Answers to Problems of the A Groups
12. (a) Second-order with respect to /V
13. (a) 31.2 kcal
(b) 1.10 x 1011
(c) 85.4 kcal
445
14. (a) 26.9 kcal
(b) 5.57 x 10-'
2
(c) 13.4 kcal
(b) Zero-order with respect to M
(d)
Products
Time course of reaction
(d)
Reactants
Time course of reaction
CHAPTER 16
1.
A
R
R
R
0
R
0
+
0
0
0
B
0
R
R
0
0
0
+
0
0
0
L
L
R
0
L
C
0
-
0
0
0
2. 1.27 atm
3. 1.10 x 1013 atm
4. (a) 2.26 x 10-" M and 4.19 x lO"
4 M
(b) 2.51 x 10" and 1.12 x 10
3
5. (a) 4.2 x 107
%
(c) 3.98 x 105 and 8.93 x 10"
1
(b) 0.28%