polyolefins. New, designed catalysts will enlarge the polyolefin industry and the
applications of polymers.
References
1. Ziegler K, Holzkamp E, Breil H, Martin H (1955) Angew Chem 67:541
2. Breslow DS, Newburg NR (1957) J Am Chem Soc 79:5072
3. Natta G, Pino P, Mazzanti G, Longi P (1957) Gazz Chim Ital 87:549
4. Patat F, Sinn H (1958) Angew Chem 70:496
5. Shilov AE (1960) Dok Akad Nauk SSS 132:599
6. Henrici-Olive ´ G, Olive ´ S (1969) J Organomet Chem 16:339
7. Reichert KH, Schoetter E (1968) Z Phys Chem 57:74
8. Fink G, Rottler R (1981) Angew Makromol Chem 94:2
9. Waters JA, Mortimer GA (1972) J Polym Sci A1 10:895–907
10. Chien JCW (1959) J Am Chem Soc 81:86
11. Fink G, Schnell D (1982) Angew Makromol Chem 105:39
12. Sinn H, Patat F (1963) Angew Chem 75:805
13. Sinn H, Hinck H, Bandermann F, Gru ¨tzmacher HF (1968) Angew Chem 80:190
14. Kaminsky W, Sinn H (1975) Justus Liebigs Ann Chem 1975:424
15. Kaminsky W, Vollmer HJ, Heins E, Sinn H (1974) Makromol Chem 175:443
16. Sinn H, Kolk E (1966) J Organomet Chem 6:373
17. Kaminsky W, Kopf J, Sinn H, Vollmer HJ (1976) Angew Chem Int Ed Engl 15:629
18. Sinn H (1974) Chem Ing Technol 46:579
19. Sinn H, Kaminsky W, Janning J (1976) Angew Chem 88:737
20. Heins E, Hinck H, Kaminsky W, Oppermann G, Raulinat P, Sinn H (1970) Makromol Chem
134:125
21. Mottweiler R (1975) Thesis. University of Hamburg, Hamburg
22. Andresen A, Cordes HG, Herwig J, Kaminsky W, Merck A, Mottweiler R, Pein J, Sinn H,
Vollmer HJ (1976) Angew Chem Int Ed Engl 15:630
23. Sinn H, Kaminsky W (1980) Ziegler–Natta catalysis. Adv Organomet Chem 18:99
24. Kaminsky W (2004) J Polym Sci A Polym Chem 42:3911
25. Kaminsky W (2012) Macromolecules 45:3289
26. Reichert KH, Meyer KR (1973) Makromol Chem 169:163
27. Long WP, Breslow DS (1975) Justus Liebigs Ann Chem 1975:463
28. Lehmkuhl H, Ziegler K (1970) In: Houben J, Weyl T (eds) Methoden der organische Chemie
(Houben-Weyl) vol XIII, part 4. Thieme, Stuttgart, p 76
29. Storr A, Jones K, Laubengayer AW (1968) J Am Chem Soc 90:3173
30. Ba ¨hr G (1946) Fiat review of German Science. Inorganic chemistry, Part II, p 161
31. Herwig J, Kaminsky W (1983) Polym Bull 9:464
32. Sinn H, Bliemeister J, Clausnitzer D, Tikwe L, Winter H, Zarncke O (1988) In: Kaminsky W,
Sinn H (eds) Transition metals and organometallics as catalysts for olefin polymerization.
Springer, Berlin, p 257
33. Bliemeister J, Hagendorf W, Harder A, Heitmann B, Schimmel I, Schmedt E, Schnuchel W,
Sinn H, Tikwe L, vThienen N, Urlass K, Winter H, Zarncke O (1995) In: Fink G, Mu ¨lhaupt P,
Brintzinger HH (eds) Ziegler catalysts. Springer, Berlin, p 57
34. Sinn H, Schimmel I, Ott M, vThienen N, Harder A, Hagendorf W, Heitmann B, Haupt E
(1999) In: Kaminsky W (ed) Metalorganic catalysts for synthesis and polymerization.
Springer, Berlin, p 105
35. Sinn H, Namyslo J (2012) Colloquium at Chemistry Department, University Hamburg,
30 May 2012
36. Smith GM, Palmaka SW, Rogers JS, Malpass DB, Monfiston DJ (1998) US Patent 5,831,109
to Akzo Nobel
Methylaluminoxane: Key Component for New Polymerization Catalysts
25
applications of polymers.
References
1. Ziegler K, Holzkamp E, Breil H, Martin H (1955) Angew Chem 67:541
2. Breslow DS, Newburg NR (1957) J Am Chem Soc 79:5072
3. Natta G, Pino P, Mazzanti G, Longi P (1957) Gazz Chim Ital 87:549
4. Patat F, Sinn H (1958) Angew Chem 70:496
5. Shilov AE (1960) Dok Akad Nauk SSS 132:599
6. Henrici-Olive ´ G, Olive ´ S (1969) J Organomet Chem 16:339
7. Reichert KH, Schoetter E (1968) Z Phys Chem 57:74
8. Fink G, Rottler R (1981) Angew Makromol Chem 94:2
9. Waters JA, Mortimer GA (1972) J Polym Sci A1 10:895–907
10. Chien JCW (1959) J Am Chem Soc 81:86
11. Fink G, Schnell D (1982) Angew Makromol Chem 105:39
12. Sinn H, Patat F (1963) Angew Chem 75:805
13. Sinn H, Hinck H, Bandermann F, Gru ¨tzmacher HF (1968) Angew Chem 80:190
14. Kaminsky W, Sinn H (1975) Justus Liebigs Ann Chem 1975:424
15. Kaminsky W, Vollmer HJ, Heins E, Sinn H (1974) Makromol Chem 175:443
16. Sinn H, Kolk E (1966) J Organomet Chem 6:373
17. Kaminsky W, Kopf J, Sinn H, Vollmer HJ (1976) Angew Chem Int Ed Engl 15:629
18. Sinn H (1974) Chem Ing Technol 46:579
19. Sinn H, Kaminsky W, Janning J (1976) Angew Chem 88:737
20. Heins E, Hinck H, Kaminsky W, Oppermann G, Raulinat P, Sinn H (1970) Makromol Chem
134:125
21. Mottweiler R (1975) Thesis. University of Hamburg, Hamburg
22. Andresen A, Cordes HG, Herwig J, Kaminsky W, Merck A, Mottweiler R, Pein J, Sinn H,
Vollmer HJ (1976) Angew Chem Int Ed Engl 15:630
23. Sinn H, Kaminsky W (1980) Ziegler–Natta catalysis. Adv Organomet Chem 18:99
24. Kaminsky W (2004) J Polym Sci A Polym Chem 42:3911
25. Kaminsky W (2012) Macromolecules 45:3289
26. Reichert KH, Meyer KR (1973) Makromol Chem 169:163
27. Long WP, Breslow DS (1975) Justus Liebigs Ann Chem 1975:463
28. Lehmkuhl H, Ziegler K (1970) In: Houben J, Weyl T (eds) Methoden der organische Chemie
(Houben-Weyl) vol XIII, part 4. Thieme, Stuttgart, p 76
29. Storr A, Jones K, Laubengayer AW (1968) J Am Chem Soc 90:3173
30. Ba ¨hr G (1946) Fiat review of German Science. Inorganic chemistry, Part II, p 161
31. Herwig J, Kaminsky W (1983) Polym Bull 9:464
32. Sinn H, Bliemeister J, Clausnitzer D, Tikwe L, Winter H, Zarncke O (1988) In: Kaminsky W,
Sinn H (eds) Transition metals and organometallics as catalysts for olefin polymerization.
Springer, Berlin, p 257
33. Bliemeister J, Hagendorf W, Harder A, Heitmann B, Schimmel I, Schmedt E, Schnuchel W,
Sinn H, Tikwe L, vThienen N, Urlass K, Winter H, Zarncke O (1995) In: Fink G, Mu ¨lhaupt P,
Brintzinger HH (eds) Ziegler catalysts. Springer, Berlin, p 57
34. Sinn H, Schimmel I, Ott M, vThienen N, Harder A, Hagendorf W, Heitmann B, Haupt E
(1999) In: Kaminsky W (ed) Metalorganic catalysts for synthesis and polymerization.
Springer, Berlin, p 105
35. Sinn H, Namyslo J (2012) Colloquium at Chemistry Department, University Hamburg,
30 May 2012
36. Smith GM, Palmaka SW, Rogers JS, Malpass DB, Monfiston DJ (1998) US Patent 5,831,109
to Akzo Nobel
Methylaluminoxane: Key Component for New Polymerization Catalysts
25