1.3 Phane Nomenclature
7
8 3 4
7
15
'(S)5
1
13
2 8
8 10
3
3
CA: 7 -Aza-6,17-dioxa-3,1O-dithiatetracyclo[10.2.2.11,12.1 5 ,8jdodecaS(18),7-diene (small outer numbering)
73
IUPAC: 17 -Oxa-3,7 -dithia-l (1,4)-bicyclo[2.2.1jheptana-S(3,S)-1,2-oxazo
lacyclooctaphane (fat numbering)
1.3.2
Other Phanes
Initially, the phane concept was intended solely for supercyclic systems,
namely, cyclophanes. During elaboration of the newall-encompassing
cyclophane nomenclature it became more and more obvious that its basic
principles apply equally well to extended linear assemblies of chain and
ring segments. Such superchains can then be treated exactly like cyclophanes, except that their names end with the morpheme ... phane after the
numerical term denoting the length of the superchain.
1 (2)-Cyclobutabenzena-3(S,2)-pyridina-7( 1,3 )-pyrrola-l0( 1)naphthalenadecaphane
7
8 3 4
7
15
'(S)5
1
13
2 8
8 10
3
3
CA: 7 -Aza-6,17-dioxa-3,1O-dithiatetracyclo[10.2.2.11,12.1 5 ,8jdodecaS(18),7-diene (small outer numbering)
73
IUPAC: 17 -Oxa-3,7 -dithia-l (1,4)-bicyclo[2.2.1jheptana-S(3,S)-1,2-oxazo
lacyclooctaphane (fat numbering)
1.3.2
Other Phanes
Initially, the phane concept was intended solely for supercyclic systems,
namely, cyclophanes. During elaboration of the newall-encompassing
cyclophane nomenclature it became more and more obvious that its basic
principles apply equally well to extended linear assemblies of chain and
ring segments. Such superchains can then be treated exactly like cyclophanes, except that their names end with the morpheme ... phane after the
numerical term denoting the length of the superchain.
1 (2)-Cyclobutabenzena-3(S,2)-pyridina-7( 1,3 )-pyrrola-l0( 1)naphthalenadecaphane