Hydrogen cyanide 217
Hydrogenation (reduction) 63, 198, 199,
271–278
a-Hydrogen 222, 223, 253, 254
Hydroxylation 266, 267
Hydrolysis 12, 56, 246, 260–264, 319, 321
Hydronium ion 6, 7, 24, 76
Hydrogen peroxide 203, 206, 208, 266
Hydrogen shift (hydride shift) 234, 235,
281
Hydrophilic 75
Hydrophobic 75
Hydroxide ion 6, 7, 235, 236, 262, 263
2-Hydroxybutane 55
Hydroxyl group 74, 75, 77
Hygrine 293
Hyoscyamine 293
Hyperconjugation 195, 197, 233
Ibuprofen 54, 115
Ice point 3
Imidazole 156–158, 289
Imidic acid 264
Imine 217, 218, 275
Imperatorin 363
Indole (benzopyrrole) 145, 168–170, 289,
297–299
Indolizidine 290
Induced dipole-induced dipole
interactions 29
Inductive effect 122, 124–127
Initiation (radical chain initiation) 192,
193, 203
Intermolecular hydrogen bonding 30, 75,
130, 131, 135, 174, 175, 184,
Intermolecular interactions or forces 28
Internal alkyne 108
Intramolecular hydrogen bonding 131
Inversion of configuration 234, 235, 238,
244, 282
Inversion of sucrose 313
Invert sugar 313
Ion pair (zwitterions) 181, 183
Ionic bond 25, 27
Ionization energy 24
Iridoid 328–331
Isobutane 29, 30, 63, 68
Isobutanol (2-butanol) 75, 225, 234, 238,
244, 248, 274
Isoelectric focusing 184
Isoelectric point (isoelectric pH) 183, 184
Isoflavonoids 360, 365–368
Isoleucine 179, 182
Isomerism 36
Isomers 36
Isopentane 4
Isopentanol 75
Isoprene rule 331
Isoprene unit 325, 331
Isopropanol 74, 75
Isoquinoline 145, 165–168, 290, 295, 296
Isothiazole 158–160
Isoxazole 145, 146, 155, 158–160
IUPAC 62
Jones’ reagents 269, 270
K a 12, 13
Kaempferol 365, 367
Kekule ´ structure 116–118
Ketal 220, 221, 307, 313
Keto-enol tautomerism 206
b-Ketoester 253, 254
Ketogenic amino acids 182
Ketones 85–89
Ketose 303, 309
Kolbe reaction 133, 134
Kovacs’ reagent 170
Kutkoside 330
b-Lactamases 188
Lactams 100, 101
Lactitol 313
Lactone 98
Lactose 311–313
Lanosterol 348, 356
Leaving group 223, 232, 234, 237, 238
Leguminosae 348, 350, 356
Leimgruber synthesis 169
Leucine 179, 182
Levorotatory 44
Lewis acids and bases 8, 9
Lewis structure 21
Lewis theory 21
Ligand 31
Lignan 361, 362
Limonene 54, 55, 331–334
Lindlar’s catalyst (poisoned catalyst) 199
Lipids 318, 354
Lithium aluminium hydride (LAH) 265,
272, 273, 274
Lithium organocuprates (Gilman
reagents) 72, 73, 78, 79, 87, 97, 240,
252, 253
Liquified petroleum gas (LPG) 68
Linaceae 321
Linalool 333, 334
Linamarin 321
INDEX
377
Hydrogenation (reduction) 63, 198, 199,
271–278
a-Hydrogen 222, 223, 253, 254
Hydroxylation 266, 267
Hydrolysis 12, 56, 246, 260–264, 319, 321
Hydronium ion 6, 7, 24, 76
Hydrogen peroxide 203, 206, 208, 266
Hydrogen shift (hydride shift) 234, 235,
281
Hydrophilic 75
Hydrophobic 75
Hydroxide ion 6, 7, 235, 236, 262, 263
2-Hydroxybutane 55
Hydroxyl group 74, 75, 77
Hygrine 293
Hyoscyamine 293
Hyperconjugation 195, 197, 233
Ibuprofen 54, 115
Ice point 3
Imidazole 156–158, 289
Imidic acid 264
Imine 217, 218, 275
Imperatorin 363
Indole (benzopyrrole) 145, 168–170, 289,
297–299
Indolizidine 290
Induced dipole-induced dipole
interactions 29
Inductive effect 122, 124–127
Initiation (radical chain initiation) 192,
193, 203
Intermolecular hydrogen bonding 30, 75,
130, 131, 135, 174, 175, 184,
Intermolecular interactions or forces 28
Internal alkyne 108
Intramolecular hydrogen bonding 131
Inversion of configuration 234, 235, 238,
244, 282
Inversion of sucrose 313
Invert sugar 313
Ion pair (zwitterions) 181, 183
Ionic bond 25, 27
Ionization energy 24
Iridoid 328–331
Isobutane 29, 30, 63, 68
Isobutanol (2-butanol) 75, 225, 234, 238,
244, 248, 274
Isoelectric focusing 184
Isoelectric point (isoelectric pH) 183, 184
Isoflavonoids 360, 365–368
Isoleucine 179, 182
Isomerism 36
Isomers 36
Isopentane 4
Isopentanol 75
Isoprene rule 331
Isoprene unit 325, 331
Isopropanol 74, 75
Isoquinoline 145, 165–168, 290, 295, 296
Isothiazole 158–160
Isoxazole 145, 146, 155, 158–160
IUPAC 62
Jones’ reagents 269, 270
K a 12, 13
Kaempferol 365, 367
Kekule ´ structure 116–118
Ketal 220, 221, 307, 313
Keto-enol tautomerism 206
b-Ketoester 253, 254
Ketogenic amino acids 182
Ketones 85–89
Ketose 303, 309
Kolbe reaction 133, 134
Kovacs’ reagent 170
Kutkoside 330
b-Lactamases 188
Lactams 100, 101
Lactitol 313
Lactone 98
Lactose 311–313
Lanosterol 348, 356
Leaving group 223, 232, 234, 237, 238
Leguminosae 348, 350, 356
Leimgruber synthesis 169
Leucine 179, 182
Levorotatory 44
Lewis acids and bases 8, 9
Lewis structure 21
Lewis theory 21
Ligand 31
Lignan 361, 362
Limonene 54, 55, 331–334
Lindlar’s catalyst (poisoned catalyst) 199
Lipids 318, 354
Lithium aluminium hydride (LAH) 265,
272, 273, 274
Lithium organocuprates (Gilman
reagents) 72, 73, 78, 79, 87, 97, 240,
252, 253
Liquified petroleum gas (LPG) 68
Linaceae 321
Linalool 333, 334
Linamarin 321
INDEX
377