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3
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u ) system of I 2 by perturbation-facilitated optical–optical
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A.I.: Heterogeneous and hyperfine interactions between valence states of molecular iodine
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2
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2
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(2016). https://doi.org/10.1063/1.4948630
58. Baturo, V.V., Cherepanov, I.N., Lukashov, S.S., Poretsky, S.A., Pravilov, A.M.:
Spectroscopic constants and potential energy curves of some iodine valence ungerade
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59. Nakano, Y., Ukeguchi, H., Ishiwata, T.: Observation and analysis of the 2 g (
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61. Herzberg, G.: Molecular Spectra and Molecular Structure. II. Infrared and Raman Spectra in
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69. Vigué, J., Broyer, M., Lehmann, J.C.: Natural hyperfine and magnetic predissociation of the
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70. Alekseev, A.B., Vilesov, A.F., Ivanov, V.S., Pravilov, Sidorov, I.I., A.M., Shestakov, O.D.:
The mechanism and kinetics HeH(B
2
P), HeD(B
2
P) molecules formation and decay during
recombination H(
2
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2
P) and He. Soviet J. Quant. Electronics (Eng.transl.) 17, 1236–1241
(1990)
71. Alekseev, A.B., Ivanov, V.S., Pravilov, A.M., Shestakov, O.D.: Theoretical study of the HeH
(B
2
P) fluorescence and predissociation. Chem. Phys. 155, 173–178 (1991)
72. Farantos, S.C., Murrel, J.N.: On the transition from quasiperiodiv to stochastic classical
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73. Pravilov, A.M., Shulpyakov, I.O.: Mechanism of CO 2 photolysis in the 167–155 nm spectral
range. Sov. J. Chem. Phys. 3, 2432–2451 (1986)
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resonance spectroscopy of the h 0
À
u (
3
P 1 ) and H1 u (
3
P 1 ) ion-pair states of I 2 . J. Chem. Phys.
117, 187–196 (2002). https://doi.org/10.1063/1.1481391
56. Motohiro, S., Nakajima, S., Aoyama, K., Kagi, E., Fujiwara, H., Fukushima, M., Ishiwata, T.:
Analysis of the 0
À
g (
3
P 1 )–B′
3
P(0
À
u ) system of I 2 by perturbation-facilitated optical–optical
double resonance. J. Chem. Phys. 117, 9777–9784 (2002). https://doi.org/10.1063/1.1516790
57. Baturo, V.V., Cherepanov, I.N., Lukashov, S.S., Poretsky, S.A., Pravilov, A.M., Zhironkin,
A.I.: Heterogeneous and hyperfine interactions between valence states of molecular iodine
correlating with the I(
2
P 1/2 ) + I(
2
P 1/2 ) dissociation limit. J. Chem. Phys. 144, 184310–184318
(2016). https://doi.org/10.1063/1.4948630
58. Baturo, V.V., Cherepanov, I.N., Lukashov, S.S., Poretsky, S.A., Pravilov, A.M.:
Spectroscopic constants and potential energy curves of some iodine valence ungerade
weakly bound states. J. Phys. B At. Mol. Opt. Phys. 48, 055101 (8pp) (2015). https://doi.org/
10.1088/0953-4075/48/5/055101
59. Nakano, Y., Ukeguchi, H., Ishiwata, T.: Observation and analysis of the 2 g (
1
D) ion-pair state
of I 2 : The g/u mixing between the 1 u (
1
D) and 2 g (
1
D) states. J. Chem. Phys. 121, 1397–1404
(2004). https://doi.org/10.1063/1.1756134
60. Baturo, V.V., Cherepanov, I.N., Lukashov, S.S., Petrov, A.N., Poretsky, S.A., Pravilov, A.
M.: Hyperfine coupling of the iodine D0
þ
u and b1g ion–pair states. J. Phys. B At. Mol. Opt.
Phys. 51, 095101 (9 pp) (2018). https://doi.org/10.1088/1361-6455/aab6e3
61. Herzberg, G.: Molecular Spectra and Molecular Structure. II. Infrared and Raman Spectra in
Polyatomic Molecules. D. van Nostrand Co., Inc. (1945)
62. Strickler, S.J., Berg, R.A.: Relationship between absorption intensity and fluorescence
lifetime of molecules. J. Chem. Phys. 37, 814–822 (1962). https://doi.org/10.1063/1.1733166
63. Douglas, A.E.: Anomalously long radiative lifetimes of molecular excited states. J. Chem.
Phys. 45, 1007–1015 (1966). https://doi.org/10.1063/1.1727650
64. Bixon, M., Jortner, J.: Long radiative lifetimes of small molecules. J. Chem. Phys. 50, 3284–
3290 (1969). https://doi.org/10.1063/1.1671552
65. Neuberger, D., Duncan, A.B.F.: Fluorescence of nitrogen dioxide. J. Chem. Phys. 22, 1693–
1696 (1954). https://doi.org/10.1063/1.1739877
66. Medvedev, E.S., Osherov, V.I.: Radiationless Transitions in Polyatomic Molecules. Springer
(1995). https://doi.org/10.1002/bbpc.19961000329
67. Broyer, M., Vigué, J., Lehmann, J.C.: Hyperfine predissociation of molecular iodine.
J. Chem. Phys. 64, 4793–4794 (1976). https://doi.org/10.1063/1.432067
68. Tellinghuisen, J.: Potentials for weakly bound states in I 2 from diffuse spectra and
predissociation data. J. Chem. Phys. 82, 4012–4016 (1985). https://doi.org/10.1063/1.448841
69. Vigué, J., Broyer, M., Lehmann, J.C.: Natural hyperfine and magnetic predissociation of the
I 2 B state II. – Experiments on natural and hyperfine predissociation. J. Phys. Fr. 42, 949–959
(1981). https://doi.org/10.1051/jphys:01981004207094900
70. Alekseev, A.B., Vilesov, A.F., Ivanov, V.S., Pravilov, Sidorov, I.I., A.M., Shestakov, O.D.:
The mechanism and kinetics HeH(B
2
P), HeD(B
2
P) molecules formation and decay during
recombination H(
2
P), D(
2
P) and He. Soviet J. Quant. Electronics (Eng.transl.) 17, 1236–1241
(1990)
71. Alekseev, A.B., Ivanov, V.S., Pravilov, A.M., Shestakov, O.D.: Theoretical study of the HeH
(B
2
P) fluorescence and predissociation. Chem. Phys. 155, 173–178 (1991)
72. Farantos, S.C., Murrel, J.N.: On the transition from quasiperiodiv to stochastic classical
motion on real polyatomic energy surfaces. Chem. Phys. 55, 205–214 (1981). https://doi.org/
10.1016/0301-0104(81)85021-5
73. Pravilov, A.M., Shulpyakov, I.O.: Mechanism of CO 2 photolysis in the 167–155 nm spectral
range. Sov. J. Chem. Phys. 3, 2432–2451 (1986)
74. Pack, R.T.: Simple theory of diffuse vibrational structure in continuous uv spectra of
polyatomic molecules. I. Collinear photodissociation of symmetric triatomics. J. Chem. Phys.
65, 4765–4770 (1976). https://doi.org/10.1063/1.432931
References
151