96
94. Zhang Z (2009) Comprehensive Organic Name Reactions and Reagents. Wiley-VCH,
Weinheim
95. Yudin AK (2010) Catalyzed Carbon-Heteroatom Bond Formation. Wiley-VCH, Weinheim
96. Ley SV, Thomas AW (2003) Modern synthetic methods for copper-mediated C(aryl)-O,
C(aryl)-N, and C(aryl)-S bond formation. Angew Chem Int Ed 42(44):5400–5449
97. Beccalli EM, Broggini G, Martinelli M, Sottocornola S (2007) C-C, C-O, C-N bond formation on sp2 carbon by palladium(II)-catalyzed reactions involving oxidant agents. Chem Rev
107(11):5318–5365
98. Liu C, Zhang H, Shi W, Lei A (2011) Bond formations between two nucleophiles: transition
metal catalyzed oxidative cross-coupling reactions. Chem Rev 111(3):1780–1824
99. Podgorsek A, Zupan M, Iskra J (2009) Oxidative halogenation with “green” oxidants: oxygen
and hydrogen peroxide. Angew Chem Int Ed 48(45):8424–8450
100. Chen X, Hao X-S, Goodhue CE, Yu J-Q (2006) Cu(II)-catalyzed functionalizations of aryl
C-H bonds using O2 as an oxidant. J Am Chem Soc 128(21):6790–6791
101. Wang D-H, Hao X-S, Wu D-F, Yu J-Q (2006) Palladium-catalyzed oxidation of Boc-protected
N-methylamines with IOAc as the oxidant: A Boc-directed sp3 C-H bond activation. Org Lett
8(15):3387–3390
102. Bedford RB, Engelhart JU, Haddow MF, Mitchell CJ, Webster RL (2010) Solvent-free aromatic C-H functionalization/halogenation reactions. Dalton Trans 39(43):10464–10472
103. Song B, Zheng X, Mo J, Xu B (2010) Palladium-catalyzed monoselective halogenation of
C-H bonds: efficient access to halogenated arylpyrimidines using calcium halides. Adv Synth
Catal 352(2+3):329–335
104. Lu Y, Wang R, Qiao X, Shen Z (2011) Copper-catalyzed aromatic C-H bond halogenation
using lithium halides as halogenating reagents. Synlett 7:1038–1042
105. Mo S, Zhu Y, Shen Z (2013) Copper-catalyzed aromatic C-H bond halogenation with lithium
halides under aerobic conditions. Org Biomol Chem 11(17):2756–2760
106. Daugulis O, Roane J, Tran LD (2015) Bidentate, monoanionic auxiliary-directed functionalization of carbon-hydrogen bonds. Acc Chem Res 48(4):1053–1064
107. Truong T, Klimovica K, Daugulis O (2013) Copper-catalyzed, directing group-assisted fluorination of arene and heteroarene C-H bonds. J Am Chem Soc 135(25):9342–9345
108. Sun C-L, Li B-J, Shi Z-J (2010) Pd-catalyzed oxidative coupling with organometallic
reagents via C-H activation. Chem Commun 46(5):677–685
109. Yan G, Jiang Y, Kuang C, Wang S, Liu H, Zhang Y, Wang J (2010) Nano-Fe 2 O 3 -catalyzed
direct borylation of arenes. Chem Commun 46(18):3170–3172
110. Dai H-X, Yu J-Q (2012) Pd-catalyzed oxidative ortho-C-H borylation of arenes. J Am Chem
Soc 134(1):134–137
111. Li H, Li B-J, Shi Z-J (2011) Challenge and progress. Palladium-catalyzed sp3 C-H activation.
Cat Sci Technol 1(2):191–206
112. Hitce J, Retailleau P, Baudoin O (2007) Palladium-catalyzed intramolecular C(sp3)-H functionalization: catalyst development and synthetic applications. Chem Eur J 13(3):792–799
113. Wasa M, Engle KM, Yu J-Q (2010) Cross-coupling of C(sp3)-H bonds with organometallic
reagents via Pd(II)/Pd(0) catalysis. Isr J Chem 50(5–6):605–616
114. He J, Wasa M, Chan KSL, Shao Q, Yu J-Q (2017) Palladium-catalyzed transformations of
alkyl C-H bonds. Chem Rev 117(13):8754–8786
115. Zheng C, You S-L (2014) Recent developments of direct asymmetric functionalization of
inert C-H bonds. RSC Adv 4(12):6173–6214
116. S-l Y, Xia J-B (2010) Palladium-catalyzed aryl-aryl bond formation through double C-H activation. Top Curr Chem 292(C-H Activation):165–194
117. Newton CG, Wang S-G, Oliveira CC, Cramer N (2017) Catalytic enantioselective transformations involving C-H bond cleavage by transition-metal complexes. Chem Rev
117(13):8908–8976
118. Giri R, Shi B-F, Engle KM, Maugel N, Yu J-Q (2009) Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity. Chem Soc Rev 38(11):3242–3272
C. He
94. Zhang Z (2009) Comprehensive Organic Name Reactions and Reagents. Wiley-VCH,
Weinheim
95. Yudin AK (2010) Catalyzed Carbon-Heteroatom Bond Formation. Wiley-VCH, Weinheim
96. Ley SV, Thomas AW (2003) Modern synthetic methods for copper-mediated C(aryl)-O,
C(aryl)-N, and C(aryl)-S bond formation. Angew Chem Int Ed 42(44):5400–5449
97. Beccalli EM, Broggini G, Martinelli M, Sottocornola S (2007) C-C, C-O, C-N bond formation on sp2 carbon by palladium(II)-catalyzed reactions involving oxidant agents. Chem Rev
107(11):5318–5365
98. Liu C, Zhang H, Shi W, Lei A (2011) Bond formations between two nucleophiles: transition
metal catalyzed oxidative cross-coupling reactions. Chem Rev 111(3):1780–1824
99. Podgorsek A, Zupan M, Iskra J (2009) Oxidative halogenation with “green” oxidants: oxygen
and hydrogen peroxide. Angew Chem Int Ed 48(45):8424–8450
100. Chen X, Hao X-S, Goodhue CE, Yu J-Q (2006) Cu(II)-catalyzed functionalizations of aryl
C-H bonds using O2 as an oxidant. J Am Chem Soc 128(21):6790–6791
101. Wang D-H, Hao X-S, Wu D-F, Yu J-Q (2006) Palladium-catalyzed oxidation of Boc-protected
N-methylamines with IOAc as the oxidant: A Boc-directed sp3 C-H bond activation. Org Lett
8(15):3387–3390
102. Bedford RB, Engelhart JU, Haddow MF, Mitchell CJ, Webster RL (2010) Solvent-free aromatic C-H functionalization/halogenation reactions. Dalton Trans 39(43):10464–10472
103. Song B, Zheng X, Mo J, Xu B (2010) Palladium-catalyzed monoselective halogenation of
C-H bonds: efficient access to halogenated arylpyrimidines using calcium halides. Adv Synth
Catal 352(2+3):329–335
104. Lu Y, Wang R, Qiao X, Shen Z (2011) Copper-catalyzed aromatic C-H bond halogenation
using lithium halides as halogenating reagents. Synlett 7:1038–1042
105. Mo S, Zhu Y, Shen Z (2013) Copper-catalyzed aromatic C-H bond halogenation with lithium
halides under aerobic conditions. Org Biomol Chem 11(17):2756–2760
106. Daugulis O, Roane J, Tran LD (2015) Bidentate, monoanionic auxiliary-directed functionalization of carbon-hydrogen bonds. Acc Chem Res 48(4):1053–1064
107. Truong T, Klimovica K, Daugulis O (2013) Copper-catalyzed, directing group-assisted fluorination of arene and heteroarene C-H bonds. J Am Chem Soc 135(25):9342–9345
108. Sun C-L, Li B-J, Shi Z-J (2010) Pd-catalyzed oxidative coupling with organometallic
reagents via C-H activation. Chem Commun 46(5):677–685
109. Yan G, Jiang Y, Kuang C, Wang S, Liu H, Zhang Y, Wang J (2010) Nano-Fe 2 O 3 -catalyzed
direct borylation of arenes. Chem Commun 46(18):3170–3172
110. Dai H-X, Yu J-Q (2012) Pd-catalyzed oxidative ortho-C-H borylation of arenes. J Am Chem
Soc 134(1):134–137
111. Li H, Li B-J, Shi Z-J (2011) Challenge and progress. Palladium-catalyzed sp3 C-H activation.
Cat Sci Technol 1(2):191–206
112. Hitce J, Retailleau P, Baudoin O (2007) Palladium-catalyzed intramolecular C(sp3)-H functionalization: catalyst development and synthetic applications. Chem Eur J 13(3):792–799
113. Wasa M, Engle KM, Yu J-Q (2010) Cross-coupling of C(sp3)-H bonds with organometallic
reagents via Pd(II)/Pd(0) catalysis. Isr J Chem 50(5–6):605–616
114. He J, Wasa M, Chan KSL, Shao Q, Yu J-Q (2017) Palladium-catalyzed transformations of
alkyl C-H bonds. Chem Rev 117(13):8754–8786
115. Zheng C, You S-L (2014) Recent developments of direct asymmetric functionalization of
inert C-H bonds. RSC Adv 4(12):6173–6214
116. S-l Y, Xia J-B (2010) Palladium-catalyzed aryl-aryl bond formation through double C-H activation. Top Curr Chem 292(C-H Activation):165–194
117. Newton CG, Wang S-G, Oliveira CC, Cramer N (2017) Catalytic enantioselective transformations involving C-H bond cleavage by transition-metal complexes. Chem Rev
117(13):8908–8976
118. Giri R, Shi B-F, Engle KM, Maugel N, Yu J-Q (2009) Transition metal-catalyzed C-H activation reactions: diastereoselectivity and enantioselectivity. Chem Soc Rev 38(11):3242–3272
C. He