48. Tomalia DA, Brothers HM II, Piehler LT, Durst HD, Swanson DR (2002) Partial shell-filled
core-shell tecto(dendrimers): a strategy to surface differentiated nano-clefts and cusps. Proc
Natl Acad Sci USA 99(8):5081–5087
49. Tomalia DA, Brothers HM II, Piehler LT, Hsu Y (1995) Polym Mater Sci Eng 73:75
50. Tomalia DA (1996) Starburst dendrimers – nanoscopic supermolecules according to dendritic rules and principles. Macromol Symp 101:243–255
51. Naj AK (1996) Persistent inventor markets a molecule. Wall Street J Feb 26(1996):B1
52. Tomalia DA, Christensen JB, Boas U (2012) Dendrimers, dendrons, and dendritic polymers:
discovery applications and the future. Cambridge University Press, New York
53. Campagna S, Ceroni P, Puntoriero F (2012) Designing dendrimers. Wiley, Hoboken
54. Hecht S, Fre ´chet JMJ (2001) Dendritic encapsulation of function: applying nature’ site
isolation principle from biomimetics to materials science. Angew Chem Int Ed 40(1):74–91
55. Fre ´chet JMJ, Tomalia DA (2001) Dendrimers and other dendritic polymers. Wiley,
Chichester
56. Newkome GR, Moorfield CN, Vo ¨gtle F (1996) Dendritic molecules. Wiley-VCH, Weinheim
57. Gunatillake PA, Odian G, Tomalia DA (1988) Thermal polymerization of a 2-(carboxyalkyl)2-oxazoline. Macromolecules 21:1556–1562
58. Kim YH, Webster OW (1988) Polym Prepr 29:310
59. Kim YH, Webster OW (1990) Water-soluble hyperbranched polyphenylene: a unimolecular
micelle. J Am Chem Soc 112:4592–4593
60. Emrick T, Chang HT, Fre `chet JMJ (2000) The preparation of hyperbranched aromatic and
aliphatic polyether epoxies by chloride-catalyzed proton transfer polymerization from
AB n and A 2 + B 3 monomers. J Poly Sci A 38:4850–4869
61. Emrick T, Fre ´chet JMJ (1999) Self-assembly of dendritic structures. Curr Opin Coll Interface
Sci 4:15–23
62. Bharati P, Moore JS (1997) Solid-supported hyperbranched polymerization: evidence for
self-limited growth. J Am Chem Soc 119:3391
63. Muzafarov AM, Rebrov EA, Gorbatsevich OB, Golly M, Gankema H, Moller M (1996)
Degradable dendritic polymers — a template for functional pores and nanocavities.
Macromol Symp 102:35
64. Miravet JF, Fre `chet JMJ (1998) New hyperbranched poly(siloxysilanes): variation of the
branching pattern and end-functionalization. Macromolecules 31:3461–3468
65. Chu F, Hawker CJ (1993) A versatile synthesis of isomeric hyperbranched polyetherketones.
Polym Bull 30:265–272
66. Hawker CJ, Lee R, Frechet JMJ (1991) One-step synthesis of hyperbranched dendritic
polyesters. J Am Chem Soc 113:4583–4588
67. Uhrich KE, Hawker CJ, Fre `chet JMJ, Turner SR (1992) One-pot synthesis of hyperbranched
polyethers. Macromolecules 25:4583–4587
68. Liu M, Vladimirov N, Fre `chet JMJ (1999) A new approach to hyperbranched polymers by
ring-opening polymerization of an AB monomer: 4-(À2-hydroxyethyl)-e-caprolactone.
Macromolecules 32:6881–6884
69. Fre ´chet JMJ, Henmi M, Gitsov I, Aoshima S, Leduc MR, Grubbs RB (1995) Self-condensing
vinyl polymerization: an approach to dendritic materials. Science 269:1080–1083
70. Hawker CJ, Farrington PJ, Mackay ME, Wooley KL, Fre `chet JMJ (1995) Molecular ball
bearings: the unusual melt viscosity behavior of dendritic macromolecules. J Am Chem Soc
117:4409–4410
71. Sunder A, Heinemann J, Frey H (2000) Controlling the growth of polymer trees: concepts and
perspectives for hyperbranched polymers. Chem Eur J 6(14):2499–2506
72. Gong C, Miravet J, Fre `chet JMJ (2000) Intramolecular cyclization in the polymerization of
AB x monomers: approaches to the control of molecular weight and polydispersity in
hyperbranched poly(siloxysilane). J Polym Sci A 37:3193–3201
73. Tomalia DA, Hedstrand DM, Ferrito MS (1991) COMBBURST™ dendrimers – a new
macromolecular architecture. Macromolecules 24:1435–1438
Twenty-First Century Polymer Science After Staudinger: The Emergence of. . .
383
core-shell tecto(dendrimers): a strategy to surface differentiated nano-clefts and cusps. Proc
Natl Acad Sci USA 99(8):5081–5087
49. Tomalia DA, Brothers HM II, Piehler LT, Hsu Y (1995) Polym Mater Sci Eng 73:75
50. Tomalia DA (1996) Starburst dendrimers – nanoscopic supermolecules according to dendritic rules and principles. Macromol Symp 101:243–255
51. Naj AK (1996) Persistent inventor markets a molecule. Wall Street J Feb 26(1996):B1
52. Tomalia DA, Christensen JB, Boas U (2012) Dendrimers, dendrons, and dendritic polymers:
discovery applications and the future. Cambridge University Press, New York
53. Campagna S, Ceroni P, Puntoriero F (2012) Designing dendrimers. Wiley, Hoboken
54. Hecht S, Fre ´chet JMJ (2001) Dendritic encapsulation of function: applying nature’ site
isolation principle from biomimetics to materials science. Angew Chem Int Ed 40(1):74–91
55. Fre ´chet JMJ, Tomalia DA (2001) Dendrimers and other dendritic polymers. Wiley,
Chichester
56. Newkome GR, Moorfield CN, Vo ¨gtle F (1996) Dendritic molecules. Wiley-VCH, Weinheim
57. Gunatillake PA, Odian G, Tomalia DA (1988) Thermal polymerization of a 2-(carboxyalkyl)2-oxazoline. Macromolecules 21:1556–1562
58. Kim YH, Webster OW (1988) Polym Prepr 29:310
59. Kim YH, Webster OW (1990) Water-soluble hyperbranched polyphenylene: a unimolecular
micelle. J Am Chem Soc 112:4592–4593
60. Emrick T, Chang HT, Fre `chet JMJ (2000) The preparation of hyperbranched aromatic and
aliphatic polyether epoxies by chloride-catalyzed proton transfer polymerization from
AB n and A 2 + B 3 monomers. J Poly Sci A 38:4850–4869
61. Emrick T, Fre ´chet JMJ (1999) Self-assembly of dendritic structures. Curr Opin Coll Interface
Sci 4:15–23
62. Bharati P, Moore JS (1997) Solid-supported hyperbranched polymerization: evidence for
self-limited growth. J Am Chem Soc 119:3391
63. Muzafarov AM, Rebrov EA, Gorbatsevich OB, Golly M, Gankema H, Moller M (1996)
Degradable dendritic polymers — a template for functional pores and nanocavities.
Macromol Symp 102:35
64. Miravet JF, Fre `chet JMJ (1998) New hyperbranched poly(siloxysilanes): variation of the
branching pattern and end-functionalization. Macromolecules 31:3461–3468
65. Chu F, Hawker CJ (1993) A versatile synthesis of isomeric hyperbranched polyetherketones.
Polym Bull 30:265–272
66. Hawker CJ, Lee R, Frechet JMJ (1991) One-step synthesis of hyperbranched dendritic
polyesters. J Am Chem Soc 113:4583–4588
67. Uhrich KE, Hawker CJ, Fre `chet JMJ, Turner SR (1992) One-pot synthesis of hyperbranched
polyethers. Macromolecules 25:4583–4587
68. Liu M, Vladimirov N, Fre `chet JMJ (1999) A new approach to hyperbranched polymers by
ring-opening polymerization of an AB monomer: 4-(À2-hydroxyethyl)-e-caprolactone.
Macromolecules 32:6881–6884
69. Fre ´chet JMJ, Henmi M, Gitsov I, Aoshima S, Leduc MR, Grubbs RB (1995) Self-condensing
vinyl polymerization: an approach to dendritic materials. Science 269:1080–1083
70. Hawker CJ, Farrington PJ, Mackay ME, Wooley KL, Fre `chet JMJ (1995) Molecular ball
bearings: the unusual melt viscosity behavior of dendritic macromolecules. J Am Chem Soc
117:4409–4410
71. Sunder A, Heinemann J, Frey H (2000) Controlling the growth of polymer trees: concepts and
perspectives for hyperbranched polymers. Chem Eur J 6(14):2499–2506
72. Gong C, Miravet J, Fre `chet JMJ (2000) Intramolecular cyclization in the polymerization of
AB x monomers: approaches to the control of molecular weight and polydispersity in
hyperbranched poly(siloxysilane). J Polym Sci A 37:3193–3201
73. Tomalia DA, Hedstrand DM, Ferrito MS (1991) COMBBURST™ dendrimers – a new
macromolecular architecture. Macromolecules 24:1435–1438
Twenty-First Century Polymer Science After Staudinger: The Emergence of. . .
383