Biosorption of Ni(II) Using Seeds of Mirabilis Jalapa
65
Table 5 FTIR Spectral Analysis of M. jalapa seeds before and after analysis
Peak Before adsorption After adsorption Difference Inference
1
3197.77
–
Stretched O–H bond. Masked
after adsorption
2
2918.95
2922.44
−3.49
C-H sym. stretching
3
2851.41
2853.83
−2.42
C-H stretching
4
2317.19
–
Stretched P–H bond for group
masked after adsorption
5
1653.13
1635.04
+18.09
C = N stretching
6
1606.66
–
C-N group masked
7
1418.95
–
N = N group masked
8
1366.02
–
Weak, deformed C-H group
masked
9
1202.78
1231.54
−28.76
C–H deformation
10
1162.63
1156.58
6.05
C–H deformation
11
1095.17
–
Group containing C–H
deformation
12
1009.67
1014.25
−4.58
C–O stretching
13
693.69
703.40
−9.71
C–S stretching vibration
References
Aikpokpodion PE, Ipinmoroti RR, Omotoso SM (2010) Biosorption of Ni(II) from aqueous
solutions using waste tea (Camella cinencis) materials. Am Eurasian J Toxicol Sci 2:72–82
Al-Rub FA, El-Naas MH, Benyahia F, Ashour I (2004) Biosorption of Nickel on blank alginate
beads, free and immobilized algal cells. Process Biochem 39:1767–1773
Aravind J, Lenin C, Nancyflavia C et al (2015) Response surface methodology optimization of
Nickel (II) removal using pigeon pea pod biosorbent. Int J Environ Sci Technol 12:105–114
Cayllahua JEB, Torem ML (2011) Biosorptive flotation of nickel and aluminum ions from aqueous
solution. Desalination 279:195–200
Cempel M, Nikel G (2006) Nickel: a review of its sources and environmental toxicology. Pol J
Environ Stud 15(3):375–382
Fu F, Wang Q (2011) Removal of heavy metals from waste water: a review. J Environ Manage
92:407–418
Fertu DIT, Gavrilescu M (2012) Application of natural zeolites as sorbent in the cleanup of aqueous
streams. Environ Eng Manage J 11(4):867–878
Flores-Garnica JG, Morales-Barrera L, Pineda-Camacho G, Cristiani-Urbina E (2013) Biosorption
of Ni(II) from aqueous solutions by Litchi chinensis seeds. Bioresour Technol 136:635–643
Gohulavani G, Andal NM (2013) Removal of Nickel from aqueous solution using Azaridachta
indica seed shell powder as adsorbent. Res Rev J Chem 2(1):78–84
Kalavathy HM, Regupathi I, Pillai MG, Miranda LR (2009) Modelling, analysis and optimization of adsorption parameters for H 3 PO 4 activated rubber wood sawdust using response surface
methodology (RSM). Colloids Surf B 70(1):35–45
Kalavathy HM, Rose ML (2010) Moringa oleifera—a solid phase extractant for the removal of
Copper, Nickel and Zinc from aqueous solutions. Chem Eng J 158:188–199
65
Table 5 FTIR Spectral Analysis of M. jalapa seeds before and after analysis
Peak Before adsorption After adsorption Difference Inference
1
3197.77
–
Stretched O–H bond. Masked
after adsorption
2
2918.95
2922.44
−3.49
C-H sym. stretching
3
2851.41
2853.83
−2.42
C-H stretching
4
2317.19
–
Stretched P–H bond for group
masked after adsorption
5
1653.13
1635.04
+18.09
C = N stretching
6
1606.66
–
C-N group masked
7
1418.95
–
N = N group masked
8
1366.02
–
Weak, deformed C-H group
masked
9
1202.78
1231.54
−28.76
C–H deformation
10
1162.63
1156.58
6.05
C–H deformation
11
1095.17
–
Group containing C–H
deformation
12
1009.67
1014.25
−4.58
C–O stretching
13
693.69
703.40
−9.71
C–S stretching vibration
References
Aikpokpodion PE, Ipinmoroti RR, Omotoso SM (2010) Biosorption of Ni(II) from aqueous
solutions using waste tea (Camella cinencis) materials. Am Eurasian J Toxicol Sci 2:72–82
Al-Rub FA, El-Naas MH, Benyahia F, Ashour I (2004) Biosorption of Nickel on blank alginate
beads, free and immobilized algal cells. Process Biochem 39:1767–1773
Aravind J, Lenin C, Nancyflavia C et al (2015) Response surface methodology optimization of
Nickel (II) removal using pigeon pea pod biosorbent. Int J Environ Sci Technol 12:105–114
Cayllahua JEB, Torem ML (2011) Biosorptive flotation of nickel and aluminum ions from aqueous
solution. Desalination 279:195–200
Cempel M, Nikel G (2006) Nickel: a review of its sources and environmental toxicology. Pol J
Environ Stud 15(3):375–382
Fu F, Wang Q (2011) Removal of heavy metals from waste water: a review. J Environ Manage
92:407–418
Fertu DIT, Gavrilescu M (2012) Application of natural zeolites as sorbent in the cleanup of aqueous
streams. Environ Eng Manage J 11(4):867–878
Flores-Garnica JG, Morales-Barrera L, Pineda-Camacho G, Cristiani-Urbina E (2013) Biosorption
of Ni(II) from aqueous solutions by Litchi chinensis seeds. Bioresour Technol 136:635–643
Gohulavani G, Andal NM (2013) Removal of Nickel from aqueous solution using Azaridachta
indica seed shell powder as adsorbent. Res Rev J Chem 2(1):78–84
Kalavathy HM, Regupathi I, Pillai MG, Miranda LR (2009) Modelling, analysis and optimization of adsorption parameters for H 3 PO 4 activated rubber wood sawdust using response surface
methodology (RSM). Colloids Surf B 70(1):35–45
Kalavathy HM, Rose ML (2010) Moringa oleifera—a solid phase extractant for the removal of
Copper, Nickel and Zinc from aqueous solutions. Chem Eng J 158:188–199