structural details down to the molecular scale and in understanding the intrinsic
crystallization mechanisms. New developments in the use of TEM to analyze the
structure of SCPs are on the way. In particular, we recently showed the possibility of
performing in-situ temperature-dependent experiments to follow structural transitions
and reorientation processes in devices and correlating them with corresponding
modifications in charge transport properties [73].
References
1. Heeger AJ (2001) Rev Mod Phys 73:681
2. James DI, Smith J, Heeney M, Anthopoulos TD, Salleo A, McCulloch I (2012) Organic
semiconductor materials for transistors. In: Klauk H (ed) Organic electronics II: more materials and applications. Wiley-VCH, Weinheim, pp 1–26
3. Virkar AA, Mannsfeld S, Bao Z, Stingelin N (2010) Adv Mater 22:3857
4. Sirringhaus H, Kawase T, Friend RH, Shimoda T, Inbasekaran M, Wu W, Woo EP (2000)
Science 290:2123
5. Friend RH, Gymer RW, Holmes AB, Burroughes JH, Marks RN, Taliani C, Bradley DDC, Dos
Santos DA, Bre ´das JL, Lo ¨gdlund M, Salaneck WR (1999) Nature 397:121
6. Sirringhaus H, Brown PJ, Friend RH, Nielsen MM, Bechgaard K, Langeveld-Voss BMW,
Spiering AJH, Janssen RAJ, Meijer EW, Herwig P, de Leeuw DM (1999) Nature 401:685
7. Nelson J (2002) Curr Opin Solid State Mater Sci 6:87
8. Brabec C, Scherff U, Diakonov V (2008) Organic photovoltaics. Wiley, Weinheim
9. Facchetti A (2010) Chem Mater 23:733
10. Himmelberger S, Dacun ˜a J, Rivnay J, Jimison LH, McCarthy-Ward T, Heeney M,
McCulloch I, Toney MF, Salleo A (2013) Adv Funct Mater 23:2091
11. Rivnay J, Mannsfeld SCB, Miller CE, Salleo A, Toney MF (2012) Chem Rev 112:5488
12. Lim JA, Liu F, Ferdous S, Muthukumar M, Briseno AL (2010) Mater Today 13:14
13. Brinkmann M (2011) J Polym Sci B 49:1218
14. Chang JF, Sun B, Breiby DW, Nielsen MN, So ¨lling TI, Giles M, McCulloch I, Sirringhaus H
(2004) Chem Mater 16:4772
15. Rivnay J, Steyrleuthner R, Jimison LH, Casadei A, Chen Z, Toney MF, Facchetti A, Neher D,
Salleo A (2011) Macromolecules 44:5246
16. Chabinyc ML, Toney MF, Kline RJ, McCulloch I, Heeney M (2007) J Am Chem Soc 129:3226
17. Yang H, Shine TJ, Yang L, Cho K, Ryu CY, Bao Z (2005) Adv Funct Mater 15:671
18. Yang H, LeFevre SW, Ryu C, Bao Z (2007) Appl Phys Lett 90:172116
19. Crossland EJW, Tremel K, Fischer F, Rahimi K, Reiter G, Steiner U, Ludwigs S (2012) Adv
Mater 24:839
20. Tremel K, Ludwigs S (2014) Morphology of P3HT in thin films in relation to optical and
electrical properties. Adv Polym Sci. doi:10.1007/12_2014_288
21. Jimison LH, Toney MF, McCulloch I, Heeney M, Salleo A (2009) Adv Mater 21:1568
22. Zheng Z, Yim KH, Saifullah MSM, Welland ME, Friend RH, Kim JS, Huck WTS (2007) Nano
Lett 7:987
23. Lan YK, Huang CI (2009) J Phys Chem B 90:62117
24. Brabec CJ, Gowrisanker S, Halls JJM, Laird D, Jia S, Williams SP (2010) Adv Mater 22:3839
25. Peet J, Heeger AJ, Bazan GC (2009) Acc Chem Res 42:1700
26. Ward MD (2001) Chem Rev 101:1697
27. Hooks DE, Fritz T, Ward MD (2001) Adv Mater 13:227
28. Jiang S, Qian H, Liu W, Wang C, Wang Z, Yan S, Zhu D (2009) Macromolecules 42:9321
104
M. Brinkmann et al.
crystallization mechanisms. New developments in the use of TEM to analyze the
structure of SCPs are on the way. In particular, we recently showed the possibility of
performing in-situ temperature-dependent experiments to follow structural transitions
and reorientation processes in devices and correlating them with corresponding
modifications in charge transport properties [73].
References
1. Heeger AJ (2001) Rev Mod Phys 73:681
2. James DI, Smith J, Heeney M, Anthopoulos TD, Salleo A, McCulloch I (2012) Organic
semiconductor materials for transistors. In: Klauk H (ed) Organic electronics II: more materials and applications. Wiley-VCH, Weinheim, pp 1–26
3. Virkar AA, Mannsfeld S, Bao Z, Stingelin N (2010) Adv Mater 22:3857
4. Sirringhaus H, Kawase T, Friend RH, Shimoda T, Inbasekaran M, Wu W, Woo EP (2000)
Science 290:2123
5. Friend RH, Gymer RW, Holmes AB, Burroughes JH, Marks RN, Taliani C, Bradley DDC, Dos
Santos DA, Bre ´das JL, Lo ¨gdlund M, Salaneck WR (1999) Nature 397:121
6. Sirringhaus H, Brown PJ, Friend RH, Nielsen MM, Bechgaard K, Langeveld-Voss BMW,
Spiering AJH, Janssen RAJ, Meijer EW, Herwig P, de Leeuw DM (1999) Nature 401:685
7. Nelson J (2002) Curr Opin Solid State Mater Sci 6:87
8. Brabec C, Scherff U, Diakonov V (2008) Organic photovoltaics. Wiley, Weinheim
9. Facchetti A (2010) Chem Mater 23:733
10. Himmelberger S, Dacun ˜a J, Rivnay J, Jimison LH, McCarthy-Ward T, Heeney M,
McCulloch I, Toney MF, Salleo A (2013) Adv Funct Mater 23:2091
11. Rivnay J, Mannsfeld SCB, Miller CE, Salleo A, Toney MF (2012) Chem Rev 112:5488
12. Lim JA, Liu F, Ferdous S, Muthukumar M, Briseno AL (2010) Mater Today 13:14
13. Brinkmann M (2011) J Polym Sci B 49:1218
14. Chang JF, Sun B, Breiby DW, Nielsen MN, So ¨lling TI, Giles M, McCulloch I, Sirringhaus H
(2004) Chem Mater 16:4772
15. Rivnay J, Steyrleuthner R, Jimison LH, Casadei A, Chen Z, Toney MF, Facchetti A, Neher D,
Salleo A (2011) Macromolecules 44:5246
16. Chabinyc ML, Toney MF, Kline RJ, McCulloch I, Heeney M (2007) J Am Chem Soc 129:3226
17. Yang H, Shine TJ, Yang L, Cho K, Ryu CY, Bao Z (2005) Adv Funct Mater 15:671
18. Yang H, LeFevre SW, Ryu C, Bao Z (2007) Appl Phys Lett 90:172116
19. Crossland EJW, Tremel K, Fischer F, Rahimi K, Reiter G, Steiner U, Ludwigs S (2012) Adv
Mater 24:839
20. Tremel K, Ludwigs S (2014) Morphology of P3HT in thin films in relation to optical and
electrical properties. Adv Polym Sci. doi:10.1007/12_2014_288
21. Jimison LH, Toney MF, McCulloch I, Heeney M, Salleo A (2009) Adv Mater 21:1568
22. Zheng Z, Yim KH, Saifullah MSM, Welland ME, Friend RH, Kim JS, Huck WTS (2007) Nano
Lett 7:987
23. Lan YK, Huang CI (2009) J Phys Chem B 90:62117
24. Brabec CJ, Gowrisanker S, Halls JJM, Laird D, Jia S, Williams SP (2010) Adv Mater 22:3839
25. Peet J, Heeger AJ, Bazan GC (2009) Acc Chem Res 42:1700
26. Ward MD (2001) Chem Rev 101:1697
27. Hooks DE, Fritz T, Ward MD (2001) Adv Mater 13:227
28. Jiang S, Qian H, Liu W, Wang C, Wang Z, Yan S, Zhu D (2009) Macromolecules 42:9321
104
M. Brinkmann et al.