138
P. Sahu
Table 6.1
Characteristics and uses of some perchlorate compounds
Compound
Formula
Molecular
weight
(g/inol)
Deusity (g/cm 3
) Physical appearance
Aqueous
solubility at
20 °C
(10 3
mg/L)
Decomposition
temp.
(°C)/Reaction
Uses
Ammonium
perchlorate
NH
4
ClO
4
117.488
1.952
Colourless or white
orthorombhic and regular
crystals
217–220
150
Energetic
booster in
rocket fuel
Sodium
perchlorate
NaCl
O
4
122.439
2.02–2.499
Hygroscopic/deliquescent,
white orthorombhic
crystals
2010
492
Strong
oxidizing agent
used in
explosive and
chemical
industries
Potassium
perchlorate
KCl
O
4
138.547
2.5298
Colourless crystal to
white crystalline powder,
hygroscopic
7.5–16.8
440
Solid oxidant
for rocket
production
Lithium
perchlorate
Licl
O
4
106.3906
2.428–2.429
Deliquescent, white
crystal
375
<250–400
Electrolyte in
voltaic cells,
synthesis of
organic
chemicals
Perchloric acid
HCl
O
4
2H
2 O
223.21
2.21
White, hygroscopic
powder
Very soluble
250
Analytical,
oxidizing and
dehydrating
agent
Source
Modified table after Sturchio et al. (2003) (Srinivasan and Viraraghavan 2009)
P. Sahu
Table 6.1
Characteristics and uses of some perchlorate compounds
Compound
Formula
Molecular
weight
(g/inol)
Deusity (g/cm 3
) Physical appearance
Aqueous
solubility at
20 °C
(10 3
mg/L)
Decomposition
temp.
(°C)/Reaction
Uses
Ammonium
perchlorate
NH
4
ClO
4
117.488
1.952
Colourless or white
orthorombhic and regular
crystals
217–220
150
Energetic
booster in
rocket fuel
Sodium
perchlorate
NaCl
O
4
122.439
2.02–2.499
Hygroscopic/deliquescent,
white orthorombhic
crystals
2010
492
Strong
oxidizing agent
used in
explosive and
chemical
industries
Potassium
perchlorate
KCl
O
4
138.547
2.5298
Colourless crystal to
white crystalline powder,
hygroscopic
7.5–16.8
440
Solid oxidant
for rocket
production
Lithium
perchlorate
Licl
O
4
106.3906
2.428–2.429
Deliquescent, white
crystal
375
<250–400
Electrolyte in
voltaic cells,
synthesis of
organic
chemicals
Perchloric acid
HCl
O
4
2H
2 O
223.21
2.21
White, hygroscopic
powder
Very soluble
250
Analytical,
oxidizing and
dehydrating
agent
Source
Modified table after Sturchio et al. (2003) (Srinivasan and Viraraghavan 2009)
