1 3
Topics in Current Chemistry (2018) 376:35
39. Hauer J, Buckup T, Motzkus M (2007) Pump-degenerate four wave mixing as a technique for analyzing structural and electronic evolution: multidimensional time-resolved dynamics near a conical
intersection. J Phys Chem A 111(42):10517–10529
40. McCamant DW, Kukura P, Mathies RA (2003) Femtosecond broadband stimulated Raman: a new
approach for high-performance vibrational spectroscopy. Appl Spectrosc 57(11):1317–1323
41. Mallick B, Lakhsmanna A, Umapathy S (2011) Ultrafast Raman loss spectroscopy (URLS): instrumentation and principle. J Raman Spectrosc 42(10):1883–1890. https ://doi.org/10.1002/jrs.2996
42. Roy K, Kayal S, Kumar VR, Beeby A, Ariese F, Umapathy S (2017) Understanding ultrafast
dynamics of conformation specific photo-excitation: a femtosecond transient absorption and ultrafast Raman loss study. J Phys Chem A 121(35):6538–6546. https ://doi.org/10.1021/acs.jpca.7b038
93
43. Kayal S, Roy K, Umapathy S (2018) Femtosecond coherent nuclear dynamics of excited tetraphenylethylene: ultrafast transient absorption and ultrafast Raman loss spectroscopic studies. J Chem
Phys 148(2):024301. https ://doi.org/10.1063/1.50087 26
44. Tokmakoff A, Lang MJ, Larsen DS, Fleming GR, Chernyak V, Mukamel S (1997) Two-dimensional Raman spectroscopy of vibrational interactions in liquids. Phys Rev Lett 79(14):2702–2705.
https ://doi.org/10.1103/PhysR evLet t.79.2702
45. Yoshizawa M, Hattori Y, Kobayashi T (1994) Femtosecond time-resolved resonance Raman gain
spectroscopy in polydiacetylene. Phys Rev B 49(18):13259–13262. https ://doi.org/10.1103/PhysR
evB.49.13259
46. Kovalenko SA, Dobryakov AL, Ernsting NP (2011) An efficient setup for femtosecond stimulated
Raman spectroscopy. Rev Sci Instrum 82(6):063102. https ://doi.org/10.1063/1.35964 53
47. Rhinehart JM, Challa JR, McCamant DW (2012) Multimode charge-transfer dynamics of
4-(dimethylamino)benzonitrile probed with ultraviolet femtosecond stimulated Raman spectroscopy. J Phys Chem B 116(35):10522–10534. https ://doi.org/10.1021/jp302 0645
48. Weigel A, Ernsting NP (2010) Excited stilbene: intramolecular vibrational redistribution and solvation studied by femtosecond stimulated Raman spectroscopy. J Phys Chem B 114(23):7879–7893.
https ://doi.org/10.1021/jp100 181z
49. McCamant DW, Kukura P, Yoon S, Mathies RA (2004) Femtosecond broadband stimulated Raman
spectroscopy: apparatus and methods. Rev Sci Instrum 75(11):4971–4980
50. Dietze DR, Mathies RA (2016) Femtosecond stimulated Raman spectroscopy. ChemPhysChem
17:1224–1251. https ://doi.org/10.1002/cphc.20160 0104
51. Quick M, Dobryakov AL, Kovalenko SA, Ernsting NP (2015) Resonance femtosecond-stimulated
Raman spectroscopy without actinic excitation showing low-frequency vibrational activity in the
S-2 state of all-trans beta-carotene. J Phys Chem Lett 6(7):1216–1220. https ://doi.org/10.1021/acs.
jpcle tt.5b002 43
52. Frobel S, Buschhaus L, Villnow T, Weingart O, Gilch P (2015) The photoformation of a phthalide:
a ketene intermediate traced by FSRS. Phys Chem Chem Phys 17(1):376–386
53. Laimgruber S, Schachenmayr H, Schmidt B, Zinth W, Gilch P (2006) A femtosecond stimulated
Raman spectrograph for the near ultraviolet. Appl Phys B Lasers Opt 85(4):557–564
54. Hall CR, Conyard J, Heisler IA, Jones G, Frost J, Browne WR, Feringa BL, Meech SR (2017)
Ultrafast dynamics in light-driven molecular rotary motors probed by femtosecond stimulated
Raman spectroscopy. J Am Chem Soc 139(21):7408–7414. https ://doi.org/10.1021/jacs.7b035 99
55. Kloz M, van Grondelle R, Kennis JTM (2012) Correction for the time dependent inner filter effect
caused by transient absorption in femtosecond stimulated Raman experiment. Chem Phys Lett
544:94–101. https ://doi.org/10.1016/j.cplet t.2012.07.005
56. Kloz M, Weissenborn J, Polivka T, Frank HA, Kennis JTM (2016) Spectral watermarking in femtosecond stimulated Raman spectroscopy: resolving the nature of the carotenoid S-star state. Phys
Chem Chem Phys 18(21):14619–14628. https ://doi.org/10.1039/c6cp0 1464j
57. Kuramochi H, Takeuchi S, Tahara T (2016) Femtosecond time-resolved impulsive stimulated
Raman spectroscopy using sub-7-fs pulses: apparatus and applications. Rev Sci Instrum 87(4):10.
https ://doi.org/10.1063/1.49452 59
58. Kraack JP, Wand A, Buckup T, Motzkus M, Ruhman S (2013) Mapping multidimensional excited
state dynamics using pump-impulsive-vibrational-spectroscopy and pump-degenerate-four-wavemixing. Phys Chem Chem Phys 15(34):14487–14501
59. Cerullo G, De Silvestri S (2003) Ultrafast optical parametric amplifiers. Rev Sci Instrum 74(1):1–
18. https ://doi.org/10.1063/1.15236 42
239
Reprinted from the journal
Topics in Current Chemistry (2018) 376:35
39. Hauer J, Buckup T, Motzkus M (2007) Pump-degenerate four wave mixing as a technique for analyzing structural and electronic evolution: multidimensional time-resolved dynamics near a conical
intersection. J Phys Chem A 111(42):10517–10529
40. McCamant DW, Kukura P, Mathies RA (2003) Femtosecond broadband stimulated Raman: a new
approach for high-performance vibrational spectroscopy. Appl Spectrosc 57(11):1317–1323
41. Mallick B, Lakhsmanna A, Umapathy S (2011) Ultrafast Raman loss spectroscopy (URLS): instrumentation and principle. J Raman Spectrosc 42(10):1883–1890. https ://doi.org/10.1002/jrs.2996
42. Roy K, Kayal S, Kumar VR, Beeby A, Ariese F, Umapathy S (2017) Understanding ultrafast
dynamics of conformation specific photo-excitation: a femtosecond transient absorption and ultrafast Raman loss study. J Phys Chem A 121(35):6538–6546. https ://doi.org/10.1021/acs.jpca.7b038
93
43. Kayal S, Roy K, Umapathy S (2018) Femtosecond coherent nuclear dynamics of excited tetraphenylethylene: ultrafast transient absorption and ultrafast Raman loss spectroscopic studies. J Chem
Phys 148(2):024301. https ://doi.org/10.1063/1.50087 26
44. Tokmakoff A, Lang MJ, Larsen DS, Fleming GR, Chernyak V, Mukamel S (1997) Two-dimensional Raman spectroscopy of vibrational interactions in liquids. Phys Rev Lett 79(14):2702–2705.
https ://doi.org/10.1103/PhysR evLet t.79.2702
45. Yoshizawa M, Hattori Y, Kobayashi T (1994) Femtosecond time-resolved resonance Raman gain
spectroscopy in polydiacetylene. Phys Rev B 49(18):13259–13262. https ://doi.org/10.1103/PhysR
evB.49.13259
46. Kovalenko SA, Dobryakov AL, Ernsting NP (2011) An efficient setup for femtosecond stimulated
Raman spectroscopy. Rev Sci Instrum 82(6):063102. https ://doi.org/10.1063/1.35964 53
47. Rhinehart JM, Challa JR, McCamant DW (2012) Multimode charge-transfer dynamics of
4-(dimethylamino)benzonitrile probed with ultraviolet femtosecond stimulated Raman spectroscopy. J Phys Chem B 116(35):10522–10534. https ://doi.org/10.1021/jp302 0645
48. Weigel A, Ernsting NP (2010) Excited stilbene: intramolecular vibrational redistribution and solvation studied by femtosecond stimulated Raman spectroscopy. J Phys Chem B 114(23):7879–7893.
https ://doi.org/10.1021/jp100 181z
49. McCamant DW, Kukura P, Yoon S, Mathies RA (2004) Femtosecond broadband stimulated Raman
spectroscopy: apparatus and methods. Rev Sci Instrum 75(11):4971–4980
50. Dietze DR, Mathies RA (2016) Femtosecond stimulated Raman spectroscopy. ChemPhysChem
17:1224–1251. https ://doi.org/10.1002/cphc.20160 0104
51. Quick M, Dobryakov AL, Kovalenko SA, Ernsting NP (2015) Resonance femtosecond-stimulated
Raman spectroscopy without actinic excitation showing low-frequency vibrational activity in the
S-2 state of all-trans beta-carotene. J Phys Chem Lett 6(7):1216–1220. https ://doi.org/10.1021/acs.
jpcle tt.5b002 43
52. Frobel S, Buschhaus L, Villnow T, Weingart O, Gilch P (2015) The photoformation of a phthalide:
a ketene intermediate traced by FSRS. Phys Chem Chem Phys 17(1):376–386
53. Laimgruber S, Schachenmayr H, Schmidt B, Zinth W, Gilch P (2006) A femtosecond stimulated
Raman spectrograph for the near ultraviolet. Appl Phys B Lasers Opt 85(4):557–564
54. Hall CR, Conyard J, Heisler IA, Jones G, Frost J, Browne WR, Feringa BL, Meech SR (2017)
Ultrafast dynamics in light-driven molecular rotary motors probed by femtosecond stimulated
Raman spectroscopy. J Am Chem Soc 139(21):7408–7414. https ://doi.org/10.1021/jacs.7b035 99
55. Kloz M, van Grondelle R, Kennis JTM (2012) Correction for the time dependent inner filter effect
caused by transient absorption in femtosecond stimulated Raman experiment. Chem Phys Lett
544:94–101. https ://doi.org/10.1016/j.cplet t.2012.07.005
56. Kloz M, Weissenborn J, Polivka T, Frank HA, Kennis JTM (2016) Spectral watermarking in femtosecond stimulated Raman spectroscopy: resolving the nature of the carotenoid S-star state. Phys
Chem Chem Phys 18(21):14619–14628. https ://doi.org/10.1039/c6cp0 1464j
57. Kuramochi H, Takeuchi S, Tahara T (2016) Femtosecond time-resolved impulsive stimulated
Raman spectroscopy using sub-7-fs pulses: apparatus and applications. Rev Sci Instrum 87(4):10.
https ://doi.org/10.1063/1.49452 59
58. Kraack JP, Wand A, Buckup T, Motzkus M, Ruhman S (2013) Mapping multidimensional excited
state dynamics using pump-impulsive-vibrational-spectroscopy and pump-degenerate-four-wavemixing. Phys Chem Chem Phys 15(34):14487–14501
59. Cerullo G, De Silvestri S (2003) Ultrafast optical parametric amplifiers. Rev Sci Instrum 74(1):1–
18. https ://doi.org/10.1063/1.15236 42
239
Reprinted from the journal