ansa-Dimethysilylene(fluorenyl)(tertbutylamido)dimethyltitanium, 143
Diphenylmethylidene(cyclopentadienylfluorenyl)MCl2/MAO, 65
Dizirconocene–triethylaluminum complex, 4
E
Enantiomeric misinsertion, 43
Enantioselectivity, 43
Energy storage, 233
EPDM (ethene propene diene monomers), 16
Epimerization, 43, 129
Ethene–1,3-butadiene, 16
Ethene–1-butene, hexene (LLDPE), 16
Ethene–cyclopentene, 16
Ethene-graft-ethene/propene, 17
Ethene–1,5-hexadiene elastomer, 16
Ethene–norbornene, 16, 19, 123
Ethene–1-octene (LLDPE), 16
Ethene–propene (EP), 16, 29, 38
diene (EPDM), 16
Ethylaluminoxane, 7
Ethylene polymerization, 341
iron catalysts, 344
reactivity, 164
F
FG/poly(ethylene-co-1-octene), 293
Fluorenyl substituents, 70
Fluorenyl–Zr–cyclopentadienyl bond, 48
Fullerene, 288
G
Gasoline depressants, 165
Graft copolymer, 233
Graphene, 283, 288
functionalized, 291
nanoplatelets (GNP), 290
Graphite oxide (GO), 290
Graphite polymerization filling technique, 292
H
Hafnocenes, 9, 13, 30
Hectorite, 314
Heterogenization, 43
Hexahydrobenzenomethanoanthracene
(HBMN), 136
Hexamethyltetraaluminoxane, 7
5-Hexen-1-ol, 212
Homopolymers, 9
I
Iminoethylpyridine, 173
Iminophenanthrolyliron, 169
Iminoquinolines, 171
Iron catalysis, 341
Isopropylidene(cyclopentadienyl fluorenyl)
MCl 2 , 48
K
Kaolinite, 313
L
Living polymerization, 143
Long-chain branching (LCB), 183, 195
M
Metallocenes, catalysts, 1, 9
bridged, 43
MAO, 1, 23
molecular symmetry, 89
siloxysubstituted, 179
Metallocenium–monoalkyl cation, 49
Methylaluminoxane (MAO), 1, 5, 30, 32, 46,
182, 283
modified (MMAO), 143, 144
trialkylaluminum-free modified
(dMMAO), 143
Microcomposites, phase-separated, 318
Molar-mass distribution, 29
Molecular reinforcement, 278
Montmorillonite, 286, 311, 313, 355
Multi-walled carbon nanotubes
(MWCNT), 19, 289
N
Nanocomposites, 278, 281, 319
BIP FeCl2 catalysis, 355
characterization, 311, 319
exfoliated, 318
intercalated, 318
polyolefin/clay, 311
Nanofillers, 19, 279
Naphthyloxydiiminato nickel, 132
Nickel complexes, 173
Nitrocyclic-6-iminopyridyliron, 170
Norbornene/1-alkene, 154
Norbornene/ethene, 18
Norbornenes, 117, 123, 143
functionalized, 131
homopolymerization, 153
364
Index
Diphenylmethylidene(cyclopentadienylfluorenyl)MCl2/MAO, 65
Dizirconocene–triethylaluminum complex, 4
E
Enantiomeric misinsertion, 43
Enantioselectivity, 43
Energy storage, 233
EPDM (ethene propene diene monomers), 16
Epimerization, 43, 129
Ethene–1,3-butadiene, 16
Ethene–1-butene, hexene (LLDPE), 16
Ethene–cyclopentene, 16
Ethene-graft-ethene/propene, 17
Ethene–1,5-hexadiene elastomer, 16
Ethene–norbornene, 16, 19, 123
Ethene–1-octene (LLDPE), 16
Ethene–propene (EP), 16, 29, 38
diene (EPDM), 16
Ethylaluminoxane, 7
Ethylene polymerization, 341
iron catalysts, 344
reactivity, 164
F
FG/poly(ethylene-co-1-octene), 293
Fluorenyl substituents, 70
Fluorenyl–Zr–cyclopentadienyl bond, 48
Fullerene, 288
G
Gasoline depressants, 165
Graft copolymer, 233
Graphene, 283, 288
functionalized, 291
nanoplatelets (GNP), 290
Graphite oxide (GO), 290
Graphite polymerization filling technique, 292
H
Hafnocenes, 9, 13, 30
Hectorite, 314
Heterogenization, 43
Hexahydrobenzenomethanoanthracene
(HBMN), 136
Hexamethyltetraaluminoxane, 7
5-Hexen-1-ol, 212
Homopolymers, 9
I
Iminoethylpyridine, 173
Iminophenanthrolyliron, 169
Iminoquinolines, 171
Iron catalysis, 341
Isopropylidene(cyclopentadienyl fluorenyl)
MCl 2 , 48
K
Kaolinite, 313
L
Living polymerization, 143
Long-chain branching (LCB), 183, 195
M
Metallocenes, catalysts, 1, 9
bridged, 43
MAO, 1, 23
molecular symmetry, 89
siloxysubstituted, 179
Metallocenium–monoalkyl cation, 49
Methylaluminoxane (MAO), 1, 5, 30, 32, 46,
182, 283
modified (MMAO), 143, 144
trialkylaluminum-free modified
(dMMAO), 143
Microcomposites, phase-separated, 318
Molar-mass distribution, 29
Molecular reinforcement, 278
Montmorillonite, 286, 311, 313, 355
Multi-walled carbon nanotubes
(MWCNT), 19, 289
N
Nanocomposites, 278, 281, 319
BIP FeCl2 catalysis, 355
characterization, 311, 319
exfoliated, 318
intercalated, 318
polyolefin/clay, 311
Nanofillers, 19, 279
Naphthyloxydiiminato nickel, 132
Nickel complexes, 173
Nitrocyclic-6-iminopyridyliron, 170
Norbornene/1-alkene, 154
Norbornene/ethene, 18
Norbornenes, 117, 123, 143
functionalized, 131
homopolymerization, 153
364
Index