Molecular Electrochemistry of Coordination Compounds …
437
54. Zhang J, Kuznetsov AM, Medvedev IG, Chi Q, Albrecht T, Jensen PS, Ulstrup J (2008) Singlemolecule electron transfer in electrochemical environments. Chem Rev 108:2737–2791
55. Blumberger J (2015) Recent advances in the theory and molecular simulation of biological
electron transfer reactions. Chem Rev 115:11191–11238. https://doi.org/10.1021/acs.chemrev.
5b00298
56. Creutz C, Taube H (1973) Binuclear complexes of ruthenium ammines. J Am Chem Soc
95:1086–1094. https://doi.org/10.1021/ja00785a016
57. McCleverty JA, Ward MD (1998) The role of bridging ligands in controlling electronic and
magnetic properties in polynuclear complexes. Acc Chem Res 31:842–851. https://doi.org/10.
1021/ar970315s
58. D’Alessandro DM, Keene FR (2006) Current trends and future challenges in the experimental,
theoretical and computational analysis of intervalence charge transfer (IVCT) transitions. Chem
Soc Rev 35:424–440. https://doi.org/10.1039/B514590M
59. Barrière F, Geiger WE (2006) Use of weakly coordinating anions to develop an integrated
approach to the tuning of E 1/2 values by medium effects. J Am Chem Soc 128:3980–3989.
https://doi.org/10.1021/ja058171x
60. Chisholm MH, Feil F, Hadad CM, Patmore NJ (2005) Electronically coupled MM quadruplybonded complexes (M Mo or W) employing functionalized terephthalate bridges: toward
molecular rheostats and switches. J Am Chem Soc 127:18150–18158. https://doi.org/10.1021/
ja0550982
61. Fox MA, Le Guennic B, Roberts RL, Brue DA, Yufit DS, Howard JAK, Manca G, Halet JF, Hartl
F, Low PJ (2011) Simultaneous bridge-localized and mixed-valence character in diruthenium
radical cations featuring diethynylaromatic bridging ligands 133:18433–18446. https://doi.org/
10.1021/ja207827m
62. Roma´ nczyk PP, Noga K, Włodarczyk AJ, Nitek W, Broclawik E (2010) Torsionally controlled
electronic coupling in mixed-valence oxodimolybdenum nitrosyl scorpionates—a DFT study.
Inorg Chem 49:7676–7684. https://doi.org/10.1021/ic100024h
63. Robin MB, Day P (1968) Mixed valence chemistry-a survey and classification. Adv Inorg
Chem Radiochem 10:247–422. https://doi.org/10.1016/S0065-2792(08)60179-X
64. Marcus RA, Sutin N (1985) Electron transfers in chemistry and biology. Biochim Biophys
Acta 811:265–322. https://doi.org/10.1016/0304-4173(85)90014-X
65. Wlodarczyk A, Doyle GA, Maher JP, McCleverty JA, Ward MD (1997) Characterisation of
two different mixed-valence states in a strongly interacting dimolybdenum complex. Chem
Commun 1997:769–770. https://doi.org/10.1039/A608157F
66. Zanello P (2003) Inorganic electrochemistry: theory, practice and application. Royal Society
of Chemistry, Oxford
67. Ventura K, Smith MB, Prat JR, Echegoyen LE, Villagrán D (2017) Introducing students to
inner sphere electron transfer concepts through electrochemistry studies in diferrocene mixedvalence systems. J Chem Educ 94:526–529. https://doi.org/10.1021/acs.jchemed.6b00642
68. Winter RF (2014) Half-wave potential splittings E 1/2 as a measure of electronic coupling in
mixed-valent systems: triumphs and defeats. Organometallics 33:4517–4536. https://doi.org/
10.1021/om500029x
69. Ding F, Wang H, Wu Q, Van Voorhis T, Chen S, Konopelski JP (2010) Computational study
of bridge-assisted intervalence electron transfer. J Phys Chem A 114:6039–6046. https://doi.
org/10.1021/jp912049p
70. Kaduk B, Kowalczyk T, Van Voorhis T (2012) Constrained density functional theory. Chem
Rev 112:321–370. https://doi.org/10.1021/cr200148b
71. Włodarczyk AJ, Roma´ nczyk PP, Kurek SS, Nitek W, McCleverty JA (2008)
Electrochemical interactions in binuclear molybdenum and tungsten nitrosyl complexes incorporating saturated n-alkanediolate bridging ligands. Crystal structures of
[Mo(NO)(Tp Me2 )I{O(CH 2 ) 2 OCOCH 3 }] and [W(NO)(Tp Me2 )I 2 ] 0.5I 2 0.5C 6 H 5 CH 3 . Polyhedron 27:783–796. https://doi.org/10.1016/j.poly.2007.11.008
72. Włodarczyk AJ, Roma´ nczyk PP (2009) Molybdenum doubly bridged and chelate nitrosyl
complexes incorporating saturated n-alkanediolate ligands. Inorg Chim Acta 362:4635–4638.
https://doi.org/10.1016/j.ica.2009.03.032
437
54. Zhang J, Kuznetsov AM, Medvedev IG, Chi Q, Albrecht T, Jensen PS, Ulstrup J (2008) Singlemolecule electron transfer in electrochemical environments. Chem Rev 108:2737–2791
55. Blumberger J (2015) Recent advances in the theory and molecular simulation of biological
electron transfer reactions. Chem Rev 115:11191–11238. https://doi.org/10.1021/acs.chemrev.
5b00298
56. Creutz C, Taube H (1973) Binuclear complexes of ruthenium ammines. J Am Chem Soc
95:1086–1094. https://doi.org/10.1021/ja00785a016
57. McCleverty JA, Ward MD (1998) The role of bridging ligands in controlling electronic and
magnetic properties in polynuclear complexes. Acc Chem Res 31:842–851. https://doi.org/10.
1021/ar970315s
58. D’Alessandro DM, Keene FR (2006) Current trends and future challenges in the experimental,
theoretical and computational analysis of intervalence charge transfer (IVCT) transitions. Chem
Soc Rev 35:424–440. https://doi.org/10.1039/B514590M
59. Barrière F, Geiger WE (2006) Use of weakly coordinating anions to develop an integrated
approach to the tuning of E 1/2 values by medium effects. J Am Chem Soc 128:3980–3989.
https://doi.org/10.1021/ja058171x
60. Chisholm MH, Feil F, Hadad CM, Patmore NJ (2005) Electronically coupled MM quadruplybonded complexes (M Mo or W) employing functionalized terephthalate bridges: toward
molecular rheostats and switches. J Am Chem Soc 127:18150–18158. https://doi.org/10.1021/
ja0550982
61. Fox MA, Le Guennic B, Roberts RL, Brue DA, Yufit DS, Howard JAK, Manca G, Halet JF, Hartl
F, Low PJ (2011) Simultaneous bridge-localized and mixed-valence character in diruthenium
radical cations featuring diethynylaromatic bridging ligands 133:18433–18446. https://doi.org/
10.1021/ja207827m
62. Roma´ nczyk PP, Noga K, Włodarczyk AJ, Nitek W, Broclawik E (2010) Torsionally controlled
electronic coupling in mixed-valence oxodimolybdenum nitrosyl scorpionates—a DFT study.
Inorg Chem 49:7676–7684. https://doi.org/10.1021/ic100024h
63. Robin MB, Day P (1968) Mixed valence chemistry-a survey and classification. Adv Inorg
Chem Radiochem 10:247–422. https://doi.org/10.1016/S0065-2792(08)60179-X
64. Marcus RA, Sutin N (1985) Electron transfers in chemistry and biology. Biochim Biophys
Acta 811:265–322. https://doi.org/10.1016/0304-4173(85)90014-X
65. Wlodarczyk A, Doyle GA, Maher JP, McCleverty JA, Ward MD (1997) Characterisation of
two different mixed-valence states in a strongly interacting dimolybdenum complex. Chem
Commun 1997:769–770. https://doi.org/10.1039/A608157F
66. Zanello P (2003) Inorganic electrochemistry: theory, practice and application. Royal Society
of Chemistry, Oxford
67. Ventura K, Smith MB, Prat JR, Echegoyen LE, Villagrán D (2017) Introducing students to
inner sphere electron transfer concepts through electrochemistry studies in diferrocene mixedvalence systems. J Chem Educ 94:526–529. https://doi.org/10.1021/acs.jchemed.6b00642
68. Winter RF (2014) Half-wave potential splittings E 1/2 as a measure of electronic coupling in
mixed-valent systems: triumphs and defeats. Organometallics 33:4517–4536. https://doi.org/
10.1021/om500029x
69. Ding F, Wang H, Wu Q, Van Voorhis T, Chen S, Konopelski JP (2010) Computational study
of bridge-assisted intervalence electron transfer. J Phys Chem A 114:6039–6046. https://doi.
org/10.1021/jp912049p
70. Kaduk B, Kowalczyk T, Van Voorhis T (2012) Constrained density functional theory. Chem
Rev 112:321–370. https://doi.org/10.1021/cr200148b
71. Włodarczyk AJ, Roma´ nczyk PP, Kurek SS, Nitek W, McCleverty JA (2008)
Electrochemical interactions in binuclear molybdenum and tungsten nitrosyl complexes incorporating saturated n-alkanediolate bridging ligands. Crystal structures of
[Mo(NO)(Tp Me2 )I{O(CH 2 ) 2 OCOCH 3 }] and [W(NO)(Tp Me2 )I 2 ] 0.5I 2 0.5C 6 H 5 CH 3 . Polyhedron 27:783–796. https://doi.org/10.1016/j.poly.2007.11.008
72. Włodarczyk AJ, Roma´ nczyk PP (2009) Molybdenum doubly bridged and chelate nitrosyl
complexes incorporating saturated n-alkanediolate ligands. Inorg Chim Acta 362:4635–4638.
https://doi.org/10.1016/j.ica.2009.03.032