Coherent Anti-Stokes Raman Scattering: Basics, Theoretical …
253
Table 1 χ 3 values for some
materials
Material
Wavelength /
nm
χ 3 / 10 –22
m 2 /V 2
Reference
Quartz
1313
4.2
[22]
Ethanol
1313
7
[22]
Cyclo-hexane
1313
8.7
[22]
Water
1053
3.9
[22]
Polydiacetylene 1053
600
[22]
spatial resolution beyond the diffraction limit of optical microscopes can be achieved
when tip-enhancement techniques are applied. A combination of SE-CARS and trCARS allows for the detection of ultrafast vibrational dynamics with ultrahigh spatial
resolution. Many potential applications can be envisaged, but at the same time still
a better understanding of the underlying enhancement mechanisms is required.
References
1. L.A. Lyon, C.D. Keating, A.P. Fox, B.E. Baker, L. He, S.R. Nicewarner, S.P. Mulvaney, M.J.
Natan, Anal. Chem. 70, 341–362 (1998)
2. C. Matthäus, B. Bird, M. Miljkovi´ c, T. Chernenko, M. Romeo, M. Diem 89, 275–308 (2008)
3. N. Jamin, P. Dumas, J. Moncuit, W. Fridman, J. Teillaud, G.L. Carr, G.P. Williams, Proc. Natl.
Acad. Sci. USA 95, 4837 (1998)
4. H. J. Humecki.: Practical guide to infrared microspectroscopy. Marcel Dekker, New York
(1995).
5. K. Shafer-Peltier, A.S. Haka, M. Fitzmaurice, J. Crowe, J. Myles, R.R. Dasari, M.S. Feld, J.
Raman Spectrosc. 33, 552–563 (2002)
6. T.H. Maiman, Nature 187, 493–494 (1960)
7. P.D. Maker, R.W. Terhune, Phys. Rev. 137, A801–A818 (1965)
8. R.F. Begley, A.B. Harvey, R.L. Byer, Appl. Phys. Lett. 25, 387–390 (1974)
9. S. Roy, J.R. Gord, A.K. Patnaik, Prog. Energy Combust. Sci. 36, 280–306 (2010)
10. W.M. Tolles, J.W. Nibler, J.R. McDonald, A.B. Harvey, Appl. Spectrosc. 31, 253–271 (1977)
11. M.J. Winterhalder, A. Zumbusch, J. Microsc. 255, 1–6 (2014)
12. J. Cheng, X.S. Xie, J Phys Chem B 108, 827–840 (2004)
13. X. S. Xie, J. Cheng, and E. Potma. In: Pawley, J (eds.) Handbook Of Biological Confocal
Microscopy pp. 595–606. Springer, Boston, MA (2006).
14. Y. R. Shen.: The principles of nonlinear optics. Wiley Interscience, New York (1984).
15. S. Mukamel.: Principles of Nonlinear Optical Spectroscopy. Oxford University Press, Oxford
(1995).
16. M. D. Levenson.: Introduction to Nonlinear Laser Spectroscopy. Academic Press, New York
(1988).
17. R. J. H. Clark, R. E. Hester.: Advances in Nonlinear Spectroscopy. John Wiley and Sons, New
York (1988).
18. M. Göppert-Mayer, Ann. Phys. 401, 273–294 (1931)
19. W. Kaiser, C.G.B. Garrett, Phys. Rev. Lett. 7, 229–231 (1961)
20. P.A. Franken, A.E. Hill, C.W. Peters, G. Weinreich, Phys. Rev. Lett. 7, 118–119 (1961)
21. N. Bloembergen.: Nonlinear optics: a lecture note and reprint volume. W. A. Benjamin, New
York, (1965).
253
Table 1 χ 3 values for some
materials
Material
Wavelength /
nm
χ 3 / 10 –22
m 2 /V 2
Reference
Quartz
1313
4.2
[22]
Ethanol
1313
7
[22]
Cyclo-hexane
1313
8.7
[22]
Water
1053
3.9
[22]
Polydiacetylene 1053
600
[22]
spatial resolution beyond the diffraction limit of optical microscopes can be achieved
when tip-enhancement techniques are applied. A combination of SE-CARS and trCARS allows for the detection of ultrafast vibrational dynamics with ultrahigh spatial
resolution. Many potential applications can be envisaged, but at the same time still
a better understanding of the underlying enhancement mechanisms is required.
References
1. L.A. Lyon, C.D. Keating, A.P. Fox, B.E. Baker, L. He, S.R. Nicewarner, S.P. Mulvaney, M.J.
Natan, Anal. Chem. 70, 341–362 (1998)
2. C. Matthäus, B. Bird, M. Miljkovi´ c, T. Chernenko, M. Romeo, M. Diem 89, 275–308 (2008)
3. N. Jamin, P. Dumas, J. Moncuit, W. Fridman, J. Teillaud, G.L. Carr, G.P. Williams, Proc. Natl.
Acad. Sci. USA 95, 4837 (1998)
4. H. J. Humecki.: Practical guide to infrared microspectroscopy. Marcel Dekker, New York
(1995).
5. K. Shafer-Peltier, A.S. Haka, M. Fitzmaurice, J. Crowe, J. Myles, R.R. Dasari, M.S. Feld, J.
Raman Spectrosc. 33, 552–563 (2002)
6. T.H. Maiman, Nature 187, 493–494 (1960)
7. P.D. Maker, R.W. Terhune, Phys. Rev. 137, A801–A818 (1965)
8. R.F. Begley, A.B. Harvey, R.L. Byer, Appl. Phys. Lett. 25, 387–390 (1974)
9. S. Roy, J.R. Gord, A.K. Patnaik, Prog. Energy Combust. Sci. 36, 280–306 (2010)
10. W.M. Tolles, J.W. Nibler, J.R. McDonald, A.B. Harvey, Appl. Spectrosc. 31, 253–271 (1977)
11. M.J. Winterhalder, A. Zumbusch, J. Microsc. 255, 1–6 (2014)
12. J. Cheng, X.S. Xie, J Phys Chem B 108, 827–840 (2004)
13. X. S. Xie, J. Cheng, and E. Potma. In: Pawley, J (eds.) Handbook Of Biological Confocal
Microscopy pp. 595–606. Springer, Boston, MA (2006).
14. Y. R. Shen.: The principles of nonlinear optics. Wiley Interscience, New York (1984).
15. S. Mukamel.: Principles of Nonlinear Optical Spectroscopy. Oxford University Press, Oxford
(1995).
16. M. D. Levenson.: Introduction to Nonlinear Laser Spectroscopy. Academic Press, New York
(1988).
17. R. J. H. Clark, R. E. Hester.: Advances in Nonlinear Spectroscopy. John Wiley and Sons, New
York (1988).
18. M. Göppert-Mayer, Ann. Phys. 401, 273–294 (1931)
19. W. Kaiser, C.G.B. Garrett, Phys. Rev. Lett. 7, 229–231 (1961)
20. P.A. Franken, A.E. Hill, C.W. Peters, G. Weinreich, Phys. Rev. Lett. 7, 118–119 (1961)
21. N. Bloembergen.: Nonlinear optics: a lecture note and reprint volume. W. A. Benjamin, New
York, (1965).