xii
Contents
23.5 Spectra of Polyatomic Molecules
975
23.6 Fluorescence, Phosphorescence, and Photochemistry
979
23.7 Raman Spectroscopy
985
23.8 Other Types of Spectroscopy
991
Chapter 24 Magnetic Resonance Spectroscopy
1001
24.1 Magnetic Fields and Magnetic Dipoles
1002
24.2 Electronic and Nuclear Magnetic Dipoles
1006
24.3 Electron Spin Resonance Spectroscopy
1010
24.4 Nuclear Magnetic Resonance Spectroscopy
1014
24.5 Fourier Transform NMR Spectroscopy
1024
Part 4 The Reconciliation of the Macroscopic and Molecular
Theories of Matter
1037
Chapter 25 Equilibrium Statistical Mechanics I. The Probability
Distribution for Molecular States
1039
25.1 The Quantum Statistical Mechanics of a Simple Model
System
1040
25.2 The Probability Distribution for a Dilute Gas
1047
25.3 The Probability Distribution and the Molecular Partition
Function
1055
25.4 The Calculation of Molecular Partition Functions
1064
Chapter 26 Equilibrium Statistical Mechanics. II. Statistical
Thermodynamics
1081
26.1 The Statistical Thermodynamics of a Dilute Gas
1082
26.2 Working Equations for the Thermodynamic Functions of a
Dilute Gas
1089
26.3 Chemical Equilibrium in Dilute Gases
1101
26.4 The Activated Complex Theory of Bimolecular Chemical
Reaction Rates in Dilute Gases
1106
26.5 Miscellaneous Topics in Statistical
Thermodynamics
1116
Chapter 27 Equilibrium Statistical Mechanics. III. Ensembles
1121
27.1 The Canonical Ensemble
1122
27.2 Thermodynamic Functions in the Canonical
Ensemble
1128
27.3 The Dilute Gas in the Canonical Ensemble
1130
27.4 Classical Statistical Mechanics
1133
27.5 Thermodynamic Functions in the Classical Canonical
Ensemble
1141
27.6 The Classical Statistical Mechanics of Dense Gases and
Liquids
1147
Chapter 28 The Structure of Solids, Liquids, and Polymers
1153
28.1 The Structure of Solids
1154
28.2 Crystal Vibrations
1162
28.3 The Electronic Structure of Crystalline Solids
1171
28.4 Electrical Resistance in Solids
1179