Molecular Electrochemistry of Coordination Compounds …
435
16. Konezny SJ, Doherty MD, Luca OR, Crabtree RH, Soloveichik GL, Batista VS (2012) Reduction of systematic uncertainty in DFT redox potentials of transition-metal complexes. J Phys
Chem C 116:6349–6356. https://doi.org/10.1021/jp300485t
17. Shi Y, Fang L, Li X, Qu L, Shao H (2015) The observation of ion-pairing effect based on
substituent effect of ferrocene derivatives. J Electroanal Chem 757:258–262. https://doi.org/
10.1016/j.jelechem.2015.10.003
18. Diggle JW, Parker AJ (1974) Liquid junction potential in electrochemical cells involving a
dissimilar solvent junction. Aust J Chem 27:1617–1621. https://doi.org/10.1071/CH9741617
19. Izutsu K (2011) Liquid junction potential between electrolyte solutions in different solvents.
Anal Sci 27:685–694. https://doi.org/10.2116/analsci.27.685
20. Radtke V, Ermantraut A, Himmel D, Koslowski T, Leito I, Krossing I (2018) The Ideal ionic
liquid salt bridge for the direct determination of gibbs energies of transfer of single ions, part
I: the concept. Angew Chem Int Ed 57:2344–2347. https://doi.org/10.1002/anie.201707333
21. Mousavi MPS, Saba SA, Anderson EL, Hillmyer MA, Bühlmann P (2016) Avoiding errors
in electrochemical measurements: effect of frit material on the performance of reference
electrodes with porous frit junctions. Anal Chem 88:8706–8713. https://doi.org/10.1021/acs.
analchem.6b02025
22. Gritzner G, Kuta J (1984) Recommendations on reporting electrode potentials in nonaqueous
solvents. Pure Appl Chem 56:461–466. https://doi.org/10.1351/pac19845604046
23. Gritzner G (2013) Reference redox systems in nonaqueous systems and the relation of electrode potentials in nonaqueous and mixed solvents to standard potential in water. In: Inzelt G,
Lewenstam A, Scholz F (eds) Handbook of reference electrodes. Springer, Berlin Heidelberg,
pp 25–31. https://doi.org/10.1007/978-3-642-36188-3_2
24. Koepp H-M, Wendt H, Strehlow H (1960) Der Vergleich der Spannungsreihen in verschiedenen
Solventien. II. Z Elektrochem 64:483–491. https://doi.org/10.1002/bbpc.19600640406
25. Namazian M, Lin CY, Coote ML (2010) Benchmark calculations of absolute reduction potential
of ferricinium/ferrocene couple in nonaqueous solutions. J Chem Theory Comput 6:2721–2725.
https://doi.org/10.1021/ct1003252
26. Marenich AV, Cramer CJ, Truhlar DG (2013) Generalized born solvation model SM12. J Chem
Theory Comput 9:609–620. https://doi.org/10.1021/ct300900e
27. Noviandri I, Brown KN, Fleming DS, Gulyas PT, Lay PA, Masters AF, Phillips L (1999) The
decamethylferrocenium/decamethylferrocene redox couple: a superior redox standard to the
ferrocenium/ferrocene redox couple for studying solvent effects on the thermodynamics of
electron transfer. J Phys Chem B 103:6713–6722. https://doi.org/10.1021/jp991381+
28. Tsierkezos NG (2007) Cyclic voltammetric studies of ferrocene in nonaqueous solvents in
the temperature range from 248.15 to 298.15 K. J Solut Chem 36:289–302. https://doi.org/10.
1007/s10953-006-9119-9
29. Krishtalik LI (2008) Solvation energy of metallocenes pilot ions: Beyond the Born approximation. Electrochim Acta 53:3722–3733. https://doi.org/10.1016/j.electacta.2007.10.026
30. ADF Program System, release 2017.105; Scientific computing & modelling NV, Vrije Universiteit: Amsterdam, The Netherlands
31. Connelly NG, Geiger WE (1996) Chemical redox agents for organometallic chemistry. Chem
Rev 96:877–910. https://doi.org/10.1021/cr940053x
32. McCleverty JA, Ward MD, Jones CJ (2001) Redox-activity in complexes with Mo(NO) and
Mo(O) cores: facts and consequences. Comments Inorg Chem 22:293–326. https://doi.org/10.
1080/02603590108050873
33. Enemark JH, Cooney JJA, Wang JJ, Holm RH (2004) Synthetic analogues and reaction systems
relevant to the molybdenum and tungsten oxotransferases. Chem Rev 104:1175–1200. https://
doi.org/10.1021/cr020609d
34. Young CG (2016) Scorpionate complexes as models for molybdenum enzymes. Eur J Inorg
Chem 2016:2357–2376. https://doi.org/10.1002/ejic.201501387
35. Roma´ nczyk PP, Radon M, Noga K, Kurek SS (2013) Autocatalytic cathodic dehalogenation
triggered by dissociative electron transfer through a C−H···O hydrogen bond. Phys Chem
Chem Phys 15:17522–17536. https://doi.org/10.1039/C3CP52933A
435
16. Konezny SJ, Doherty MD, Luca OR, Crabtree RH, Soloveichik GL, Batista VS (2012) Reduction of systematic uncertainty in DFT redox potentials of transition-metal complexes. J Phys
Chem C 116:6349–6356. https://doi.org/10.1021/jp300485t
17. Shi Y, Fang L, Li X, Qu L, Shao H (2015) The observation of ion-pairing effect based on
substituent effect of ferrocene derivatives. J Electroanal Chem 757:258–262. https://doi.org/
10.1016/j.jelechem.2015.10.003
18. Diggle JW, Parker AJ (1974) Liquid junction potential in electrochemical cells involving a
dissimilar solvent junction. Aust J Chem 27:1617–1621. https://doi.org/10.1071/CH9741617
19. Izutsu K (2011) Liquid junction potential between electrolyte solutions in different solvents.
Anal Sci 27:685–694. https://doi.org/10.2116/analsci.27.685
20. Radtke V, Ermantraut A, Himmel D, Koslowski T, Leito I, Krossing I (2018) The Ideal ionic
liquid salt bridge for the direct determination of gibbs energies of transfer of single ions, part
I: the concept. Angew Chem Int Ed 57:2344–2347. https://doi.org/10.1002/anie.201707333
21. Mousavi MPS, Saba SA, Anderson EL, Hillmyer MA, Bühlmann P (2016) Avoiding errors
in electrochemical measurements: effect of frit material on the performance of reference
electrodes with porous frit junctions. Anal Chem 88:8706–8713. https://doi.org/10.1021/acs.
analchem.6b02025
22. Gritzner G, Kuta J (1984) Recommendations on reporting electrode potentials in nonaqueous
solvents. Pure Appl Chem 56:461–466. https://doi.org/10.1351/pac19845604046
23. Gritzner G (2013) Reference redox systems in nonaqueous systems and the relation of electrode potentials in nonaqueous and mixed solvents to standard potential in water. In: Inzelt G,
Lewenstam A, Scholz F (eds) Handbook of reference electrodes. Springer, Berlin Heidelberg,
pp 25–31. https://doi.org/10.1007/978-3-642-36188-3_2
24. Koepp H-M, Wendt H, Strehlow H (1960) Der Vergleich der Spannungsreihen in verschiedenen
Solventien. II. Z Elektrochem 64:483–491. https://doi.org/10.1002/bbpc.19600640406
25. Namazian M, Lin CY, Coote ML (2010) Benchmark calculations of absolute reduction potential
of ferricinium/ferrocene couple in nonaqueous solutions. J Chem Theory Comput 6:2721–2725.
https://doi.org/10.1021/ct1003252
26. Marenich AV, Cramer CJ, Truhlar DG (2013) Generalized born solvation model SM12. J Chem
Theory Comput 9:609–620. https://doi.org/10.1021/ct300900e
27. Noviandri I, Brown KN, Fleming DS, Gulyas PT, Lay PA, Masters AF, Phillips L (1999) The
decamethylferrocenium/decamethylferrocene redox couple: a superior redox standard to the
ferrocenium/ferrocene redox couple for studying solvent effects on the thermodynamics of
electron transfer. J Phys Chem B 103:6713–6722. https://doi.org/10.1021/jp991381+
28. Tsierkezos NG (2007) Cyclic voltammetric studies of ferrocene in nonaqueous solvents in
the temperature range from 248.15 to 298.15 K. J Solut Chem 36:289–302. https://doi.org/10.
1007/s10953-006-9119-9
29. Krishtalik LI (2008) Solvation energy of metallocenes pilot ions: Beyond the Born approximation. Electrochim Acta 53:3722–3733. https://doi.org/10.1016/j.electacta.2007.10.026
30. ADF Program System, release 2017.105; Scientific computing & modelling NV, Vrije Universiteit: Amsterdam, The Netherlands
31. Connelly NG, Geiger WE (1996) Chemical redox agents for organometallic chemistry. Chem
Rev 96:877–910. https://doi.org/10.1021/cr940053x
32. McCleverty JA, Ward MD, Jones CJ (2001) Redox-activity in complexes with Mo(NO) and
Mo(O) cores: facts and consequences. Comments Inorg Chem 22:293–326. https://doi.org/10.
1080/02603590108050873
33. Enemark JH, Cooney JJA, Wang JJ, Holm RH (2004) Synthetic analogues and reaction systems
relevant to the molybdenum and tungsten oxotransferases. Chem Rev 104:1175–1200. https://
doi.org/10.1021/cr020609d
34. Young CG (2016) Scorpionate complexes as models for molybdenum enzymes. Eur J Inorg
Chem 2016:2357–2376. https://doi.org/10.1002/ejic.201501387
35. Roma´ nczyk PP, Radon M, Noga K, Kurek SS (2013) Autocatalytic cathodic dehalogenation
triggered by dissociative electron transfer through a C−H···O hydrogen bond. Phys Chem
Chem Phys 15:17522–17536. https://doi.org/10.1039/C3CP52933A