42. Bundhun A, Ramasami P, Murray JS, Politzer P (2012) Trends in σ-hole strengths and
interactions of F3MX molecules (M = C, Si, Ge and X = F, Cl, Br, I). J Mol Mod 19:2739–
2746
43. Bauzá A, Mooibroek TJ, Frontera A (2013) Tetrel-bonding interaction rediscovered
supramolecular force ? Angew Chem Int Ed Engl 52:12317–12321
44. Mani D, Arunan E (2013) The X-C…Y (X = O/F, Y = O/S/F/Cl/Br/N/P) ‘carbon bond’ and
hydrophobic interactions. Phys Chem Chem Phys 15:14377–14383
45. Grabowski SJ (2014) Tetrel bond—σ-hole bond as a preliminary stage of the S N 2 reaction.
Phys Chem Chem Phys 16:1824–1834
46. Sundberg MR, Uggla R, Viñas C, Teixidor F, Paavola S, Kivekäs R (2007) Nature of
intramolecular interactions in hypercoordinate C-substituted 1,2-dicarba-closo-dodecaboranes
with short P…P distances. Inorg Chem Commun 10:713–716
47. Bauer S, Tschirschwitz S, Lönnecke P, Franck R, Kirchner B, Clark ML, Hey-Hawkins E
(2009) Enantiomerically Pure Bis(phosphanyl)carbaborane(12) Compounds. Eur J Inorg
Chem 2776–2788
48. Del Bene JE, Alkorta I, Sanchez-Sanz G, Elguero J (2011) Structures, energies, bonding, and
NMR properties of pnicogen complexes H 2 XP:NXH 2 (X = H, CH 3 , NH 2 , OH, F, Cl). J Phys
Chem A 115:13724–13731
49. Scheiner S (2011) Can two trivalent N atoms engage in a direct N…N noncovalent
interaction? Chem Phys Lett 514:32–35
50. Grabowski SJ (2013) σ-Hole bond versus hydrogen bond: from tetravalent to pentavalent N, P,
and as atoms. Chem Eur J 19:14600–14611
51. Sanz P, Yañez M, Mó O (2002) Competition between X…H…Y intramolecular hydrogen
bonds and X…Y (X = O, S, and Y = Se, Te) chalcogen-chalcogen interactions. J Phys
Chem A 106:4661–4668
52. Wang W, Ji B, Zhang Y (2009) Chalcogen bond: a sister noncovalent bond to halogen bond.
J Phys Chem A 113:8132–8135
53. Alikhani E, Fuster F, Madebene B, Grabowski SJ (2014) Topological reaction sites—very
strong chalcogen bonds. Phys Chem Chem Phys 16:2430–2442
54. Del Bene JE, Alkorta I, Sánchez-Sanz G, Elguero J (2011)
31
P31
P Spin-Spin coupling
constants for pnicogen homodimers. Chem Phys Lett 512:184–187
55. Del Bene JE, Alkorta I, Elguero J (2015) Substituent effects on the properties of
pnicogen-bonded complexes H 2 XP:PYH 2 , for X, Y = F, Cl, OH, NC, CCH, CH 3 , CN, and
H. J Phys Chem A 119:224–233
56. Eskandari K, Mahmoodabadi N (2013) Pnicogen bonds: a theoretical study based on the
laplacian of electron density. J Phys Chem A 117:13018–13024
57. Eskandari K, Zariny H (2010) Halogen bonding: a lump-hole interaction. Chem Phys Lett
492:9–13
58. Bento AP, Solà M, Bickelhaupt FM (2005) Ab initio and DFT benchmark study for
nucleophilic substitution at carbon (S N 2@C) and silicon (S N 2@Si). J Comput Chem 26:1497–
1504
59. Pierrefixe SCAH, Guerra CF, Bickelhaupt FM (2008) Hypervalent silicon versus carbon:
ball-in-a-box model. Chem Eur J 14:819–828
60. Levy CJ, Puddephatt RJ (1997) Rapid reversible oxidative addition of group 14-halide bonds
to platinum(ii): rates, equilibria, and bond energies. J Am Chem Soc 119:10127–10136
61. Grabowski SJ (2014) Clusters of ammonium cation–hydrogen bond versus σ-hole bond.
ChemPhysChem 15:876–884
62. Murray JS, Riley KE, Politzer P, Clark T (2010) Directional weak intermolecular interactions:
σ-hole bonding. Aust J Chem 63:1598–1607
63. Lipkowski P, Grabowski SJ (2014) Could the lithium bond be classified as the σ-hole bond?—
QTAIM and NBO analysis. Chem Phys Lett 591:113–118
64. Allen FH (2002) The cambridge structural database: a quarter of a million crystal structures
and rising. Acta Cryst B58:380–388
65. http://www.ccdc.cam.ac.uk/Lists/ResourceFileList/2014_stats_entries.pdf
432
S.J. Grabowski
interactions of F3MX molecules (M = C, Si, Ge and X = F, Cl, Br, I). J Mol Mod 19:2739–
2746
43. Bauzá A, Mooibroek TJ, Frontera A (2013) Tetrel-bonding interaction rediscovered
supramolecular force ? Angew Chem Int Ed Engl 52:12317–12321
44. Mani D, Arunan E (2013) The X-C…Y (X = O/F, Y = O/S/F/Cl/Br/N/P) ‘carbon bond’ and
hydrophobic interactions. Phys Chem Chem Phys 15:14377–14383
45. Grabowski SJ (2014) Tetrel bond—σ-hole bond as a preliminary stage of the S N 2 reaction.
Phys Chem Chem Phys 16:1824–1834
46. Sundberg MR, Uggla R, Viñas C, Teixidor F, Paavola S, Kivekäs R (2007) Nature of
intramolecular interactions in hypercoordinate C-substituted 1,2-dicarba-closo-dodecaboranes
with short P…P distances. Inorg Chem Commun 10:713–716
47. Bauer S, Tschirschwitz S, Lönnecke P, Franck R, Kirchner B, Clark ML, Hey-Hawkins E
(2009) Enantiomerically Pure Bis(phosphanyl)carbaborane(12) Compounds. Eur J Inorg
Chem 2776–2788
48. Del Bene JE, Alkorta I, Sanchez-Sanz G, Elguero J (2011) Structures, energies, bonding, and
NMR properties of pnicogen complexes H 2 XP:NXH 2 (X = H, CH 3 , NH 2 , OH, F, Cl). J Phys
Chem A 115:13724–13731
49. Scheiner S (2011) Can two trivalent N atoms engage in a direct N…N noncovalent
interaction? Chem Phys Lett 514:32–35
50. Grabowski SJ (2013) σ-Hole bond versus hydrogen bond: from tetravalent to pentavalent N, P,
and as atoms. Chem Eur J 19:14600–14611
51. Sanz P, Yañez M, Mó O (2002) Competition between X…H…Y intramolecular hydrogen
bonds and X…Y (X = O, S, and Y = Se, Te) chalcogen-chalcogen interactions. J Phys
Chem A 106:4661–4668
52. Wang W, Ji B, Zhang Y (2009) Chalcogen bond: a sister noncovalent bond to halogen bond.
J Phys Chem A 113:8132–8135
53. Alikhani E, Fuster F, Madebene B, Grabowski SJ (2014) Topological reaction sites—very
strong chalcogen bonds. Phys Chem Chem Phys 16:2430–2442
54. Del Bene JE, Alkorta I, Sánchez-Sanz G, Elguero J (2011)
31
P31
P Spin-Spin coupling
constants for pnicogen homodimers. Chem Phys Lett 512:184–187
55. Del Bene JE, Alkorta I, Elguero J (2015) Substituent effects on the properties of
pnicogen-bonded complexes H 2 XP:PYH 2 , for X, Y = F, Cl, OH, NC, CCH, CH 3 , CN, and
H. J Phys Chem A 119:224–233
56. Eskandari K, Mahmoodabadi N (2013) Pnicogen bonds: a theoretical study based on the
laplacian of electron density. J Phys Chem A 117:13018–13024
57. Eskandari K, Zariny H (2010) Halogen bonding: a lump-hole interaction. Chem Phys Lett
492:9–13
58. Bento AP, Solà M, Bickelhaupt FM (2005) Ab initio and DFT benchmark study for
nucleophilic substitution at carbon (S N 2@C) and silicon (S N 2@Si). J Comput Chem 26:1497–
1504
59. Pierrefixe SCAH, Guerra CF, Bickelhaupt FM (2008) Hypervalent silicon versus carbon:
ball-in-a-box model. Chem Eur J 14:819–828
60. Levy CJ, Puddephatt RJ (1997) Rapid reversible oxidative addition of group 14-halide bonds
to platinum(ii): rates, equilibria, and bond energies. J Am Chem Soc 119:10127–10136
61. Grabowski SJ (2014) Clusters of ammonium cation–hydrogen bond versus σ-hole bond.
ChemPhysChem 15:876–884
62. Murray JS, Riley KE, Politzer P, Clark T (2010) Directional weak intermolecular interactions:
σ-hole bonding. Aust J Chem 63:1598–1607
63. Lipkowski P, Grabowski SJ (2014) Could the lithium bond be classified as the σ-hole bond?—
QTAIM and NBO analysis. Chem Phys Lett 591:113–118
64. Allen FH (2002) The cambridge structural database: a quarter of a million crystal structures
and rising. Acta Cryst B58:380–388
65. http://www.ccdc.cam.ac.uk/Lists/ResourceFileList/2014_stats_entries.pdf
432
S.J. Grabowski