development of highly efficient and stable photocatalyst and the study of the
reason of catalysts’ deactivation are important.
References
1. Marszewski M, Cao S, Yu J, Jaroniec M (2015) Semiconductor-based photocatalytic CO 2
conversion. Mater Horiz 2(3):261–278
2. Walsh B, Ciais P, Janssens IA, JP ˜u, Riahi K, Rydzak F, DPv V, Obersteiner M (2017)
Pathways for balancing CO 2 emissions and sinks. Nat Commun 8:14856–14868
3. Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38
4. Ma Y, Wang X, Jia Y, Chen X, Han H, Li C (2014) Titanium dioxide-based nanomaterials for
photocatalytic fuel generations. Chem Rev 114(19):9987–10043
5. Habisreutinger SN, Schmidt-Mende L, Stolarczyk JK (2013) Photocatalytic reduction of CO 2
on TiO 2 and other semiconductors. Angew Chem Int Ed 52(29):7372–7408
6. Dong C, Xing M, Zhang J (2016) Economic hydrophobicity triggering of CO 2 photoreduction
for selective CH 4 generation on noble-metal-free TiO 2 -SiO 2 . J Phys Chem Lett 7:2962–2966
7. Li K, Peng B, Peng T (2016) Recent advances in heterogeneous photocatalytic CO 2 conversion
to solar fuels. ACS Catal 6:7485–7527
8. Dong C, Xing M, Zhang J (2016) Double-cocatalysts promote charge separation efficiency in
CO 2 photoreduction: spatial location matters. Mater Horiz 3(6):608–612
9. Wang W, An WJ, Ramalingam B, Mukherjee S, Niedzwiedzki DM, Gangopadhyay S, Biswas P
(2012) Size and structure matter: enhanced CO 2 photoreduction efficiency by size-resolved
ultrafine Pt nanoparticles on TiO 2 single crystals. J Am Chem Soc 134(27):11276–11281
10. Xie S, Wang Y, Zhang Q, Deng W, Wang Y (2014) MgO- and Pt-promoted TiO 2 as an efficient
photocatalyst for the preferential reduction of carbon dioxide in the presence of water. ACS
Catal 4(10):3644–3653
11. Feng X, Sloppy JD, LaTempa TJ et al (2011) Synthesis and deposition of ultrafine Pt
nanoparticles within high aspect ratio TiO 2 nanotube arrays: application to the photocatalytic
reduction of carbon dioxide. J Mater Chem 21:13429–13433
12. Manzi A, Simon T, Sonnleitner C, Doblinger M, Wyrwich R, Stern O, Stolarczyk JK, Feldmann
J (2015) Light-induced cation exchange for copper sulfide based CO 2 reduction. J Am Chem
Soc 137(44):14007–14010
13. Mao J, Ye L, Li K et al (2014) Pt-loading reverses the photocatalytic activity order of anatase
TiO 2 {001} and {010} facets for photoreduction of CO 2 to CH 4 . Appl Catal B-Environ
144:855–862
14. Neatu S, Macia-Agullo JA, Concepcion P, Garcia H (2014) Gold-copper nanoalloys supported
on TiO 2 as photocatalysts for CO 2 reduction by water. J Am Chem Soc 136(45):15969–15976
15. Bai S, Wang X, Hu C, Xie M, Jiang J, Xiong Y (2014) Two-dimensional g-C 3 N 4 : an ideal
platform for examining facet selectivity of metal co-catalysts in photocatalysis. Chem Commun
(Camb) 50(46):6094–6097
16. Zhu Y, Xu Z, Jiang W et al (2017) Engineering on the edge of Pd nanosheet cocatalysts for
enhanced photocatalytic reduction of CO 2 to fuels. J Mater Chem A 5(6):2619–2628
17. Li N, Liu M, Yang B et al (2017) Enhanced photocatalytic performance toward CO 2 hydrogenation over nanosized TiO 2 -loaded Pd under UV irradiation. J Phys Chem C 121(5):2923–2932
18. Long R, Li Y, Liu Y et al (2017) Isolation of Cu atoms in Pd lattice: forming highly selective
sitesfor photocatalytic conversion of CO 2 to CH 4 . J Am Chem Soc 139:4486–4492
19. Kong D, Tan JZY, Yang F, Zeng J, Zhang X (2013) Electrodeposited Ag nanoparticles on TiO 2
nanorods for enhanced UV visible light photoreduction CO 2 to CH 4 . Appl Surf Sci
277:105–110
302
12 Roles and Properties of Cocatalysts in Semiconductor-Based Materials. . .
reason of catalysts’ deactivation are important.
References
1. Marszewski M, Cao S, Yu J, Jaroniec M (2015) Semiconductor-based photocatalytic CO 2
conversion. Mater Horiz 2(3):261–278
2. Walsh B, Ciais P, Janssens IA, JP ˜u, Riahi K, Rydzak F, DPv V, Obersteiner M (2017)
Pathways for balancing CO 2 emissions and sinks. Nat Commun 8:14856–14868
3. Fujishima A, Honda K (1972) Electrochemical photolysis of water at a semiconductor electrode. Nature 238:37–38
4. Ma Y, Wang X, Jia Y, Chen X, Han H, Li C (2014) Titanium dioxide-based nanomaterials for
photocatalytic fuel generations. Chem Rev 114(19):9987–10043
5. Habisreutinger SN, Schmidt-Mende L, Stolarczyk JK (2013) Photocatalytic reduction of CO 2
on TiO 2 and other semiconductors. Angew Chem Int Ed 52(29):7372–7408
6. Dong C, Xing M, Zhang J (2016) Economic hydrophobicity triggering of CO 2 photoreduction
for selective CH 4 generation on noble-metal-free TiO 2 -SiO 2 . J Phys Chem Lett 7:2962–2966
7. Li K, Peng B, Peng T (2016) Recent advances in heterogeneous photocatalytic CO 2 conversion
to solar fuels. ACS Catal 6:7485–7527
8. Dong C, Xing M, Zhang J (2016) Double-cocatalysts promote charge separation efficiency in
CO 2 photoreduction: spatial location matters. Mater Horiz 3(6):608–612
9. Wang W, An WJ, Ramalingam B, Mukherjee S, Niedzwiedzki DM, Gangopadhyay S, Biswas P
(2012) Size and structure matter: enhanced CO 2 photoreduction efficiency by size-resolved
ultrafine Pt nanoparticles on TiO 2 single crystals. J Am Chem Soc 134(27):11276–11281
10. Xie S, Wang Y, Zhang Q, Deng W, Wang Y (2014) MgO- and Pt-promoted TiO 2 as an efficient
photocatalyst for the preferential reduction of carbon dioxide in the presence of water. ACS
Catal 4(10):3644–3653
11. Feng X, Sloppy JD, LaTempa TJ et al (2011) Synthesis and deposition of ultrafine Pt
nanoparticles within high aspect ratio TiO 2 nanotube arrays: application to the photocatalytic
reduction of carbon dioxide. J Mater Chem 21:13429–13433
12. Manzi A, Simon T, Sonnleitner C, Doblinger M, Wyrwich R, Stern O, Stolarczyk JK, Feldmann
J (2015) Light-induced cation exchange for copper sulfide based CO 2 reduction. J Am Chem
Soc 137(44):14007–14010
13. Mao J, Ye L, Li K et al (2014) Pt-loading reverses the photocatalytic activity order of anatase
TiO 2 {001} and {010} facets for photoreduction of CO 2 to CH 4 . Appl Catal B-Environ
144:855–862
14. Neatu S, Macia-Agullo JA, Concepcion P, Garcia H (2014) Gold-copper nanoalloys supported
on TiO 2 as photocatalysts for CO 2 reduction by water. J Am Chem Soc 136(45):15969–15976
15. Bai S, Wang X, Hu C, Xie M, Jiang J, Xiong Y (2014) Two-dimensional g-C 3 N 4 : an ideal
platform for examining facet selectivity of metal co-catalysts in photocatalysis. Chem Commun
(Camb) 50(46):6094–6097
16. Zhu Y, Xu Z, Jiang W et al (2017) Engineering on the edge of Pd nanosheet cocatalysts for
enhanced photocatalytic reduction of CO 2 to fuels. J Mater Chem A 5(6):2619–2628
17. Li N, Liu M, Yang B et al (2017) Enhanced photocatalytic performance toward CO 2 hydrogenation over nanosized TiO 2 -loaded Pd under UV irradiation. J Phys Chem C 121(5):2923–2932
18. Long R, Li Y, Liu Y et al (2017) Isolation of Cu atoms in Pd lattice: forming highly selective
sitesfor photocatalytic conversion of CO 2 to CH 4 . J Am Chem Soc 139:4486–4492
19. Kong D, Tan JZY, Yang F, Zeng J, Zhang X (2013) Electrodeposited Ag nanoparticles on TiO 2
nanorods for enhanced UV visible light photoreduction CO 2 to CH 4 . Appl Surf Sci
277:105–110
302
12 Roles and Properties of Cocatalysts in Semiconductor-Based Materials. . .