39
ylic acid-based deep eutectic solvent. Langmuir 33(50):14304–14314. https://doi.org/10.1021/
acs.langmuir.7b03254
Santana APR, Mora-Vargas JA, Guimarães TGS, Amaral CDB, Oliveira A, Gonzalez MH (2019)
Sustainable synthesis of natural deep eutectic solvents (NADES) by different methods. J Mol
Liq 293:111452. https://doi.org/10.1016/j.molliq.2019.111452
Savi LK, Carpiné D, Waszczynskyj N, Ribani RH, Haminiuk CWI (2019a) Influence of temperature, water content and type of organic acid on the formation, stability and properties of functional natural deep eutectic solvents. Fluid Phase Equilib 488:40–47. https://doi.org/10.1016/j.
fluid.2019.01.025
Savi LK, Dias MCGC, Carpine D, Waszczynskyj N, Ribani RH, Haminiuk CWI (2019b) Natural
deep eutectic solvents (NADES) based on citric acid and sucrose as a potential green technology:
a comprehensive study of water inclusion and its effect on thermal, physical and rheological
properties. Int J Food Sci Technol 54(3):898–907. https://doi.org/10.1111/ijfs.14013
Scientific opinion on safety and efficacy of choline chloride as a feed additive for all animal species (2011) EFSA J 9(9):2353. https://doi.org/10.2903/j.efsa.2011.2353
Shah D, Mjalli FS (2014) Effect of water on the thermo-physical properties of reline: an experimental and molecular simulation based approach. Phys Chem Chem Phys 16(43):23900–23907.
https://doi.org/10.1039/C4CP02600D
Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM (2011a) Prediction of deep eutectic solvents
densities at different temperatures. Thermochim Acta 515(1):67–72. https://doi.org/10.1016/j.
tca.2010.12.022
Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM (2011b) Using deep eutectic solvents based on
methyl triphenyl phosphunium bromide for the removal of glycerol from palm-oil-based biodiesel. Energy Fuel 25(6):2671–2678. https://doi.org/10.1021/ef2004943
Shahbaz K, Baroutian S, Mjalli FS, Hashim MA, AlNashef IM (2012a) Densities of ammonium and phosphonium based deep eutectic solvents: prediction using artificial intelligence
and group contribution techniques. Thermochim Acta 527:59–66. https://doi.org/10.1016/j.
tca.2011.10.010
Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM (2012b) Prediction of the surface tension of deep
eutectic solvents. Fluid Phase Equilib 319:48–54. https://doi.org/10.1016/j.fluid.2012.01.025
Shahbaz K, Bagh FSG, Mjalli FS, AlNashef IM, Hashim MA (2013) Prediction of refractive
index and density of deep eutectic solvents using atomic contributions. Fluid Phase Equilib
354:304–311. https://doi.org/10.1016/j.fluid.2013.06.050
Silva LP, Fernandez L, Conceição JHF, Martins MAR, Sosa A, Ortega J, Pinho SP, Coutinho JAP
(2018) Design and characterization of sugar-based deep eutectic solvents using conductorlike screening model for real solvents. ACS Sustain Chem Eng. https://doi.org/10.1021/
acssuschemeng.8b02042
Smith EL, Abbott AP, Ryder KS (2014) Deep eutectic solvents (DESs) and their applications.
Chem Rev 114(21):11060–11082. https://doi.org/10.1021/cr300162p
Smith PJ, Arroyo CB, Hernandez FL, Goeltz JC (2019) Ternary deep eutectic solvent behavior
of water and urea–choline chloride mixtures. J Phys Chem B. https://doi.org/10.1021/acs.
jpcb.8b12322
Tang B, Row KH (2013) Recent developments in deep eutectic solvents in chemical sciences. Monatshefte Für Chem – Chem Month 144(10):1427–1454. https://doi.org/10.1007/
s00706-013-1050-3
Teles ARR, Capela EV, Carmo RS, Coutinho JAP, Silvestre AJD, Freire MG (2017) Solvatochromic
parameters of deep eutectic solvents formed by ammonium-based salts and carboxylic acids.
Fluid Phase Equilib 448:15–21. https://doi.org/10.1016/j.fluid.2017.04.020
Valvi A, Dutta J, Tiwari S (2017) Temperature-dependent empirical parameters for polarity in
choline chloride based deep eutectic solvents. J Phys Chem B 121(50):11356–11366. https://
doi.org/10.1021/acs.jpcb.7b07754
1 Understanding the Basics and Properties of Deep Eutectic Solvents
ylic acid-based deep eutectic solvent. Langmuir 33(50):14304–14314. https://doi.org/10.1021/
acs.langmuir.7b03254
Santana APR, Mora-Vargas JA, Guimarães TGS, Amaral CDB, Oliveira A, Gonzalez MH (2019)
Sustainable synthesis of natural deep eutectic solvents (NADES) by different methods. J Mol
Liq 293:111452. https://doi.org/10.1016/j.molliq.2019.111452
Savi LK, Carpiné D, Waszczynskyj N, Ribani RH, Haminiuk CWI (2019a) Influence of temperature, water content and type of organic acid on the formation, stability and properties of functional natural deep eutectic solvents. Fluid Phase Equilib 488:40–47. https://doi.org/10.1016/j.
fluid.2019.01.025
Savi LK, Dias MCGC, Carpine D, Waszczynskyj N, Ribani RH, Haminiuk CWI (2019b) Natural
deep eutectic solvents (NADES) based on citric acid and sucrose as a potential green technology:
a comprehensive study of water inclusion and its effect on thermal, physical and rheological
properties. Int J Food Sci Technol 54(3):898–907. https://doi.org/10.1111/ijfs.14013
Scientific opinion on safety and efficacy of choline chloride as a feed additive for all animal species (2011) EFSA J 9(9):2353. https://doi.org/10.2903/j.efsa.2011.2353
Shah D, Mjalli FS (2014) Effect of water on the thermo-physical properties of reline: an experimental and molecular simulation based approach. Phys Chem Chem Phys 16(43):23900–23907.
https://doi.org/10.1039/C4CP02600D
Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM (2011a) Prediction of deep eutectic solvents
densities at different temperatures. Thermochim Acta 515(1):67–72. https://doi.org/10.1016/j.
tca.2010.12.022
Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM (2011b) Using deep eutectic solvents based on
methyl triphenyl phosphunium bromide for the removal of glycerol from palm-oil-based biodiesel. Energy Fuel 25(6):2671–2678. https://doi.org/10.1021/ef2004943
Shahbaz K, Baroutian S, Mjalli FS, Hashim MA, AlNashef IM (2012a) Densities of ammonium and phosphonium based deep eutectic solvents: prediction using artificial intelligence
and group contribution techniques. Thermochim Acta 527:59–66. https://doi.org/10.1016/j.
tca.2011.10.010
Shahbaz K, Mjalli FS, Hashim MA, AlNashef IM (2012b) Prediction of the surface tension of deep
eutectic solvents. Fluid Phase Equilib 319:48–54. https://doi.org/10.1016/j.fluid.2012.01.025
Shahbaz K, Bagh FSG, Mjalli FS, AlNashef IM, Hashim MA (2013) Prediction of refractive
index and density of deep eutectic solvents using atomic contributions. Fluid Phase Equilib
354:304–311. https://doi.org/10.1016/j.fluid.2013.06.050
Silva LP, Fernandez L, Conceição JHF, Martins MAR, Sosa A, Ortega J, Pinho SP, Coutinho JAP
(2018) Design and characterization of sugar-based deep eutectic solvents using conductorlike screening model for real solvents. ACS Sustain Chem Eng. https://doi.org/10.1021/
acssuschemeng.8b02042
Smith EL, Abbott AP, Ryder KS (2014) Deep eutectic solvents (DESs) and their applications.
Chem Rev 114(21):11060–11082. https://doi.org/10.1021/cr300162p
Smith PJ, Arroyo CB, Hernandez FL, Goeltz JC (2019) Ternary deep eutectic solvent behavior
of water and urea–choline chloride mixtures. J Phys Chem B. https://doi.org/10.1021/acs.
jpcb.8b12322
Tang B, Row KH (2013) Recent developments in deep eutectic solvents in chemical sciences. Monatshefte Für Chem – Chem Month 144(10):1427–1454. https://doi.org/10.1007/
s00706-013-1050-3
Teles ARR, Capela EV, Carmo RS, Coutinho JAP, Silvestre AJD, Freire MG (2017) Solvatochromic
parameters of deep eutectic solvents formed by ammonium-based salts and carboxylic acids.
Fluid Phase Equilib 448:15–21. https://doi.org/10.1016/j.fluid.2017.04.020
Valvi A, Dutta J, Tiwari S (2017) Temperature-dependent empirical parameters for polarity in
choline chloride based deep eutectic solvents. J Phys Chem B 121(50):11356–11366. https://
doi.org/10.1021/acs.jpcb.7b07754
1 Understanding the Basics and Properties of Deep Eutectic Solvents