Fundamentals and Applications of Surface Enhanced Raman …
207
dye molecule. The vertical orientations of MoS 2 provides a larger accessible area
for effective dye absorption and also enhance the light trapping, which leads to an
improved charge transfer process. Such nanostructures can be easily scaled up and
used as SERS substrates for technological applications.
5 Summary
In this chapter, we have discussed the basic principle of SERS process on metallic
and semiconducting substrates. The mechanism for enhanced Raman signal in SERS
process has been discussed for both the SERS substrates. The main origin of SERS
on metallic substrate is the electromagnetic enhancement and for semiconducting
substrate is chemical enhancement. Different calculation methods for enhancement
factor (EF) have also been discussed in this chapter. At last, we have discussed
few examples of SERS study on different metallic and semiconducting substrate for
the detection of organic pollutants. Advancement in the area of 2D materials like
Graphene, MoS 2 etc. as SERS substrates have also been discussed.
References
1. S.K. Urek, N. Francic, M. Turel, A. Lobnik, J. Nanomat. 2013, 501320 (2013)
2. I.C.L. Pillai et al., Cell Stem Cell 20, 218 (2017)
3. E.C. Le Ru, P.G. Etchegoin, in Annual Review of Physical Chemistry, vol. 63, ed. by M.A.
Johnson, T.J. Martinez (Annual Reviews, Palo Alto, 2012), p. 65
4. S.C. Luo, K. Sivashanmugan, J.D. Liao, C.K. Yao, H.C. Peng, Biosens. Bioelectron. 61, 232
(2014)
5. M. Fleischmann, P.J. Hendra, A.J. McQuillan, Chem. Phys. Lett. 26, 163 (1974)
6. F.-G. Banica, in Chemical Sensors and Biosensors: Fundamentals and Applications (John
Wiley & Sons, Chichester, UK, 2012).
7. H. Yamada, Y. Yamamoto, N. Tani, Chem. Phys. Lett. 86, 397 (1982)
8. S. Hayashi, R. Koh, Y. Ichiyama, K. Yamamoto, Phys. Rev. Lett. 60, 1085 (1988)
9. C. Muehlethaler, C.R. Considine, V. Menon, W.C. Lin, Y.H. Lee, J.R. Lombardi, Acs Photonics
3, 1164 (2016)
10. J. Yu, Y. Guo, H.J. Wang, S. Su, C. Zhang, B.Y. Man, F.C. Lei, J. Phys. Chem. Lett. 10, 3676
(2019)
11. L.M. Xie, X. Ling, Y. Fang, J. Zhang, Z.F. Liu, J. Am. Chem. Soc. 131, 9890 (2009)
12. I. Alessandri, J.R. Lombardi, Chem. Rev. 116, 14921 (2016)
13. S.P. Mulvaney, C.D. Keating, Anal. Chem. 72, 145 (2000)
14. P.K. Kannan, P. Shankar, C. Blackman, C.H. Chung, Adv. Mater. 31, 1803432 (2019)
15. S. Schlucker, Angewandte Chemie-International Edition 53, 4756 (2014)
16. S. Schlucker, in Surface Enhanced Raman Spectroscopy: Analytical, Biophysical and Life
Science Applications (WILEY-VCH Verlag GmbH & Co., 2011)
17. R.J.C. Brown, J. Wang, M.J.T. Milton, J. Nanomater. 2007, 12086 (2007)
18. A. Campion, P. Kambhampati, Chem. Soc. Rev. 27, 241 (1998)
19. J.I. Gersten, J. Chem. Phys. 72, 5779 (1980)
20. J.I. Gersten, J. Chem. Phys. 72, 5780 (1980)
207
dye molecule. The vertical orientations of MoS 2 provides a larger accessible area
for effective dye absorption and also enhance the light trapping, which leads to an
improved charge transfer process. Such nanostructures can be easily scaled up and
used as SERS substrates for technological applications.
5 Summary
In this chapter, we have discussed the basic principle of SERS process on metallic
and semiconducting substrates. The mechanism for enhanced Raman signal in SERS
process has been discussed for both the SERS substrates. The main origin of SERS
on metallic substrate is the electromagnetic enhancement and for semiconducting
substrate is chemical enhancement. Different calculation methods for enhancement
factor (EF) have also been discussed in this chapter. At last, we have discussed
few examples of SERS study on different metallic and semiconducting substrate for
the detection of organic pollutants. Advancement in the area of 2D materials like
Graphene, MoS 2 etc. as SERS substrates have also been discussed.
References
1. S.K. Urek, N. Francic, M. Turel, A. Lobnik, J. Nanomat. 2013, 501320 (2013)
2. I.C.L. Pillai et al., Cell Stem Cell 20, 218 (2017)
3. E.C. Le Ru, P.G. Etchegoin, in Annual Review of Physical Chemistry, vol. 63, ed. by M.A.
Johnson, T.J. Martinez (Annual Reviews, Palo Alto, 2012), p. 65
4. S.C. Luo, K. Sivashanmugan, J.D. Liao, C.K. Yao, H.C. Peng, Biosens. Bioelectron. 61, 232
(2014)
5. M. Fleischmann, P.J. Hendra, A.J. McQuillan, Chem. Phys. Lett. 26, 163 (1974)
6. F.-G. Banica, in Chemical Sensors and Biosensors: Fundamentals and Applications (John
Wiley & Sons, Chichester, UK, 2012).
7. H. Yamada, Y. Yamamoto, N. Tani, Chem. Phys. Lett. 86, 397 (1982)
8. S. Hayashi, R. Koh, Y. Ichiyama, K. Yamamoto, Phys. Rev. Lett. 60, 1085 (1988)
9. C. Muehlethaler, C.R. Considine, V. Menon, W.C. Lin, Y.H. Lee, J.R. Lombardi, Acs Photonics
3, 1164 (2016)
10. J. Yu, Y. Guo, H.J. Wang, S. Su, C. Zhang, B.Y. Man, F.C. Lei, J. Phys. Chem. Lett. 10, 3676
(2019)
11. L.M. Xie, X. Ling, Y. Fang, J. Zhang, Z.F. Liu, J. Am. Chem. Soc. 131, 9890 (2009)
12. I. Alessandri, J.R. Lombardi, Chem. Rev. 116, 14921 (2016)
13. S.P. Mulvaney, C.D. Keating, Anal. Chem. 72, 145 (2000)
14. P.K. Kannan, P. Shankar, C. Blackman, C.H. Chung, Adv. Mater. 31, 1803432 (2019)
15. S. Schlucker, Angewandte Chemie-International Edition 53, 4756 (2014)
16. S. Schlucker, in Surface Enhanced Raman Spectroscopy: Analytical, Biophysical and Life
Science Applications (WILEY-VCH Verlag GmbH & Co., 2011)
17. R.J.C. Brown, J. Wang, M.J.T. Milton, J. Nanomater. 2007, 12086 (2007)
18. A. Campion, P. Kambhampati, Chem. Soc. Rev. 27, 241 (1998)
19. J.I. Gersten, J. Chem. Phys. 72, 5779 (1980)
20. J.I. Gersten, J. Chem. Phys. 72, 5780 (1980)