219
© The Editor(s) (if applicable) and The Author(s), under exclusive license to
Springer Nature Switzerland AG 2020
G. Crini et al. (eds.), The History of Cyclodextrins, Environmental Chemistry
for a Sustainable World 52, https://doi.org/10.1007/978-3-030-49308-0_5
Chapter 5
Metal Nanoparticles and Cyclodextrins
for Catalytic Applications
Sébastien Noël, Anne Ponchel, Samahe Sadjadi, Eric Monflier,
and Bastien Léger
Contents
5.1 Introduction
220
5.2 Nanoparticles Stabilized by Cyclodextrins in Solution
222
5.2.1 Nanoparticles Stabilized by Native Cyclodextrins
222
5.2.2 Nanoparticles Stabilized by Functionalized Cyclodextrins
227
5.2.3 Nanoparticles Stabilized by Polymers in the Presence of Cyclodextrin
240
5.2.4 Nanoparticles Stabilized by Cyclodextrin-Based Inclusion Complex
247
5.3 Nanoparticles Immobilized on a Support in the Presence of Cyclodextrin
257
5.3.1 Nanoparticles Immobilized on a Support Considering One-Step Method
258
5.3.2 Nanoparticles Immobilized on a Support Considering Two-Step Method
269
5.4 Conclusion
272
References
273
Abstract The development of efficient catalysts in terms of activity and selectivity
has always been a major topic for researchers since several decades. The use of colloidal metallic nanoparticles received an increasing interest due to their large surface area leading to high catalytic activities. The main problems for these
nanoparticles arise from the control of their size and also their aggregation before
and during the catalytic process. In this context, the use of cyclodextrins as protective agents proved to be effective and allowed the rise of a large variety of catalytic
systems at the nanoscale.
In this chapter, we reviewed all the articles related to the metallic nanoparticles
synthesized in the presence of cyclodextrin for catalytic applications since the 1980s
S. Noël · A. Ponchel · E. Monflier · B. Léger (*)
Université d’Artois, CNRS, Centrale Lille, Université de Lille, UMR 8181, Unité de Catalyse
et de Chimie du Solide (UCCS), Lens, France
e-mail: sebastien.noel@univ-artois.fr; anne.ponchel@univ-artois.fr; eric.monflier@
univ-artois.fr; bastien.leger@univ-artois.fr
S. Sadjadi
Gas Conversion Department, Faculty of Petrochemicals, Iran Polymer and Petrochemical
Institute, Tehran, Iran
e-mail: s.sadjadi@ippi.ac.ir
© The Editor(s) (if applicable) and The Author(s), under exclusive license to
Springer Nature Switzerland AG 2020
G. Crini et al. (eds.), The History of Cyclodextrins, Environmental Chemistry
for a Sustainable World 52, https://doi.org/10.1007/978-3-030-49308-0_5
Chapter 5
Metal Nanoparticles and Cyclodextrins
for Catalytic Applications
Sébastien Noël, Anne Ponchel, Samahe Sadjadi, Eric Monflier,
and Bastien Léger
Contents
5.1 Introduction
220
5.2 Nanoparticles Stabilized by Cyclodextrins in Solution
222
5.2.1 Nanoparticles Stabilized by Native Cyclodextrins
222
5.2.2 Nanoparticles Stabilized by Functionalized Cyclodextrins
227
5.2.3 Nanoparticles Stabilized by Polymers in the Presence of Cyclodextrin
240
5.2.4 Nanoparticles Stabilized by Cyclodextrin-Based Inclusion Complex
247
5.3 Nanoparticles Immobilized on a Support in the Presence of Cyclodextrin
257
5.3.1 Nanoparticles Immobilized on a Support Considering One-Step Method
258
5.3.2 Nanoparticles Immobilized on a Support Considering Two-Step Method
269
5.4 Conclusion
272
References
273
Abstract The development of efficient catalysts in terms of activity and selectivity
has always been a major topic for researchers since several decades. The use of colloidal metallic nanoparticles received an increasing interest due to their large surface area leading to high catalytic activities. The main problems for these
nanoparticles arise from the control of their size and also their aggregation before
and during the catalytic process. In this context, the use of cyclodextrins as protective agents proved to be effective and allowed the rise of a large variety of catalytic
systems at the nanoscale.
In this chapter, we reviewed all the articles related to the metallic nanoparticles
synthesized in the presence of cyclodextrin for catalytic applications since the 1980s
S. Noël · A. Ponchel · E. Monflier · B. Léger (*)
Université d’Artois, CNRS, Centrale Lille, Université de Lille, UMR 8181, Unité de Catalyse
et de Chimie du Solide (UCCS), Lens, France
e-mail: sebastien.noel@univ-artois.fr; anne.ponchel@univ-artois.fr; eric.monflier@
univ-artois.fr; bastien.leger@univ-artois.fr
S. Sadjadi
Gas Conversion Department, Faculty of Petrochemicals, Iran Polymer and Petrochemical
Institute, Tehran, Iran
e-mail: s.sadjadi@ippi.ac.ir