New Concepts for Organocatalysis
23
The first highly enantioselective examples of this catalysis strategy
were reported by MacMillan et al. in 2000 (Ahrendt et al. 2000; also
see: Wilson et al. 2005; Northrup and MacMillan 2002b), shortly after
our first report on the proline-catalyzed intermolecular aldol reaction
had appeared. The MacMillan group has quickly established that Diels–
Scheme 17. Iminium catalytic asymmetric transformations
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