179
friendly and relatively hydrophobic deep eutectic solvent. J Chromatogr A 1576:1–9. https://
doi.org/10.1016/j.chroma.2018.07.040
Rajabi M, Ghassab N, Hemmati M, Asghari A (2019) Highly effective and safe intermediate based
on deep eutectic medium for carrier less-three phase hollow fiber microextraction of antiarrhythmic agents in complex matrices. J Chromatogr B 1104:196–204. https://doi.org/10.1016/j.
jchromb.2018.11.008
Ravandi MG, Fat’hi MR (2018) Green effervescence assisted dispersive liquid–liquid microextraction based on a hydrophobic deep eutectic solvent for determination of sunset yellow and
brilliant blue FCF in food samples. New J Chem 42:14901–14908. https://doi.org/10.1039/
c8nj00782a
Ribeiro BD, Florindo C, Iff LC, Coelho MAZ, Marrucho IM (2015) Menthol-based eutectic mixtures: hydrophobic low viscosity solvents. ACS Sustain Chem Eng 3(10):2469–2477. https://
doi.org/10.1021/acssuschemeng.5b00532
Sangster J (1989) Octanol-water partition coefficients of simple organic compounds. J Phys Chem
Ref Data 18:1111–1229. https://doi.org/10.1063/1.555833
Sas OG, Castro M, Domínguez Á, González B (2019) Removing phenolic pollutants using
deep eutectic solvents. Sep Purif Technol 227:115703–115708. https://doi.org/10.1016/j.
seppur.2019.115703
Schaeffer N, Martins MAR, Neves CMSS, Pinho SP, Coutinho JAP (2018) Sustainable hydrophobic terpene-based eutectic solvents for the extraction and separation of metals. Chem Commun
54:8104–8107. https://doi.org/10.1039/c8cc04152k
Seddon KR, Stark A, Torres M (2002) Viscosity and density of 1-Alkyl-3-methylimidazolium ionic
liquids. In: Abraham MA, Moens L (eds) Clean solvents. ACS Symposium Series; American
Chemical Society, Washington, DC, pp 34–49
Shukla SK, Pandey S, Pandey S (2018) Applications of ionic liquids in biphasic separation: aqueous biphasic systems and liquid-liquid equilibria. J Chromatogr A 1559:44–61. https://doi.
org/10.1016/j.chroma.2017.10.019
Silva LP, Fernandez L, Conceicao JHF, Martins MAR, Sosa A, Ortega J, Pinho SP, Coutinho JAP
(2018) Design and characterization of sugar-based deep eutectic solvents using conductorlike screening model for real solvents. ACS Sustain Chem Eng 6(8):10724–10734. https://doi.
org/10.1021/acssuschemeng.8b02042
Silva YPA, Ferreira TAPC, Jiao G, Brooks MS (2019) Sustainable approach for lycopene extraction from tomato processing by-product using hydrophobic eutectic solvents. J Food Sci
Technol 56(3):1649–1654. https://doi.org/10.1007/s13197-019-03618-8
Smith EL, Abbott AP, Ryder KS (2014) Deep eutectic solvents (DESs) and their applications.
Chem Rev 114(21):11060–11082. https://doi.org/10.1021/cr300162p
Souza AGO, Aliprandini P, Espinosa DCR, Tenório JAS (2019) Scandium extraction from nickel
processing waste using Cyanex 923 in sulfuric medium. JOM 71(6):2003–2009. https://doi.
org/10.1007/s11837-019-03427-6
Stefanovic R, Ludwig M, Webber GB, Atkin R, Page AJ (2017) Nanostructure, hydrogen bonding
and rheology in choline chloride deep eutectic solvents as a function of the hydrogen bond
donor. Phys Chem Chem Phys 19:3297–3306. https://doi.org/10.1039/C6CP07932F
Tang W, Dai Y, Row KH (2018) Evaluation of fatty acid/alcohol-based hydrophobic deep eutectic
solvents as media for extracting antibiotics from environmental water. Anal Bioanal Chem
410(28):7325–7336. https://doi.org/10.1007/s00216-018-1346-6
Tereshatov EE, Boloeva MY, Folden lll CM (2016) First evidence of metal transfer into hydrophobic deep eutectic and low-transition-temperature mixtures: indium extraction from hydrochloric and oxalic acids. Green Chem 18:4616–4622. https://doi.org/10.1039/c5gc03080c
Thongsaw A, Udnan Y, Ross GM, Chaiyasith WC (2019) Speciation of mercury in water and biological samples by eco-friendly ultrasound-assisted deep eutectic solvent based on liquid phase
microextraction with electrothermal atomic absorption spectrometry. Talanta 197:310–318.
https://doi.org/10.1016/j.talanta.2019.01.018
5 Hydrophobic Deep Eutectic Solvents
friendly and relatively hydrophobic deep eutectic solvent. J Chromatogr A 1576:1–9. https://
doi.org/10.1016/j.chroma.2018.07.040
Rajabi M, Ghassab N, Hemmati M, Asghari A (2019) Highly effective and safe intermediate based
on deep eutectic medium for carrier less-three phase hollow fiber microextraction of antiarrhythmic agents in complex matrices. J Chromatogr B 1104:196–204. https://doi.org/10.1016/j.
jchromb.2018.11.008
Ravandi MG, Fat’hi MR (2018) Green effervescence assisted dispersive liquid–liquid microextraction based on a hydrophobic deep eutectic solvent for determination of sunset yellow and
brilliant blue FCF in food samples. New J Chem 42:14901–14908. https://doi.org/10.1039/
c8nj00782a
Ribeiro BD, Florindo C, Iff LC, Coelho MAZ, Marrucho IM (2015) Menthol-based eutectic mixtures: hydrophobic low viscosity solvents. ACS Sustain Chem Eng 3(10):2469–2477. https://
doi.org/10.1021/acssuschemeng.5b00532
Sangster J (1989) Octanol-water partition coefficients of simple organic compounds. J Phys Chem
Ref Data 18:1111–1229. https://doi.org/10.1063/1.555833
Sas OG, Castro M, Domínguez Á, González B (2019) Removing phenolic pollutants using
deep eutectic solvents. Sep Purif Technol 227:115703–115708. https://doi.org/10.1016/j.
seppur.2019.115703
Schaeffer N, Martins MAR, Neves CMSS, Pinho SP, Coutinho JAP (2018) Sustainable hydrophobic terpene-based eutectic solvents for the extraction and separation of metals. Chem Commun
54:8104–8107. https://doi.org/10.1039/c8cc04152k
Seddon KR, Stark A, Torres M (2002) Viscosity and density of 1-Alkyl-3-methylimidazolium ionic
liquids. In: Abraham MA, Moens L (eds) Clean solvents. ACS Symposium Series; American
Chemical Society, Washington, DC, pp 34–49
Shukla SK, Pandey S, Pandey S (2018) Applications of ionic liquids in biphasic separation: aqueous biphasic systems and liquid-liquid equilibria. J Chromatogr A 1559:44–61. https://doi.
org/10.1016/j.chroma.2017.10.019
Silva LP, Fernandez L, Conceicao JHF, Martins MAR, Sosa A, Ortega J, Pinho SP, Coutinho JAP
(2018) Design and characterization of sugar-based deep eutectic solvents using conductorlike screening model for real solvents. ACS Sustain Chem Eng 6(8):10724–10734. https://doi.
org/10.1021/acssuschemeng.8b02042
Silva YPA, Ferreira TAPC, Jiao G, Brooks MS (2019) Sustainable approach for lycopene extraction from tomato processing by-product using hydrophobic eutectic solvents. J Food Sci
Technol 56(3):1649–1654. https://doi.org/10.1007/s13197-019-03618-8
Smith EL, Abbott AP, Ryder KS (2014) Deep eutectic solvents (DESs) and their applications.
Chem Rev 114(21):11060–11082. https://doi.org/10.1021/cr300162p
Souza AGO, Aliprandini P, Espinosa DCR, Tenório JAS (2019) Scandium extraction from nickel
processing waste using Cyanex 923 in sulfuric medium. JOM 71(6):2003–2009. https://doi.
org/10.1007/s11837-019-03427-6
Stefanovic R, Ludwig M, Webber GB, Atkin R, Page AJ (2017) Nanostructure, hydrogen bonding
and rheology in choline chloride deep eutectic solvents as a function of the hydrogen bond
donor. Phys Chem Chem Phys 19:3297–3306. https://doi.org/10.1039/C6CP07932F
Tang W, Dai Y, Row KH (2018) Evaluation of fatty acid/alcohol-based hydrophobic deep eutectic
solvents as media for extracting antibiotics from environmental water. Anal Bioanal Chem
410(28):7325–7336. https://doi.org/10.1007/s00216-018-1346-6
Tereshatov EE, Boloeva MY, Folden lll CM (2016) First evidence of metal transfer into hydrophobic deep eutectic and low-transition-temperature mixtures: indium extraction from hydrochloric and oxalic acids. Green Chem 18:4616–4622. https://doi.org/10.1039/c5gc03080c
Thongsaw A, Udnan Y, Ross GM, Chaiyasith WC (2019) Speciation of mercury in water and biological samples by eco-friendly ultrasound-assisted deep eutectic solvent based on liquid phase
microextraction with electrothermal atomic absorption spectrometry. Talanta 197:310–318.
https://doi.org/10.1016/j.talanta.2019.01.018
5 Hydrophobic Deep Eutectic Solvents