Hence, video microscopy analysis is not only a tool for screening of supported
catalysts [66] but is also useful for the assignment of a given (industrial) catalyst
system to the appropriate kinetic profile and the describing mathematical model.
Finally, it is possible to explain certain aspects of crystalline homopolymer growth
versus amorphous copolymer growth and the comonomer effect [63–66].
References
1. Haenel MW (2009) Historische Sta ¨tten der Chemie: Karl Ziegler. Max-Planck-Institut fu ¨r
Kohlenforschung, Mu ¨lheim An der Ruhr. English version available at www.kofo.mpg.de/media/
2/D1105213/0478051227/Festschrift_e.pdf (Accessed 3 May 2013)
2. Martin H (1995) In: Fink G, Mu ¨lhaupt R, Brintzinger HH (eds) Ziegler catalysts: recent
scientific innovations and technological improvements. Springer, Berlin, p 15
3. Martin H (2002) Polymere und Patente – Karl Ziegler, das Team, 1953–1998. Wiley-VCH,
Weinheim
4. Breslow DS, Newburg NR (1957) J Am Chem Soc 79:5072
5. Natta G, Pino P, Mazzanti G, Gianinni U (1957) J Am Chem Soc 79:2975
6. Long WP (1959) J Am Chem Soc 81:5312
7. Chien JCW (1959) J Am Chem Soc 81:86
8. Meyer K, Reichert K-H (1970) Angew Makromol Chem 12:175
9. Reichert KH (1970) Angew Makromol Chem 13:177
10. Reichert KH, Meyer KR (1973) Makromol Chem 169:163
11. Fink G, Zoller W (1981) Makromol Chem 182:3265
12. Fink G, Rottler R (1981) Angew Makromol Chem 94:25
13. Schnell D, Fink G (1974) Angew Makromol Chem 39:131
14. Fink G, Rottler R, Schnell D, Zoller W (1976) J Appl Polym Sci 20:2779
15. Fink G, Rottler R, Kreiter CG (1981) Angew Makromol Chem 96:1
16. Fink G, Schnell D (1982) Angew Makromol Chem 105(15):31–39
17. Fink G, Fenzl W, Mynott R (1985) Z Naturforsch 40B:158
18. Mynott R, Fink G, Fenzl W (1987) Angew Makromol Chem 154:1
19. Fink G, Do ¨llinger G (1981) J Appl Polym Symp 36:67
20. Cossee P (1964) J Catal 3:80
21. Arlman EJ (1964) J Catal 3:89–99
22. Natta G, Mazzanti G (1960) Tetrahedron 8:86
23. Patat F, Sinn H (1958) Angew Chem 70:496
24. Brintzinger HH, Fischer D, Mu ¨lhaupt R, Rieger B, Waymouth R (1995) Angew Chem Int Ed
Engl 34:1143–1170
25. Kaminsky W, Ku ¨lper K, Brintzinger HH, Wild FRWP (1985) Angew Chem 97:507
26. Ewen JA (1984) J Am Chem Soc 106:6355
27. Busico V (2013) Giulio Natta and the development of the stereoselective propene polymerization. Adv Polym Sci. doi:10.1007/12_2013_213
28. Kaminsky W, Sinn H (2013) Methylaluminoxane: key component for new polymerization
catalysts. Adv Polym Sci. doi:10.1007/12_2013_226
29. Brintzinger HH, Fischer D (2013) Development of ansa-metallocenes for isotactic olefin
polymerization. Adv Polym Sci. doi:10.1007/12_2013_215
30. Ewen JA, Mol J (1998) Catal A 128:103
31. Rappe AK, Skiff WM, Casewit CJ (2000) Chem Rev 100:1435
32. van der Leek J, Angermund K, Reffke M, Kleinschmidt R, Goretzki R, Fink G (1997) Chem
Eur J 3:585
33. Kleinschmidt R, Reffke M, Fink G (1999) Macromol Rapid Commun 20:284
34
G. Fink
catalysts [66] but is also useful for the assignment of a given (industrial) catalyst
system to the appropriate kinetic profile and the describing mathematical model.
Finally, it is possible to explain certain aspects of crystalline homopolymer growth
versus amorphous copolymer growth and the comonomer effect [63–66].
References
1. Haenel MW (2009) Historische Sta ¨tten der Chemie: Karl Ziegler. Max-Planck-Institut fu ¨r
Kohlenforschung, Mu ¨lheim An der Ruhr. English version available at www.kofo.mpg.de/media/
2/D1105213/0478051227/Festschrift_e.pdf (Accessed 3 May 2013)
2. Martin H (1995) In: Fink G, Mu ¨lhaupt R, Brintzinger HH (eds) Ziegler catalysts: recent
scientific innovations and technological improvements. Springer, Berlin, p 15
3. Martin H (2002) Polymere und Patente – Karl Ziegler, das Team, 1953–1998. Wiley-VCH,
Weinheim
4. Breslow DS, Newburg NR (1957) J Am Chem Soc 79:5072
5. Natta G, Pino P, Mazzanti G, Gianinni U (1957) J Am Chem Soc 79:2975
6. Long WP (1959) J Am Chem Soc 81:5312
7. Chien JCW (1959) J Am Chem Soc 81:86
8. Meyer K, Reichert K-H (1970) Angew Makromol Chem 12:175
9. Reichert KH (1970) Angew Makromol Chem 13:177
10. Reichert KH, Meyer KR (1973) Makromol Chem 169:163
11. Fink G, Zoller W (1981) Makromol Chem 182:3265
12. Fink G, Rottler R (1981) Angew Makromol Chem 94:25
13. Schnell D, Fink G (1974) Angew Makromol Chem 39:131
14. Fink G, Rottler R, Schnell D, Zoller W (1976) J Appl Polym Sci 20:2779
15. Fink G, Rottler R, Kreiter CG (1981) Angew Makromol Chem 96:1
16. Fink G, Schnell D (1982) Angew Makromol Chem 105(15):31–39
17. Fink G, Fenzl W, Mynott R (1985) Z Naturforsch 40B:158
18. Mynott R, Fink G, Fenzl W (1987) Angew Makromol Chem 154:1
19. Fink G, Do ¨llinger G (1981) J Appl Polym Symp 36:67
20. Cossee P (1964) J Catal 3:80
21. Arlman EJ (1964) J Catal 3:89–99
22. Natta G, Mazzanti G (1960) Tetrahedron 8:86
23. Patat F, Sinn H (1958) Angew Chem 70:496
24. Brintzinger HH, Fischer D, Mu ¨lhaupt R, Rieger B, Waymouth R (1995) Angew Chem Int Ed
Engl 34:1143–1170
25. Kaminsky W, Ku ¨lper K, Brintzinger HH, Wild FRWP (1985) Angew Chem 97:507
26. Ewen JA (1984) J Am Chem Soc 106:6355
27. Busico V (2013) Giulio Natta and the development of the stereoselective propene polymerization. Adv Polym Sci. doi:10.1007/12_2013_213
28. Kaminsky W, Sinn H (2013) Methylaluminoxane: key component for new polymerization
catalysts. Adv Polym Sci. doi:10.1007/12_2013_226
29. Brintzinger HH, Fischer D (2013) Development of ansa-metallocenes for isotactic olefin
polymerization. Adv Polym Sci. doi:10.1007/12_2013_215
30. Ewen JA, Mol J (1998) Catal A 128:103
31. Rappe AK, Skiff WM, Casewit CJ (2000) Chem Rev 100:1435
32. van der Leek J, Angermund K, Reffke M, Kleinschmidt R, Goretzki R, Fink G (1997) Chem
Eur J 3:585
33. Kleinschmidt R, Reffke M, Fink G (1999) Macromol Rapid Commun 20:284
34
G. Fink