26
K. P. Kepp
4. Brooker S (2015) Spin crossover with thermal hysteresis: practicalities and lessons learnt.
Chem Soc Rev 44:2880–2892
5. Gütlich P, Garcia Y, Goodwin HA (2000) Spin crossover phenomena in Fe(II) complexes.
Chem Soc Rev 29:419–427
6. Harding DJ, Harding P, Phonsri W (2016) Spin crossover in iron (III) complexes. Coord Chem
Rev 313:38–61
7. Kumar KS, Ruben M (2017) Emerging trends in spin crossover (SCO) based functional
materials and devices. Coord Chem Rev 346:176–205
8. Guionneau P (2014) Crystallography and spin-crossover. A view of breathing materials. Dalt
Trans 43:382–393
9. Ruiz E (2014) Charge transport properties of spin crossover systems. Phys Chem Chem Phys
16:14–22
10. Cambi L, Szegö L (1931) Über die magnetische Susceptibilität der komplexen Verbindungen.
Berichte der Dtsch Chem Gesellschaft A B Ser 64:2591–2598
11. Šalitroš I, Madhu NT, Boˇ ca R, Pavlik J, Ruben M (2009) Room-temperature spin-transition
iron compounds. Chem Mon 140:695–733
12. Kepp KP (2017) Heme: from quantum spin crossover to oxygen manager of life. Coord Chem
Rev 344:363–374
13. Scheidt WR, Reed CA (1981) Spin-state/stereochemical relationships in iron porphyrins:
implications for the hemoproteins. Chem Rev 81:543–555
14. Jensen KP, Ryde U (2004) How O 2 binds to heme: reasons for rapid binding and spin inversion.
J Biol Chem 279:14561–14569
15. Gaspar AB, Muñoz MC, Real JA (2006) Dinuclear iron (II) spin crossover compounds:
singular molecular materials for electronics. J Mater Chem 16:2522–2533
16. Bousseksou A, Molnár G, Demont P, Menegotto J (2003) Observation of a thermal hysteresis loop in the dielectric constant of spin crossover complexes: towards molecular memory
devices. J Mater Chem 13:2069–2071
17. Miyamachi T, Gruber M, Davesne V, Bowen M, Boukari S, Joly L, Scheurer F, Rogez G,
Yamada TK, Ohresser P (2012) Robust spin crossover and memristance across a single
molecule. Nat Commun 3:938
18. Linares J, Codjovi E, Garcia Y (2012) Pressure and temperature spin crossover sensors with
optical detection. Sensors 12:4479–4492
19. Salmon L, Molnár G, Zitouni D, Quintero C, Bergaud C, Micheau J-C, Bousseksou A (2010)
A novel approach for fluorescent thermometry and thermal imaging purposes using spin
crossover nanoparticles. J Mater Chem 20:5499–5503
20. Bartual-Murgui C, Akou A, Thibault C, Molnár G, Vieu C, Salmon L, Bousseksou A (2015)
Spin-crossover metal–organic frameworks: promising materials for designing gas sensors. J
Mater Chem C 3:1277–1285
21. Manrique-Juarez MD, Mathieu F, Shalabaeva V, Cacheux J, Rat S, Nicu L, Leïchlé T, Salmon
L, Molnár G, Bousseksou A (2017) A bistable microelectromechanical system actuated by
spin-crossover molecules. Angew Chem 129:8186–8190
22. Shepherd HJ, Il’ya A, Quintero CM, Tricard S, Salmon L, Molnár G, Bousseksou A (2013)
Molecular actuators driven by cooperative spin-state switching. Nat Commun 4:2607
23. Harvey JN, Poli R, Smith KM (2003) Understanding the reactivity of transition metal complexes involving multiple spin states. Coord Chem Rev 238:347–361
24. Sorai M, Nakano M, Miyazaki Y (2006) Calorimetric investigation of phase transitions occurring in molecule-based magnets. Chem Rev 106:976–1031
25. Molnár G, Salmon L, Nicolazzi W, Terki F, Bousseksou A (2014) Emerging properties and
applications of spin crossover nanomaterials. J Mater Chem C 2:1360–1366
26. Liu T, Zheng H, Kang S, Shiota Y, Hayami S, Mito M, Sato O, Yoshizawa K, Kanegawa S,
Duan C (2013) A light-induced spin crossover actuated single-chain magnet. Nat. Commun.
4:2826
27. Cirera J, Ruiz E (2015) Theoretical modeling of two-step spin-crossover transitions in Fe II
dinuclear systems. J Mater Chem C 3:7954–7961
K. P. Kepp
4. Brooker S (2015) Spin crossover with thermal hysteresis: practicalities and lessons learnt.
Chem Soc Rev 44:2880–2892
5. Gütlich P, Garcia Y, Goodwin HA (2000) Spin crossover phenomena in Fe(II) complexes.
Chem Soc Rev 29:419–427
6. Harding DJ, Harding P, Phonsri W (2016) Spin crossover in iron (III) complexes. Coord Chem
Rev 313:38–61
7. Kumar KS, Ruben M (2017) Emerging trends in spin crossover (SCO) based functional
materials and devices. Coord Chem Rev 346:176–205
8. Guionneau P (2014) Crystallography and spin-crossover. A view of breathing materials. Dalt
Trans 43:382–393
9. Ruiz E (2014) Charge transport properties of spin crossover systems. Phys Chem Chem Phys
16:14–22
10. Cambi L, Szegö L (1931) Über die magnetische Susceptibilität der komplexen Verbindungen.
Berichte der Dtsch Chem Gesellschaft A B Ser 64:2591–2598
11. Šalitroš I, Madhu NT, Boˇ ca R, Pavlik J, Ruben M (2009) Room-temperature spin-transition
iron compounds. Chem Mon 140:695–733
12. Kepp KP (2017) Heme: from quantum spin crossover to oxygen manager of life. Coord Chem
Rev 344:363–374
13. Scheidt WR, Reed CA (1981) Spin-state/stereochemical relationships in iron porphyrins:
implications for the hemoproteins. Chem Rev 81:543–555
14. Jensen KP, Ryde U (2004) How O 2 binds to heme: reasons for rapid binding and spin inversion.
J Biol Chem 279:14561–14569
15. Gaspar AB, Muñoz MC, Real JA (2006) Dinuclear iron (II) spin crossover compounds:
singular molecular materials for electronics. J Mater Chem 16:2522–2533
16. Bousseksou A, Molnár G, Demont P, Menegotto J (2003) Observation of a thermal hysteresis loop in the dielectric constant of spin crossover complexes: towards molecular memory
devices. J Mater Chem 13:2069–2071
17. Miyamachi T, Gruber M, Davesne V, Bowen M, Boukari S, Joly L, Scheurer F, Rogez G,
Yamada TK, Ohresser P (2012) Robust spin crossover and memristance across a single
molecule. Nat Commun 3:938
18. Linares J, Codjovi E, Garcia Y (2012) Pressure and temperature spin crossover sensors with
optical detection. Sensors 12:4479–4492
19. Salmon L, Molnár G, Zitouni D, Quintero C, Bergaud C, Micheau J-C, Bousseksou A (2010)
A novel approach for fluorescent thermometry and thermal imaging purposes using spin
crossover nanoparticles. J Mater Chem 20:5499–5503
20. Bartual-Murgui C, Akou A, Thibault C, Molnár G, Vieu C, Salmon L, Bousseksou A (2015)
Spin-crossover metal–organic frameworks: promising materials for designing gas sensors. J
Mater Chem C 3:1277–1285
21. Manrique-Juarez MD, Mathieu F, Shalabaeva V, Cacheux J, Rat S, Nicu L, Leïchlé T, Salmon
L, Molnár G, Bousseksou A (2017) A bistable microelectromechanical system actuated by
spin-crossover molecules. Angew Chem 129:8186–8190
22. Shepherd HJ, Il’ya A, Quintero CM, Tricard S, Salmon L, Molnár G, Bousseksou A (2013)
Molecular actuators driven by cooperative spin-state switching. Nat Commun 4:2607
23. Harvey JN, Poli R, Smith KM (2003) Understanding the reactivity of transition metal complexes involving multiple spin states. Coord Chem Rev 238:347–361
24. Sorai M, Nakano M, Miyazaki Y (2006) Calorimetric investigation of phase transitions occurring in molecule-based magnets. Chem Rev 106:976–1031
25. Molnár G, Salmon L, Nicolazzi W, Terki F, Bousseksou A (2014) Emerging properties and
applications of spin crossover nanomaterials. J Mater Chem C 2:1360–1366
26. Liu T, Zheng H, Kang S, Shiota Y, Hayami S, Mito M, Sato O, Yoshizawa K, Kanegawa S,
Duan C (2013) A light-induced spin crossover actuated single-chain magnet. Nat. Commun.
4:2826
27. Cirera J, Ruiz E (2015) Theoretical modeling of two-step spin-crossover transitions in Fe II
dinuclear systems. J Mater Chem C 3:7954–7961