1 3
Top Curr Chem (Z) (2018) 376:24
1D pump–probe techniques, and their particular contributions to the overall deexcitation process are key to understanding photo-induced lesions and mutations [108, 109]. Figure 16 shows the simulated 2DES spectra of water-solvated
Fig. 16 a Ground- (FC) and excited-state optimized structures of the solvated ApU dinucleoside
monophosphate, including S(U),
1
L b and CT states. Representative inter-bases or bond distances (in
Å) are reported, with GS values in parentheses for excited-state minima. b Schematic representation of
the PES involved in excited-state decay channels. c Predicted time evolution of the 2DUV–UV spectra
for stacked ApU conformations. The time arrow marks the approximate scale at which the spectra will
evolve according to the potential energy calculations. Reproduced from data reported in Ref. [60]
101
Reprinted from the journal
Top Curr Chem (Z) (2018) 376:24
1D pump–probe techniques, and their particular contributions to the overall deexcitation process are key to understanding photo-induced lesions and mutations [108, 109]. Figure 16 shows the simulated 2DES spectra of water-solvated
Fig. 16 a Ground- (FC) and excited-state optimized structures of the solvated ApU dinucleoside
monophosphate, including S(U),
1
L b and CT states. Representative inter-bases or bond distances (in
Å) are reported, with GS values in parentheses for excited-state minima. b Schematic representation of
the PES involved in excited-state decay channels. c Predicted time evolution of the 2DUV–UV spectra
for stacked ApU conformations. The time arrow marks the approximate scale at which the spectra will
evolve according to the potential energy calculations. Reproduced from data reported in Ref. [60]
101
Reprinted from the journal