3.11 Compounds with Chains of Three or More Nitrogen Atoms
143
Compounds of type RN=NX having X linked directly to the diazo group
have already been treated in Section 3.8.
3.11
Compounds with Chains of Three or More Nitrogen Atoms
The first compounds to be considered here are azides, which are mostly
named radicofunctionally as ... yl azides or substitutively as azido ...
derivatives.
1H-Indol-2-yl azide or 2-Azido-1H-indole
Benzoyl azide
All other compounds containing such nitrogen chains are designated as
polyazanes, -azenes, -azadienes, etc. with double bonds being preferred for
numbering.
H2N-NH-NH-CH3
H3C-NH-N=N-C6Hs
Et \6
3
1
N-NH-N=N-N=N-Me
ptf
1-Methyltriazane
3-Methyl-1-phenyltriazene
6-Ethyl-1-methyl-6-phenylhexaazal,3-diene
HN=N-NH-G-COOH 4-(Triaz-2-enyl)benzoic acid
Triazenes substituted at both ends with identical organyl groups were formerly denoted as diazo amino ... compounds.
2,2' -Diazoaminonaphthalene
[1,3- Di(naphthalen-2-yl)triazene 1
143
Compounds of type RN=NX having X linked directly to the diazo group
have already been treated in Section 3.8.
3.11
Compounds with Chains of Three or More Nitrogen Atoms
The first compounds to be considered here are azides, which are mostly
named radicofunctionally as ... yl azides or substitutively as azido ...
derivatives.
1H-Indol-2-yl azide or 2-Azido-1H-indole
Benzoyl azide
All other compounds containing such nitrogen chains are designated as
polyazanes, -azenes, -azadienes, etc. with double bonds being preferred for
numbering.
H2N-NH-NH-CH3
H3C-NH-N=N-C6Hs
Et \6
3
1
N-NH-N=N-N=N-Me
ptf
1-Methyltriazane
3-Methyl-1-phenyltriazene
6-Ethyl-1-methyl-6-phenylhexaazal,3-diene
HN=N-NH-G-COOH 4-(Triaz-2-enyl)benzoic acid
Triazenes substituted at both ends with identical organyl groups were formerly denoted as diazo amino ... compounds.
2,2' -Diazoaminonaphthalene
[1,3- Di(naphthalen-2-yl)triazene 1
