum, 254
Ascorbic acid, 182
Aspartame, 351
Aspartase, 227
Aspartic acid, 227
Aspergillus niger, 162, 171
Astaxanthin, 165
Atazanavir, 160
Atom efficiency, 224
Autooxidation, 382
Auxiliary substrate, 135
Avidin, 383
Axial chirality, 17, 67
Azafenidin, 129
Azeotropic distillation, 325
Azide, 260
Aziridines, 119
Azlactones, 90
B
Bacillus megaterium, 177, 247
Bacillus subtilis, 69
Bacillus subtilis esterase, 79
Baeyer-villigerases, 193
Baeyer villiger oxidations, 177, 178,
189–194, 365
Baker’s yeast, 52, 69, 147, 162, 164, 187, 219
Beauveria bassiana, 162, 180
Benzaldehyde lyase (BAL), 221–222
Benzoin reactions, 218–224
Benzoylformate decarboxylase, 221
Biaryls, 201
Biodegradation, 112
Biomass, 412
Bio-synthesis, 112
Biotin, 24, 66, 383
Biphasic, 318–319
medium, 96
systems, 102
Boceprevir, 172
Borderline-S N 2, 117
Borrowing hydrogen, 358, 364
Bound water, 316
Bovine pancreas, 52
serum albumin, 322
Brevicomin, 105, 210
Bromelain, 70
Bromoperoxidases, 252
Brønsted acid, 159
Bücherer–Bergs synthesis, 55
Bulk water, 11, 316
Butyrolactones, 166, 227
C
Calcimycin, 179
Caldariomyces fumago, 201, 252
Camphor hydroxylase, 175
Candida antarctica lipase, 86, 94, 340
Candida antarctica lipase B, 11, 76, 81, 326
Candida parapsilosis, 155
Candida rugosa lipase, 85
Candida sp. Lipases, 92–95
Cannizzaro-reaction, 4
Caprolactone, 193, 366
424
Index
Alternative pig liver esterase, 68
Amberlite, 370
Amidase, 130
Amidase method, 53–54
Amide bond, 49–58
hydrolysis, 31
synthesis, 344–347
Amination, 139
Amine, 156
Amine dehydrogenase, 160, 365
donor, 247
transaminases, 246
Amino acid, 49, 159
L-α-Aminoadipate, 139
Aminoalcohols, 260
p-Aminobenzoic acid, 129
α-Amino-ε-caprolactam racemase, 53, 57
Aminolysis, 33, 344
6-Aminopenicillanic acid, 344
α-Aminophosphonic acid, 55
Amino transfer, 245–250
Ammonia, 245
Ammonia lyases, 227
Ammonolysis, 32
Amoxicillin, 50, 344
Ampicillin, 50, 344
Anaerobic organisms, 139
Anchor group, 181
Anion exchange resin, 339
Anomeric center, 240, 243
control, 243
Antibiotics, 9
Antifoam, 417
Arbutin, 244
Aristeromycin, 106
Aromatase, 167
Artemisinic acid, 9
Arthrobacter citreus, 247
Artificial metabolism, 213
Ascophyllum nodosum, 254
Ascorbic acid, 182
Aspartame, 351
Aspartase, 227
Aspartic acid, 227
Aspergillus niger, 162, 171
Astaxanthin, 165
Atazanavir, 160
Atom efficiency, 224
Autooxidation, 382
Auxiliary substrate, 135
Avidin, 383
Axial chirality, 17, 67
Azafenidin, 129
Azeotropic distillation, 325
Azide, 260
Aziridines, 119
Azlactones, 90
B
Bacillus megaterium, 177, 247
Bacillus subtilis, 69
Bacillus subtilis esterase, 79
Baeyer-villigerases, 193
Baeyer villiger oxidations, 177, 178,
189–194, 365
Baker’s yeast, 52, 69, 147, 162, 164, 187, 219
Beauveria bassiana, 162, 180
Benzaldehyde lyase (BAL), 221–222
Benzoin reactions, 218–224
Benzoylformate decarboxylase, 221
Biaryls, 201
Biodegradation, 112
Biomass, 412
Bio-synthesis, 112
Biotin, 24, 66, 383
Biphasic, 318–319
medium, 96
systems, 102
Boceprevir, 172
Borderline-S N 2, 117
Borrowing hydrogen, 358, 364
Bound water, 316
Bovine pancreas, 52
serum albumin, 322
Brevicomin, 105, 210
Bromelain, 70
Bromoperoxidases, 252
Brønsted acid, 159
Bücherer–Bergs synthesis, 55
Bulk water, 11, 316
Butyrolactones, 166, 227
C
Calcimycin, 179
Caldariomyces fumago, 201, 252
Camphor hydroxylase, 175
Candida antarctica lipase, 86, 94, 340
Candida antarctica lipase B, 11, 76, 81, 326
Candida parapsilosis, 155
Candida rugosa lipase, 85
Candida sp. Lipases, 92–95
Cannizzaro-reaction, 4
Caprolactone, 193, 366
424
Index